Flotation two-stage desiliconization method for high-silicon bauxite

A high-silicon bauxite and bauxite technology, applied in flotation, solid separation, etc., can solve the problems affecting the recovery rate of concentrate, fine particle size of embedding, easy grinding, etc., to improve flotation index and flotation rate, reduction of silica content, and the effect of high-efficiency enrichment and recovery

Active Publication Date: 2013-11-27
山西道尔铝业有限公司
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Problems solved by technology

my country's bauxite has high aluminum, high silicon, and most of the aluminum-containing minerals are diaspore, which is hard, hard to grind, fine-grained, and has many types of silicon-containing minerals (kaolinite, illite, pyrophyllite etc.) and low hardness, low density, easy to grind, etc., the ore dressing and desiliconization process used for it mainly includes one-stage grinding and one-time flotation and stage grinding and one-time flotation, etc. During the ore grinding process, these processes often lead to Silicon-containing minerals are over-crushed and muddied, resulting in the entrainment and floating of silicon-containing fine-grained gangue during the flotation process, and the desiliconization effect is poor, which affects the recovery rate of concentrate

Method used

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  • Flotation two-stage desiliconization method for high-silicon bauxite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) First, the Ludian bauxite in Zhaotong, Yunnan Province (the main component of bauxite is Al 2 o 3 60.50wt%, SiO 2 18.68wt%, TiO 2 2.06wt%, Fe 2 o 3 0.55wt%, CaO 0.55wt%, MgO 0.52wt%, K 2 O 3.17 wt%, Na 2 O 0.10%, aluminum-silicon ratio 3.24, aluminum-containing minerals are mainly diaspore, silicon-containing minerals are mainly kaolinite, illite, chlorite, pyrophyllite, quartz, muscovite, etc.) The raw ore is crushed and screened to - 2mm, then coarsely grind it until the particle size is -0.074mm, accounting for 75 wt%, add water to adjust the pulp concentration to 35 wt%, then add 5000g / t sodium carbonate to the pulp once, adjust the pH value to 8, and then add water in turn 500g / t of glass, 300g / t of sodium hexametaphosphate, 200g / t of lead acetate, 900g / t of sodium oleate, 20g / t of pine oil are used for pulping. The foam obtained by selecting I is bauxite coarse concentrate, and the underflow in the tank passes through roughing II in (2) as follows; ...

Embodiment 2

[0028] (1) Firstly, the bauxite of Zunyi Bauxite in Guizhou Province (the main component of bauxite is Al 2 o 3 56.70wt%, SiO 2 17.32wt%, TiO 2 2.31wt%, Fe 2 o 3 0.95wt%, CaO 0.45wt%, MgO 0.76wt%, K 2 O 2.18wt%, Na 2 O 0.32%, aluminum-silicon ratio 3.27, aluminum-containing minerals are mainly diaspore, silicon-containing minerals are mainly kaolinite, illite, chlorite, pyrophyllite, quartz, muscovite, etc.) The raw ore is crushed and screened to - 2mm, then roughly grind it until the particle size is -0.074mm, accounting for 70 wt%, add water to adjust the pulp concentration to 33 wt%, then add 5500g / t sodium carbonate to the pulp once, adjust the pH value to 8.7, and then add water in turn Glass 550g / t, sodium hexametaphosphate 330g / t, lead acetate 260g / t, sodium oleate 1000g / t, pine oil 15g / t for pulping, after pulping, carry out flotation for a stage of desiliconization roughing I, roughing The foam obtained by selecting I is bauxite coarse concentrate, and the ...

Embodiment 3

[0034] (1) First, bauxite from Tiandong Bauxite Mine in Guangxi (the main component of bauxite is Al 2 o 3 62.20wt%, SiO 2 18.30wt%, TiO 2 2.47wt%, Fe 2 o 3 1.43wt%, CaO 0.37wt%, MgO 0.68wt%, K 2 O1.20wt%, Na 2 O 0.22%, aluminum-silicon ratio 3.40, aluminum-containing minerals are mainly diaspore, silicon-containing minerals are mainly kaolinite, illite, chlorite, pyrophyllite, quartz, muscovite, etc.) The raw ore is crushed and screened to - 2mm, then roughly grind it until the particle size is -0.074mm, accounting for 72 wt%, add water to adjust the pulp concentration to 30 wt%, then add 6000g / t sodium carbonate to the pulp once, adjust the pH value to 9, and then add water in turn Glass 600g / t, sodium hexametaphosphate 500g / t, lead acetate 300g / t, sodium oleate 800g / t, pine oil 10g / t for pulping, and after pulping, carry out flotation for a stage of desiliconization. The foam obtained by selecting I is bauxite coarse concentrate, and the underflow in the tank pas...

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Abstract

The invention relates to a flotation two-stage desiliconization method for high-silicon bauxite, which is a flotation desiliconization technology for bauxite and belongs to the technical field of mineral processing engineering. The method comprises the following steps of: coarsely grinding the bauxite into particles with certain fine granularity; under the condition of a certain ore pulp concentration, performing flotation first-stage desiliconization by using sodium carbonate as a pH regulator and a dispersing agent of the ore pulp, water glass and sodium hexametaphosphate as a combined inhibitor of gangue mineral, lead acetate as an activating agent of the bauxite, sodium oleate as a collector of the bauxite and pine oil as a foaming agent, wherein the base flow in a flotation groove is a section of silicon-containing tailings; allowing foam products to enter a grinding machine and grinding the foam products into particles with fine granularity; adding the medicaments sequentially and mixing pulp; performing flotation second-stage desiliconization, wherein the base flow in the flotation groove is a section of silicon-containing tailings; and selecting the foaming products for multiple times to form bauxite concentrate. The sectional desiliconization method for 'flotation first-stage desiliconization after coarse grinding and flotation second-stage desiliconization after regrinding rough concentrate' is utilized, so the influence of ore argillization phenomenon on desiliconization is greatly reduced, the flotation desiliconization effect on the high-silicon bauxite is obvious, the silicon dioxide content of the bauxite concentrate can be reduced greatly, the ratio of aluminum to silicon of the bauxite concentrate is increased, and the recovery rate is high.

Description

technical field [0001] The invention relates to a two-stage desiliconization method of high-silicon bauxite flotation, belonging to the field of mineral processing engineering. Background technique [0002] A high aluminum-silicon ratio is the most important requirement for the quality of bauxite in the alumina industry and the refractory industry. With the rapid development of alumina and refractory materials industry, high-quality bauxite resources with low silicon content are decreasing day by day, and the beneficiation of poor-quality high-silicon bauxite has attracted widespread attention at home and abroad. More than 80% of my country's bauxite resources are bauxite with high silicon content. Therefore, desiliconization and obtaining high-aluminum-silicon ratio concentrates are the main purposes of my country's bauxite beneficiation. [0003] The flotation desiliconization method is currently researched and applied more, and it is also a more effective method. my cou...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B03D1/018B03D101/02B03D101/04B03D101/06
Inventor 谢海云周平庄故章高利坤姜亚雄
Owner 山西道尔铝业有限公司
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