Quaternary composite carbon conductive agent and preparation method thereof

A conductive agent and composite carbon technology, which is applied in cable/conductor manufacturing, conductive materials dispersed in non-conductive inorganic materials, circuits, etc., can solve the problems of low conductivity, poor dispersion, high addition ratio, etc., and achieve high specific surface area , excellent electrical conductivity, the effect of low addition ratio

Inactive Publication Date: 2012-07-25
湖南楚有材新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Due to the low conductivity of the electrode materials of most high-performance batteries, the internal resistance of the entire electrode increases, the utilization rate of active materials is low, and the overall performance decreases. A certain amount of conductive agent can increase its conductivity, but the current common conductive agents have disadvantages such as low specific surface area, poor dispersion, high addition ratio, and insufficient conductivity.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] This embodiment illustrates according to a kind of quaternary composite carbon conductive agent of the present invention and preparation method thereof:

[0026] Evenly mix 23 grams of conductive carbon black with a screening particle size finer than 200 meshes and 23 grams of flake graphite, put it into a microwave oven with a power of 2500W, heat it with microwave discharge in a nitrogen atmosphere for 18 minutes, take out the microwave discharge product after cooling, and add polyethylene 8 grams of pyrrolidine, 46 grams of polyvinylidene fluoride, and 200 grams of N-methylpyrrolidone are put into a stirring ball mill and carried out stirring ball milling. The process conditions during stirring ball milling are: the abrasive ratio is 5: 1, and the ball milling speed is 550 rpm. minutes, and the ball milling time is 2.5 hours, and finally a quaternary composite carbon conductive agent composed of carbon black, carbon nanofibers, graphite and quasi-two-dimensional nanoc...

Embodiment 2

[0033] This embodiment illustrates according to a kind of quaternary composite carbon conductive agent of the present invention and preparation method thereof:

[0034] Evenly mix 75 grams of conductive carbon black with a screening particle size finer than 200 meshes and 15 grams of flake graphite, put it into a microwave oven with a power of 5000W, and heat it with microwave discharge in a nitrogen atmosphere for 2 minutes. After cooling, take out the microwave discharge product and add alkane 4 grams of phenol polyoxyethyl alcohol, 90 grams of polytetrafluoroethylene, and 400 grams of dehydrated alcohol are put into a stirring ball mill and carried out stirring ball milling. The process conditions during stirring ball milling are: the abrasive ratio is 10: 1, and the ball milling speed is 1000 revolutions per minute and ball milling time of 5 hours, and finally a quaternary composite carbon conductive agent composed of carbon black, carbon nanofibers, graphite and quasi-two-...

Embodiment 3

[0041] This embodiment illustrates according to a kind of quaternary composite carbon conductive agent of the present invention and preparation method thereof:

[0042] Evenly mix 3 grams of conductive carbon black with particle size finer than 200 mesh and 15 grams of flake graphite, put it into a microwave oven with a power of 500W, and heat it with microwave discharge in a nitrogen atmosphere for 60 minutes. After cooling, take out the product of microwave discharge discharge, add 9 grams of polyvinylpyrrolidone, 9 grams of polytetrafluoroethylene, 9 grams of sodium carboxymethyl cellulose, 15 grams of N-methylpyrrolidone, and 15 grams of isopropanol were put into a stirring ball mill and carried out stirring ball milling, and stirring ball milling was carried out for 30 minutes. The process conditions are as follows: the abrasive ratio is 1:1, the ball milling speed is 100 rpm, and the ball milling time is 2000 hrs. Finally, a quaternary composite carbon conductive agent co...

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PUM

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Abstract

The invention discloses a quaternary composite carbon conductive agent, which mainly comprises carbon black, carbon nano-fibers, graphite and quasi-two-dimensional nano carbon. The preparation method of the quaternary composite carbon conductive agent mainly includes the steps: mixing the carbon black and the graphite to form carbon-containing mixture and performing microwave discharge under the protection of nitrogen to generate a conductive agent head product with parts of the carbon nano-fibers; adding dispersing agents, adhesives and solvents into the conductive agent head product to perform wet stirring and ball milling; and obtaining the quaternary composite carbon conductive agent. The quaternary composite carbon conductive agent has the advantages of high conductivity, large specific surface area, high purity, high dispersibility, low addition ratio and the like, the conductivity is higher than 10S/cm, the specific surface area can reach 40 (m2/g), the ash content is lower than 0.02%, and the addition ratio can be generally smaller than 2%. The quaternary composite carbon conductive agent has excellent conductivity, can be sufficiently dispersed in an electrode and can be used for a high-performance battery.

Description

technical field [0001] The invention relates to a battery electrode material and a preparation method thereof, in particular to the technical field of an electrode conductive material and a preparation method thereof. Background technique [0002] Energy crisis, exhaustion of petrochemical resources, it is imminent to find alternative energy sources and increase the development and utilization of renewable energy. High-performance energy storage batteries are one of the key components of renewable energy generation systems such as solar photovoltaic power generation systems and wind power generation systems. It is not only related to the power quality of solar and wind power generation, but also has a decisive impact on the cost of the generated electricity, which in turn affects whether solar and wind power generation technology can really enter thousands of households; the intensification of environmental protection pressure and the promotion of low-carbon economy , has pu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B13/00H01B1/24H01M4/62
CPCY02E60/12Y02E60/10
Inventor 梁逵胡军叶江海
Owner 湖南楚有材新材料科技有限公司
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