Preparation method of filter core of composite ultrafiltration tube membrane
A technology of ultrafiltration tubes and ultrafiltration membranes, applied in ultrafiltration, chemical instruments and methods, membrane technology, etc., can solve problems such as poor removal of heavy metal ions, excessive bacterial content in effluent, short service life, etc., and reach the production cycle Short, fast removal, simple process effect
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Embodiment 1
[0026] Dissolve 0.01g of silver nitrate in 10mL of deionized water at room temperature, dissolve 20g of copper acetate and 20g of zinc acetate in 500mL of deionized water at 70°C, and after completely dissolving, add 100g of diatomite powder with a diameter of 0.1 to 5μm into copper acetate , zinc acetate solution, then add silver nitrate solution, keep the solution temperature at 70°C, stir at a low speed for 4 hours, remove the residual solution, mix the diatomite loaded with metal ions obtained above with 200g deionized water and 0.5g carboxymethyl fiber After the sodium is mixed, stir for 1 hour to prepare a composite slurry; inject the prepared composite slurry into a metal tube with a rotation speed of 10,000 rpm, rotate for 10 minutes, and centrifugally form it to prepare a composite ultrafiltration membrane tube green body; the green body is baked After drying, demould, under hydrogen reduction, microwave sintering, the sintering temperature is 1600 ℃, keep warm for 4 h...
Embodiment 2
[0028] Dissolve 0.1g of silver nitrate in 20mL of deionized water at room temperature, dissolve 10g of copper sulfate and 10g of zinc sulfate in 200mL of deionized water at room temperature, and after completely dissolving, add 500g of natural zeolite powder with a diameter of 0.5-5μm , zinc sulfate solution, then add silver nitrate solution, stir at low speed for 2 hours, remove the residual solution, mix the above-mentioned natural zeolite powder loaded with metal ions with 1000g deionized water and 1.5g polyvinyl alcohol, stir for 1 hour, and prepare into a composite slurry; inject the prepared composite slurry into a metal tube with a rotating speed of 5000rpm, rotate for 15min, and centrifuge to form a composite ultrafiltration membrane tube green body; the green body is demoulded after drying, and reduced in hydrogen Under microwave sintering, the sintering temperature is 1200°C, heat preservation for 2h, and the composite ultrafiltration tube membrane filter element is m...
Embodiment 3
[0030] Dissolve 0.3g of silver nitrate in 20mL of deionized water at room temperature, dissolve 50g of copper chloride and 50g of zinc acetate in 500mL of deionized water at room temperature. In copper chloride, zinc chloride solution, add silver nitrate solution again, after low-speed stirring 3h, remove residual solution, after the medical stone powder of loading metal ion obtained above is mixed with 2000g deionized water and 10g silica sol, stir 2h, Prepare a composite slurry; inject the prepared composite slurry into a metal tube with a rotational speed of 15,000 rpm, rotate for 15 minutes, and centrifuge to form a composite ultrafiltration membrane tube green body; the green body is demoulded after drying, and the Under reduction, microwave sintering, the sintering temperature is 1400°C, heat preservation for 2 hours, and after cooling, a composite ultrafiltration tube membrane filter element is made. Its pore diameter is 100 nm, its porosity is 40%, its diameter is 40 m...
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