This invention provides a method for the resource-based regeneration of waste
tungsten based on low-temperature catalytic leaching, belonging to the technical field of waste
tungsten resource recycling. The method includes: collecting
tungsten waste, pre-treating it to obtain tungsten particles; adding a leaching agent and catalyst to the tungsten particles for low-temperature catalytic leaching, collecting the tungsten
leachate after
solid-liquid separation; adding
oxalic acid to adjust the pH to 2.5-4.0, allowing it to stand to remove
silicon and
phosphorus, then adding
sodium sulfide solution to remove
heavy metals, obtaining a pure tungsten solution after
solid-liquid separation; preparing
ammonium paratungstate or
tungsten trioxide from the pure tungsten solution; and performing staged reduction heat treatment to obtain regenerated tungsten
powder. The leaching agent is a mixture of
sodium hydroxide and
hydrogen peroxide; the catalyst is a mixture of
sodium metavanadate and
sodium carbonate. This invention covers the entire process of tungsten
waste recycling, pre-treatment, leaching, purification, product preparation, and
waste recycling, with each link working synergistically to form a closed-loop industrial chain, maximizing the utilization of waste tungsten resources and avoiding resource waste.