Rare earth permanent magnet and preparation method thereof

Abstract

Disclosed are a rare earth permanent magnet and a preparation method. The preparation method of the rare earth permanent magnet is capable of improving coercivity of the magnet while keeping binding strength of a base body and a plated layer or coated layer after plating or coating on the basis without reducing remanence and magnetic energy product of the magnet and includes: firstly dissolving powder of fluoride containing R2, nitrate containing R3 and phosphate containing R4 into water or alcohol to prepare solution; uniformly applying the solution on the surface of a magnet to be treated; then dewatering or performing alcohol treatment on the magnet to be treated; finally, enabling the magnet to be treated to be subjected to diffusion heat treatment to obtain the treated magnet. By the aid of the preparation method, uniformity of the powder on the surface of the magnet can be improved, powder residues on the surface of the magnet after heat diffusion are reduced, the coercivity of the magnet is improved, and the binding strength of the magnet of the base body and the plated layer or coated layer after plating or coating is kept constant.

Description

technical field [0001] The invention relates to a rare earth permanent magnet and a method for preparing the magnet. In particular, it relates to a rare earth permanent magnet that improves the bonding strength of the plating layer or coating and the substrate on the basis of increasing the coercive force of the magnet and the method for preparing the magnet. Background technique [0002] Rare earth permanent magnets have excellent magnetic properties. In recent years, they have been widely used in the fields of air-conditioning motors, hybrid vehicles and wind power generation. The use of magnets in these fields has to face high temperature and humid environments. in salty humidity. Therefore, not only magnets are required to have high magnetic properties, but also high corrosion resistance is required. [0003] The industry has done a lot of work to improve the magnetic properties of magnets. In recent years, in-depth research has been done on how to improve the coercive...

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Problems solved by technology

[0004] However, in this method, rare earth fluorides, oxides, and oxyfluorides will have uneven residues after thermal diffusion on the surface of the magnet. Although the surface is removed by acid / alkali treatment or sandblasting or processing in the later stage, due to the diffusion The depth is limited (according to the diffusion depth disclosed in Chinese Patent Application Publication No. CN1838342, the diffusion depth is about 20 μm or more), if too much skin is removed, the coercive force will increase little or not; if less skin is removed, the surface or near surface will be uneven The residue of fluorine, especially the residue of fluorine, has a great influence on the corrosion resistance of the magnet. Generally, the surface of the magnet is protected by plating or coating, but the magnet plating or coating obtained by diffusing rare earth Dy and Tb to the surface After that, there will often be a problem of poor bonding strength between the substrate and the coating or coating, which will affect the corrosion resistance of the magnet after coating or coating

And CN1898757 patent application does not have relevant expression to the corrosion resistance of magnet

[0005] The bonding strength between the substrate and the coating or coating is poor after the magnet is plated or coated by the method described in CN1898757. The reason is that when the powder is placed on the surface of the magnet, the powder is in water or organic solvent. The solubility is very poor, and it cannot be evenly distributed on the surface of the magnet. After thermal diffusion, there is a melt of unevenly distributed powder on the surface of the magnet.

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