Copolyester staple fiber and preparation method thereof
A copolyester and polyester technology, which is applied in the field of atmospheric pressure disperse dyeable copolyester staple fibers, copolyester staple fibers and their manufacturing fields, can solve difficult spinning, poor fiber physical properties, and poor heat resistance. and other problems, to achieve the effect of good dyeing performance, simple and easy production method, and good heat resistance performance.
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Embodiment 1
[0034] Add bishydroxyethyl terephthalate into the esterification reaction tank, keep the temperature at 250°C and the pressure at 1.2×10 5 Pa, the high-purity terephthalic acid of 8.25kg and the ethylene glycol slurry of 3.54kg are gradually added to the esterification reaction layer in 4 hours, then carry out the esterification reaction of 1 hour, finally from the esterification reactant obtained 10.2kg was taken and added to the polycondensation reaction layer.
[0035] The esterification reaction product was kept at 250° C. under normal pressure, and 2-methyl-1,3 propanediol was added in an amount corresponding to 10 mol% of all diols in the obtained polyester and stirred for 30 minutes. Then add phosphoric acid with a phosphorus atomic weight equivalent to 18 ppm of the polymer, 5 minutes later add antimony trioxide with an antimony atomic weight equivalent to 230 ppm of the polymer, and cobalt acetate with a cobalt atomic weight equivalent to 15 ppm of the polymer. After...
Embodiment 2
[0049] Select to add PEG10003wt% in the copolyester described in Example 1 and make 2-methyl-1,3 propanediol content is 9.2mol%, length is 38mm short fiber, after spinning into 45 yarns according to Example 1 After dyeing the tubular knitted fabric by the method, when the dyestuff is 0.3owf%, the L value is 35, and the color fastness to light is above grade 4. When the dye is 5owf%, the L value is 22, and the washing fastness is grade 4. Adding PEG can effectively improve the dyeability during normal pressure dyeing.
Embodiment 3
[0051] Through the slice preparation method described in Example 1, the esterification reaction product is kept at 250°C and under normal pressure, and 2-methyl-1,3-propanediol equivalent to 21mol% of all diols in the obtained polyester is added At a spinning temperature of 280°C, a cross-section spinneret is used, melt spinning, winding, winding, balance clustering, guide wire, pre-stretching, oiling, and then crimping, cutting, and packaging after one pass Obtained 2-methyl-1, the content of 3 propanediol is 19.8mol%, fineness is 1.5dtex, and length is 38mm cross section short fiber, obtains 45 yarns through spinning, dyeing method 95 ℃ × by the described embodiment 1 Dyeing under the condition of 30min, when the dye is 0.3owf%, the L value of the tubular knitted fabric is 32, and the light fastness is grade 4; when the dye is 5owf%, the L value is 21, and the washing fastness is above grade 4.
[0052] Without the addition of 2-methyl-1,3 propanediol equivalents, the dyeing...
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