Alkenyl succinic acid polyethylene glycol phosphate ester additive agent as metal rolling oil and preparation method

A technology of polyethylene glycol phosphate and oleyl alkenyl succinic acid, which is applied in the direction of additives, petroleum industry, lubricating compositions, etc., can solve problems such as complex formula system, dirty rolling mill, and scratched steel plate surface, and achieve Simple Effects of Recipe Technology

Active Publication Date: 2013-02-06
JINGJIANG HENGFENG CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But now the rolling oil using emulsifier is often controlled by changing the type and amount of emulsifier to control the metastability of the emulsion to adjust the amount of oil attached to the surface of the steel plate, and then control the rolling lubricity, but the metal rolling of this system The lubricating performance of the oil cannot meet the high lubricity required by the rolling of extremely thin steel plates with large deformation and large width, resulting in scratches on the surface of the steel plate, and even quality accidents such as broken strips of the steel plate
Therefore, it is necessary to improve and control the rolling lubricity by changing, adding lubricants, the type and amount of extreme pressure additives, because the addition of lubricants and extreme pressure additiv

Method used

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Examples

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Embodiment

[0019] 1) Synthesis of alkenyl maleic anhydride such as dodecenyl succinate monopolyethylene glycol

[0020] In a three-necked flask with a reflux condenser, add alkenyl maleic anhydride such as dodecenyl maleic anhydride 265 grams and 205 grams of polyethylene glycol with an average molecular weight of 200 in a nitrogen atmosphere, add dodecenyl 0.5% of the weight of maleic anhydride toluenesulfonic acid as a catalyst, and 10% of the total amount of xylene as a solvent, after stirring, the temperature is raised to 145-150 ° C, and the acid value of the reaction system is analyzed every 0.5 hours during the reaction until the acid value Until the value remains unchanged, the reaction time is 3-4 hours, and then the solution is decompressed to make the vacuum of the system reach 0.07-0.08Mpa, and the solvent xylene is evaporated, and the reaction product is used as the raw material for the next step reaction.

[0021] 2) Synthesis of alkenyl succinic acid polyethylene glyc...

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PUM

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Abstract

An alkenyl succinic acid polyethylene glycol phosphate ester additive agent as metal rolling oil comprises the following components: alkenyl maleic anhydride with appropriate alkyl, polyethylene glycol with appropriate degree of polymerization, phosphorus pentoxide and a catalyst, and is characterized by comprising the steps of: reacting the alkenyl maleic anhydride with appropriate alkyl and the polyethylene glycol with appropriate degree of polymerization under the action of the catalyst to generate alkenyl succinic acid mono-polyethylene glycol ester; and reacting the alkenyl succinic acid mono-polyethylene glycol ester and the phosphorus pentoxide to generate alkenyl succinic acid polyethylene glycol phosphate ester and bis-alkenyl succinic acid polyethylene glycol phosphate ester. The invention has the distinct advantages that the additive agent has emulsification, lubrication and extreme pressure properties and oil coke resistance function; the formulation technology of the metal rolling oil becomes simple, a large quantities of steel plates with large deformation values above 90 percent can be rolled at a high speed by adding 5-20 percent of the additive agent of the invention into the metal rolling oil, and the surfaces of the rolled steel plates have no scratch.

Description

technical field [0001] The invention relates to the field of lubricants, in particular to a metal rolling oil alkenyl succinic acid polyethylene glycol phosphate additive with emulsifying performance, lubricating performance, extreme pressure performance and oil coke resistance function and a preparation method. Background technique [0002] When cold-rolling steel sheets or strips, they must go through various processes such as pickling-cold rolling-cleaning-annealing-levelling-inspection. Generally, during cold rolling, the reduction rate of the rolled material is 40% to 90%, and the rolling load is also a high load of 800 tons to 1500 tons. Under such high load conditions, the rolling oil can act as a lubricant to prevent the direct contact between the roll and the material being rolled. The composition of general metal rolling oil is based on grease, mineral oil or fatty acid synthetic fat, etc., adding additives such as antirust agent, extreme pressure agent, oili...

Claims

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Application Information

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IPC IPC(8): C10M153/04C10M177/00C08G65/00C10N30/06C10N40/24
Inventor 韦利行任晓平赵洪
Owner JINGJIANG HENGFENG CHEM IND CO LTD
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