The application discloses a kind of asymmetric structure double secondary amine propylenediamine carbon capture agent and preparation method thereof, it is related to
organic synthesis technology and
carbon dioxide capture and separation technical field.The method uses propylenediamine compound with primary amine group and secondary amine group as
raw material,
aldehyde compound is primary amine modifier.Based on the principle that
nucleophilic addition reaction occurs between
aldehyde group and primary amine group in propylenediamine compound, the primary amine group of propylenediamine compound is converted into secondary amine group containing hydroxyalkyl substitution structure, and becomes asymmetric structure N-
alkyl N-hydroxyalkyl propylenediamine compound.The carbon capture agent has two secondary amine reaction sites, wherein
alkyl substituent group can induce to increase the nucleophilicity of secondary amine
nitrogen atom as
electron-donating group, improve absorption performance, and hydroxyalkyl
substituent group can promote the generation of unstable
carbamate between secondary amine and CO2, improve
desorption performance.