Polyether polyol system for external wall spraying and preparation method

A combination of polyether and low-density technology, applied in the field of polyurethane foam, can solve the problems of unsatisfactory application, high production cost, and large change in dimensional stability, and achieve high labor production efficiency, flexible and convenient construction, and high dimensional change rate small effect

Inactive Publication Date: 2014-03-26
绍兴广佳庄鑫建材制造有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. Market participants have insufficient knowledge of polyurethane insulation materials for construction, and their concepts lag behind;
[0005] 2. The spray foam used in domestic building exterior wall insulation requires a density greater than 34kg / m3, and the production cost is high, which restricts its development and application;
[0006] 3. The dimensional stability of polyurethane exterior wall spray foam with low density varies greatly, and the thermal conductivity is relatively high. The existing technology still cannot meet its application in this field

Method used

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  • Polyether polyol system for external wall spraying and preparation method

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Embodiment Construction

[0032] A low-density exterior wall spraying assembly polymer, which consists of the following parts by weight:

[0033] Polyether polyol Ⅰ is 10-40 parts,

[0034] Polyether polyol II is 0-50 parts,

[0035] Polyether polyol Ⅲ is 0-50 parts,

[0036] 15-30 parts of polyether polyol IV,

[0037] Catalyst I is 0.6-4 parts,

[0038] Catalyst III is 0~2 parts,

[0039] Catalyst IV is 0-10 parts,

[0040] Catalyst V is 0 to 1 part,

[0041] Silicone oil I is 0-5 parts,

[0042] Additive flame retardant is 10~35 parts,

[0043] 2.6-10 parts of water,

[0044] The blowing agent HCFC-141b is 36-150 parts,

[0045] Said polyether polyol I uses ethylene diamine as an initiator, propylene oxide and ethylene oxide are polymerized, and has a functionality of 4 and a hydroxyl value of 700-900 mgKOH / g; polyether polyol II uses sucrose, two Glycol is the starter, propylene oxide is polymerized, and its functionality is 6, and the hydroxyl value is 300-450mgKOH / g; polyether polyol Ⅲ uses sorbitol as the initia...

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Abstract

The invention relates to a low-density conjugate polyether for external wall spraying. The low-density conjugate polyether comprises the following components in parts by weight: 10-40 parts of polyether polyol I, 0-50 parts of polyether polyol II, 0-50 parts of polyether polyol III, 15-30 parts of polyether polyol IV, 0.6-4 parts of catalyst I, 0-2 parts of catalyst III, 0-10 parts of catalyst IV, 0-1 part of catalyst V, 0-5 parts of silicone oil I, 10-35 parts of additive flame retardant, 2.6-10 parts of water and 36-150 parts of HCFC-141b (Hydrochlorofluorocarbon-141b). The preparation method for the low-density conjugate polyether comprises the following step of: putting the raw materials into a container in percentage by weight and uniformly stirring to obtain the low-density conjugate polyether for the external wall spraying. The shaping density of rigid polyurethane foaming plastic prepared from the low-density conjugate polyether is 25-34kg / m<3>, and the rigid polyurethane foaming plastic can maintain excellent thermal insulation properties and dimension stability and has a self-quenching function. The low-density conjugate polyether has the advantages of flexibility and convenience in construction and low cost, conforms to the requirements of energy conservation, emission reduction, safety, environmental protection of China and is an ideal material of the external wall thermal insulation field.

Description

Technical field: [0001] The invention relates to the technical field of polyurethane foam, and more specifically to a rigid polyurethane foam with a molding density of 25~34kg / m 3 It is the raw material for spraying rigid polyurethane plastic foam on the exterior wall and its preparation method, which maintains excellent thermal insulation performance and dimensional stability. Background technique: [0002] At present, the materials used for building exterior walls are mainly foamed polystyrene board (EPS board) exterior wall exterior insulation system, mechanically fixed foamed polystyrene board steel wire mesh frame board exterior wall exterior insulation system, and rubber powder polystyrene particle exterior wall exterior insulation system. Thermal insulation system, foamed polystyrene board cast-in-place concrete external wall external thermal insulation system, extruded polystyrene board (XPS board) external wall external thermal insulation system, rubber powder polystyrene...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/48C08G18/32C08J9/14
Inventor 山柏芳李志生徐胜戴静波
Owner 绍兴广佳庄鑫建材制造有限公司
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