The invention relates to a composite decarburization solution for capturing carbon dioxide in mixed gas, belonging to the technical field of carbon dioxide gas capture. It relates to a composite decarburization solution, which is composed of solvent benzyl alcohol, phenyl alcohol, N-methylpyrrolidone or a mixture thereof, main absorption component MEA, auxiliary absorption components EDA, DETA and TETA, active components PZ and 2, 3-butanedione, the corrosion inhibitor is sodium chromate, and the antioxidant is sodium metavanadate and copper carbonate. Since the composite decarburization liquid uses a mixed solvent, it not only improves the absorption capacity, purification degree and desorption rate of carbon dioxide, expands the reaction temperature range, but also reduces the volume of the desorption tower, greatly reduces regeneration energy consumption, and reduces equipment investment and operating costs. The invention is mainly used for capturing carbon dioxide in various chemical reaction tail gas, ore decomposition gas, combustion flue gas, natural gas, city gas and biogas, and has broad application prospects.