A thermal magnesium smelting process

A process and method of magnesium, applied in the field of thermal magnesium smelting process, can solve the problems of complex operation, waste of equipment investment, labor, etc., and achieve the effect of eliminating calcination system, reducing waste of raw materials and unique process method.

Inactive Publication Date: 2011-12-14
开泰镁业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] (1) In the calcination kiln, the raw material containing magnesium carbonate is directly burned by the direct heating of the fuel, that is, the flame and the flue gas directly burn the raw material to decompose CO 2 , the CO emitted by its calcination 2 It is mixed with gas and smoke generated by fuel combustion, not pure single-component CO 2 Gas, which is not conducive to its comprehensive utilization and treatment, is usually directly discharged into the atmosphere, forming a greenhouse gas effect;
[0005] (2) The carbon dioxide produced after calcination in the calciner kiln does not contain CO 2 The raw materials will absorb moisture and CO in the air during storage, transportation and briquetting. 2 Combination into the state of magnesium carbonate before calcination causes the reduction of the active ingredients of the raw materials in the subsequent reduction process and reduces the magnesium production rate of the reduction process;
[0006] (3) Due to the consideration of flue gas permeability and other factors during the calcination process, there are certain requirements for the particle size of magnesium carbonate-containing ore raw materials, and finely crushed magnesium carbonate-containing ores smaller than a certain size cannot be used as raw materials for magnesium smelting;
[0007] (4) Calcination and reduction are completed twice in two sets of equipment, and the calcination system is huge in equipment, complicated in operation, energy consumption accounts for about half of the energy consumption of the whole plant, and the storage and transportation process of raw materials is long, causing energy, raw materials, Significant waste of labor, especially equipment investment

Method used

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Examples

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Embodiment 1

[0025] A thermal magnesium smelting process whose ore raw material is dolomite CaCO 3 .MgCO 3 or magnesite MgCO 3 and limestone CaCO 3 The mixture, the reducing agent is ferrosilicon: the alloy FeSi of silicon and iron, which contains a certain proportion of active silicon, and the catalyst is fluorite CaF 2 .

[0026] First, the ore raw material containing magnesium carbonate, reducing agent, and fluorite catalyst are crushed, mixed according to the reasonable ratio required for the reduction reaction, and ground into a powder with a particle size of no more than 500 mesh, and then the mixed powder is extruded into a converted equivalent by a press Approximate walnut-shaped, pillow-shaped, ellipsoidal, spherical, cylindrical and other solid blocks with a diameter of no more than 100 mm, and the pressed pellets are placed in a closed reactor, and finally heated by the pellets , Exhaust, heat up, and vacuumize to produce magnesium metal.

[0027] The chemical reaction in t...

Embodiment 2

[0037] A thermal magnesium smelting process whose ore raw material is dolomite CaCO 3. MgCO 3 , or magnesite MgCO 3 and limestone CaCO 3 mixtures, or magnesite MgCO 3 , the reducing agent is coal, coke, petroleum coke, graphite and other carbon-rich substances, and the catalyst is fluorite CaF 2 .

[0038] First, the ore raw material containing magnesium carbonate, reducing agent, and fluorite catalyst are crushed, mixed according to the reasonable ratio required for the reduction reaction, and ground into a powder with a particle size of no more than 500 mesh, and then the mixed powder is extruded into a converted equivalent by a press Approximate walnut-shaped, pillow-shaped, ellipsoidal, spherical, cylindrical and other solid blocks with a diameter of no more than 100 mm, and the pressed pellets are placed in a closed reactor, and finally heated by the pellets , Exhaust, heat up, and vacuumize to produce magnesium metal.

[0039] When the raw material is dolomite, or ...

Embodiment 3

[0054] A thermal magnesium smelting process whose ore raw material is dolomite CaCO 3 .MgCO 3 , or magnesite MgCO 3 and limestone CaCO 3 mixtures, or magnesite MgCO 3 , the reducing agent is calcium carbide CaC 2 , the catalyst is fluorite CaF 2 .

[0055] First, the ore raw material containing magnesium carbonate, reducing agent, and fluorite catalyst are crushed, mixed according to the reasonable ratio required for the reduction reaction, and ground into a powder with a particle size of no more than 500 mesh, and then the mixed powder is extruded into a converted equivalent by a press Approximate walnut-shaped, pillow-shaped, ellipsoidal, spherical, cylindrical and other solid blocks with a diameter of no more than 100 mm, and the pressed pellets are placed in a closed reactor, and finally heated by the pellets , Exhaust, heat up, and vacuumize to produce magnesium metal.

[0056] When the raw material is dolomite, or magnesite MgCO 3 and limestone CaCO 3 When the m...

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Abstract

The present invention relates to a magnesium smelting process, in particular to a thermal magnesium smelting process. The smelting process comprises the following steps: first, the ore raw material containing magnesium carbonate, the reducing agent, and the fluorite catalyst are crushed, and a reasonable Proportionally mixed and ground into powder, then the mixed powder is extruded into agglomerates with a press, and the pressed pellets are placed in a closed reactor, and finally the balls are heated, exhausted, and heated , vacuuming to produce metal magnesium; the invention has unique process method, good environmental protection effect and high utilization rate of raw materials.

Description

technical field [0001] The invention relates to a magnesium smelting process, in particular to a thermal magnesium smelting process. Background technique [0002] The traditional thermal magnesium smelting process is as follows: one is to crush the raw material containing magnesium carbonate into a certain particle size → add it to the calciner kiln for calcination to decompose and discharge CO 2 → will not contain CO after calcination 2 The raw materials, reducing agent and fluorite catalyst are uniformly mixed, ground into powder → pressed into pellets → loaded into the reducer → heated to reduce magnesium vapor → cooled magnesium vapor to obtain solid or liquid magnesium; the other is magnesium carbonate containing The ore raw material is crushed into a certain particle size → put into the calciner kiln for calcining and decomposing to discharge CO 2 → will not contain CO after calcination 2 The raw materials, reducing agent, and fluorite catalyst are ground into powde...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B26/22C22B5/02
Inventor 张少军
Owner 开泰镁业有限公司
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