Quaternary composite carbon conductive agent and preparation method thereof
A conductive agent and composite carbon technology, which is applied in cable/conductor manufacturing, conductive materials dispersed in non-conductive inorganic materials, circuits, etc., can solve the problems of low conductivity, poor dispersion, high addition ratio, etc., and achieve high specific surface area , excellent electrical conductivity, the effect of low addition ratio
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Embodiment 1
[0025] This embodiment illustrates according to a kind of quaternary composite carbon conductive agent of the present invention and preparation method thereof:
[0026] Evenly mix 23 grams of conductive carbon black with a screening particle size finer than 200 meshes and 23 grams of flake graphite, put it into a microwave oven with a power of 2500W, heat it with microwave discharge in a nitrogen atmosphere for 18 minutes, take out the microwave discharge product after cooling, and add polyethylene 8 grams of pyrrolidine, 46 grams of polyvinylidene fluoride, and 200 grams of N-methylpyrrolidone are put into a stirring ball mill and carried out stirring ball milling. The process conditions during stirring ball milling are: the abrasive ratio is 5: 1, and the ball milling speed is 550 rpm. minutes, and the ball milling time is 2.5 hours, and finally a quaternary composite carbon conductive agent composed of carbon black, carbon nanofibers, graphite and quasi-two-dimensional nanoc...
Embodiment 2
[0033] This embodiment illustrates according to a kind of quaternary composite carbon conductive agent of the present invention and preparation method thereof:
[0034] Evenly mix 75 grams of conductive carbon black with a screening particle size finer than 200 meshes and 15 grams of flake graphite, put it into a microwave oven with a power of 5000W, and heat it with microwave discharge in a nitrogen atmosphere for 2 minutes. After cooling, take out the microwave discharge product and add alkane 4 grams of phenol polyoxyethyl alcohol, 90 grams of polytetrafluoroethylene, and 400 grams of dehydrated alcohol are put into a stirring ball mill and carried out stirring ball milling. The process conditions during stirring ball milling are: the abrasive ratio is 10: 1, and the ball milling speed is 1000 revolutions per minute and ball milling time of 5 hours, and finally a quaternary composite carbon conductive agent composed of carbon black, carbon nanofibers, graphite and quasi-two-...
Embodiment 3
[0041] This embodiment illustrates according to a kind of quaternary composite carbon conductive agent of the present invention and preparation method thereof:
[0042] Evenly mix 3 grams of conductive carbon black with particle size finer than 200 mesh and 15 grams of flake graphite, put it into a microwave oven with a power of 500W, and heat it with microwave discharge in a nitrogen atmosphere for 60 minutes. After cooling, take out the product of microwave discharge discharge, add 9 grams of polyvinylpyrrolidone, 9 grams of polytetrafluoroethylene, 9 grams of sodium carboxymethyl cellulose, 15 grams of N-methylpyrrolidone, and 15 grams of isopropanol were put into a stirring ball mill and carried out stirring ball milling, and stirring ball milling was carried out for 30 minutes. The process conditions are as follows: the abrasive ratio is 1:1, the ball milling speed is 100 rpm, and the ball milling time is 2000 hrs. Finally, a quaternary composite carbon conductive agent co...
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