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Preparation method of composite ordered porous nanometer titanium dioxide (TiO2) film

A nano-titanium dioxide and thin film technology, applied in the field of dye-sensitized solar cells, can solve problems such as electron-hole recombination, achieve the effects of large specific surface area, inhibit electron-hole recombination, and increase adsorption capacity

Inactive Publication Date: 2012-06-06
惠州市惠阳皇磁陶瓷有限公司
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  • Application Information

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Problems solved by technology

However, the structure of the porous film has a great influence on the performance of the battery, especially the serious electron-hole recombination in the disordered structure, which is limited to the influence of different preparation methods on the structure of the porous film and the impact of TiO 2 Larger forbidden band width, the above technology still has certain limitations

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  • Preparation method of composite ordered porous nanometer titanium dioxide (TiO2) film
  • Preparation method of composite ordered porous nanometer titanium dioxide (TiO2) film
  • Preparation method of composite ordered porous nanometer titanium dioxide (TiO2) film

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Embodiment Construction

[0024] Below in conjunction with example and accompanying drawing, the present invention is described in further detail.

[0025] Preparation of polystyrene microsphere emulsion and assembly of polystyrene microsphere colloidal crystal template: Pour styrene into a separatory funnel, wash it four times with 0.1M NaOH solution and secondary deionized water to remove inhibition Add 40mL of secondary deionized water and 0.0125g of sodium dodecylbenzenesulfonate into a 100mL four-necked flask, stir to dissolve, heat the water bath to 78°C, and then pass in nitrogen, then add 0.04g of NaHCO 3 and 10mL of washed styrene monomer; continue to heat and reflux and stir for 1 hour, and 0.1gK 2 S 2 o 8 Dissolve it in 10mL of secondary deionized water and drop it into a flask, control the temperature at (78±2)°C, heat to reflux and stir to react for 12 hours, then stop the reaction to obtain a polystyrene microsphere emulsion with a particle size of 450nm.

[0026] Using FTO conductive ...

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Abstract

The invention discloses a preparation method of a composite ordered porous nanometer titanium dioxide (TiO2) film. The method comprises the following steps: synthesizing a polystyrene microsphere emulsion and assembling a polystyrene microsphere colloidal crystal template; preparing a modified sol-gel doping precursor body; using a sol-gel dip-coating method to prepare a composite ordered porous nanometer TiO2 film. The invention provides the anatase phase composite porous TiO2 film with doping modification, an ordered structure and a high specific surface area, wherein the film is prepared by the PS colloidal crystal template and through a sol-gel process. The film can be applied in a DSSC.

Description

technical field [0001] The invention relates to dye-sensitized solar cell technology in the field of solar photoelectric utilization, in particular to a method for preparing a nanocomposite ordered porous electrode of a dye-sensitized solar cell. Background technique [0002] With the continuous development of economy and society, energy crisis and environmental pollution have become serious challenges to the survival and development of all human beings. Dye-sensitized solar cells (DSSCs) have become an important research direction due to their high photoelectric conversion efficiency, low cost, and simple process. Among them, porous titanium dioxide (TiO 2 ) nanocrystalline film-based DSSC has achieved a photoelectric conversion efficiency of 11%. [0003] The core part of the dye-sensitized solar cell is a nanocrystalline film. Porous films with a large specific surface area are commonly used at home and abroad to increase the adsorption amount of dyes and improve the abs...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/04H01G9/048H01G9/20H01M14/00H01L51/42H01L51/44H01L51/48
CPCY02E10/542Y02E10/549
Inventor 周艺朱志平李宏
Owner 惠州市惠阳皇磁陶瓷有限公司
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