Flame-retardant polyacrylate emulsion and preparation method thereof

A technology of polyacrylate and isooctyl acrylate, applied in the direction of adhesive types, ester copolymer adhesives, adhesive additives, etc., can solve the problems of limited flame retardant effect, difficulty in implementation, and high cost, and achieve Conducive to stability, high cost solution, and reduced dosage

Inactive Publication Date: 2012-07-25
SHANGHAI APPLIED TECHNOLOGIES COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Adding reactive flame retardants is difficult to implement due to high cost
Adding flame retardants is widely used because of low cost and convenient op

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0048] Example 1

[0049] A flame-retardant polyacrylate latex, calculated in parts by weight, composed of 100 parts of polyacrylate latex and 31.6 parts of flame retardant;

[0050] The said polyacrylate latex is calculated in parts by weight, and its raw material composition and content are as follows:

[0051] 5.13 parts of isooctyl acrylate (16kg)

[0052] 24.39 parts of butyl acrylate (76kg)

[0053] 3.85 parts of methyl methacrylate (12kg)

[0054] 1.93 parts of methacrylic acid (6kg)

[0055] 1.28 parts of acrylic acid (4kg)

[0056] Styrene 2.57 parts (8kg)

[0057] Functional monomer 1.93 parts (6kg)

[0058] Reactive emulsifier 0.77 parts (2.4kg)

[0059] Emulsifier OP 0.19 parts (0.6kg)

[0060] 0.19 parts of ammonium persulfate (0.6kg)

[0061] 57.77 parts of deionized water (180kg)

[0062] The functional monomer is hydroxyethyl acrylate;

[0063] The reactive emulsifier is allyl polyoxyethylene ether ammonium sulfate.

[0064] The flame re...

Example Embodiment

[0074] Example 2

[0075] A flame-retardant polyacrylate latex, calculated in parts by weight, consisting of 100 parts of polyacrylate latex and 6.76 parts of flame retardant;

[0076] The said polyacrylate latex is calculated in parts by weight, and its raw material composition and content are as follows:

[0077] 0.66 parts of isooctyl acrylate (1kg)

[0078] 15.23 parts of butyl acrylate (23kg)

[0079] 19.87 parts of methyl methacrylate (30kg)

[0080] 0.53 parts of methacrylic acid (0.8kg)

[0081] 4.64 parts of acrylic acid (7kg)

[0082] Styrene 23.18 parts (35kg)

[0083] Functional monomer 3.31 parts (5kg)

[0084] 1.33 parts of reactive emulsifier (2kg)

[0085] Emulsifier OP 0.46 parts (0.7kg)

[0086] 0.33 parts of ammonium persulfate (0.5kg)

[0087] 30.46 parts of deionized water (46kg)

[0088] The functional monomer is diglycidyl methacrylate;

[0089] The reactive emulsifier is 2-acrylamido-2-methyl-propyl ammonium sulfonate;

[0090] T...

Example Embodiment

[0099] Example 3

[0100] A flame-retardant polyacrylate latex, calculated in parts by weight, consisting of 100 parts of polyacrylate latex and 12 parts of flame retardant;

[0101] The said polyacrylate latex is calculated in parts by weight, and its raw material composition and content are as follows:

[0102] 9.38 parts of isooctyl acrylate (16kg)

[0103] 15.24 parts of butyl acrylate (26kg)

[0104] 2.34 parts of methyl methacrylate (4kg)

[0105] 4.69 parts of methacrylic acid (8kg)

[0106] 0.59 parts of acrylic acid (1kg)

[0107] Styrene 2.93 parts (5kg)

[0108] Functional monomer 8.79 parts (15kg)

[0109] 0.12 part of reactive emulsifier (0.2kg)

[0110] Emulsifier OP 1.17 parts (2kg)

[0111] 0.24 parts of ammonium persulfate (0.4kg)

[0112] 54.51 parts of deionized water (93kg)

[0113] The functional monomer is N-methylol acrylamide;

[0114] The reactive emulsifier is sodium p-styrene sulfonate;

[0115] The flame retardant is an intum...

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Abstract

The invention discloses a flame-retardant polyacrylate emulsion and a preparation method thereof. The flame-retardant polyacrylate emulsion consists of 100 parts of polyacrylate emulsion and 5-35 parts of flame retardant by weight parts, wherein the polyacrylate emulsion consists of ethylhexyl acrylate, butyl acrylate, methyl methacrylate, methacrylic acid, crylic acid, functional monomer, reaction emulsifier, emulsifier OP, ammonium persulfate and deionized water; the flame retardant consists of carbonized catalyst, carbonizer and expanding agent. The preparation method of the flame-retardant polyacrylate emulsion includes: utilizing the combined process of pre-emulsifying and seeding polymerizing and adding expansion flame retardant. The flame-retardant polyacrylate emulsion prepared by the preparation method has excellent flame retardancy, adhesivity, filming ability and stability and excellent waterproofness, and can be widely used in the industries of adhesives and coatings and the like.

Description

technical field [0001] The invention relates to a flame-retardant polyacrylate latex and a preparation method thereof, which mainly solves the flame-retardant problem of polyacrylate latex, relates to the formula and process of polyacrylate latex polymerization, the composition, proportion and dosage of flame retardants, etc. content. Background technique [0002] Polyacrylate latex is the product of emulsion polymerization of acrylate or methacrylate and other vinyl ester monomers. Currently the most widely used are (meth)acrylate copolymer emulsion, vinyl acetate / (meth)acrylate copolymer emulsion, styrene / (meth)acrylate copolymer emulsion. The emulsion polymerization process generally includes batch emulsion polymerization, semi-continuous emulsion polymerization, continuous emulsion polymerization, pre-emulsification process, seed emulsion polymerization, etc. Because acrylate copolymer emulsions overcome the shortcomings of oily copolymers that are flammable, explosive...

Claims

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Application Information

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IPC IPC(8): C09J133/08C09J11/04C09J11/06C09J11/08C08F220/18C08F212/08C08F220/14C08F220/06C08F220/32C08F220/28C08F220/58C08F2/26
Inventor 黄剑清潘安健
Owner SHANGHAI APPLIED TECHNOLOGIES COLLEGE
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