Preparation method for fiber-based activate core-shell micro-nano structure environment purifying material
A technology of micro-nano structure and environmental purification, applied in fiber treatment, light water/sewage treatment, textile and papermaking, etc., to achieve the effect of wide source, easy industrial production and convenient use
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Embodiment 1
[0042] (1) Wool fabric surface pretreatment
[0043]Ultrasonic cleaning of wool fabric (1g) with acetone for 30min, drying at 20°C for 10h, then treating in high-efficiency detergent Kieralon OL (Basf) solution at 40°C for 15min, drying at 80°C for 30min;
[0044] (2) Preparation of solution A
[0045] Under nitrogen atmosphere, take 0.005mol bismuth nitrate and 0.010mol edetate disodium into 50ml nitric acid solution (0.5mol / L) respectively, and drop Tween 80, a wetting agent 2% relative to the weight of the fabric, at 200rpm Stir for 30min, add 4gNaHCO 3 ;
[0046] Preparation of Solution B
[0047] Under a nitrogen atmosphere, take 0.005mol of sodium metavanadate and add it to 50ml of deionized water, stir at 200rpm for 5min, and add 10ml of sodium hydroxide solution (1.5mol / L) dropwise during the stirring process to obtain a clear solution;
[0048] (3) Preparation of unactivated photocatalyst
[0049] Add the above solution B to the above solution A dropwise, control...
Embodiment 2
[0059] (1) Cotton fabric surface pretreatment
[0060] Ultrasonic cleaning of cotton fabric (1g) with ethanol for 45min, drying at 30°C for 10h, then treating in the high-efficiency cleaning agent Span-one (Desang Chemical) solution at 45°C for 20min, drying at 80°C for 25min;
[0061] (2) Preparation of solution A
[0062] Under a nitrogen atmosphere, take 0.006mol of bismuth nitrate and 0.015mol of disodium edetate and add them to 50ml of nitric acid solution (1.0mol / L) respectively, and add 3% of the wetting agent Triton X-100 relative to the weight of the fabric dropwise, Stir at 200rpm for 30min, add 3g K 2 CO 3 ;
[0063] Preparation of Solution B
[0064] Under a nitrogen atmosphere, take 0.006mol of sodium metavanadate and add it to 50ml of deionized water, stir at 200rpm for 5min, and add 10ml of sodium hydroxide solution (0.5mol / L) dropwise during the stirring process to obtain a clear solution;
[0065] (3) Preparation of unactivated photocatalyst
[0066] Add...
Embodiment 3
[0076] (1) Surface pretreatment of linen fabric
[0077] Ultrasonic cleaning of linen fabric (1g) with acetone for 60min, drying at 30°C for 10h, then treating in high-efficiency detergent LS (Demei Chemical) solution at 45°C for 20min, drying at 80°C for 25min;
[0078] (2) Preparation of solution A
[0079] Under nitrogen atmosphere, take 0.006mol bismuth nitrate and 0.018mol edetate disodium into 50ml nitric acid solution (2.0mol / L) respectively, and add 5% wetting agent JFC (fatty alcohol poly Oxyethylene ether), stirred at 200rpm for 30min, added 4g Na 2 CO 3 ;
[0080] Preparation of Solution B
[0081] Under a nitrogen atmosphere, take 0.006mol of sodium metavanadate and add it to 50ml of deionized water, stir at 200rpm for 5min, and add 10ml of sodium hydroxide solution (1mol / L) dropwise during the stirring process to obtain a clear solution;
[0082] (3) Preparation of unactivated photocatalyst
[0083] Add the above solution B to the above solution A dropwise, ...
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