The invention discloses a
chemical reaction system for producing
oxalic acid diester and
oxalic acid as main products by using
sodium formate as raw materials. The
chemical reaction system comprises a first reaction unit, a second reaction unit and a third reaction unit, wherein the
sodium formate is subjected to
dehydrogenation reaction to generate
sodium oxalate in the first reaction unit; in the second reaction unit, the
sodium oxalate is mixed with solvents, then, the
oxalic acid is added, the reaction is carried out, and then, the
solid and liquid separation is carried out, wherein the
solid phase is
phosphate, and the oxalic acid diester is rich in the
liquid phase; and in the third reaction unit, the oxalic acid diester-rich
liquid phase is subjected to
distillation separation, then, the oxalic acid diester is respectively subjected to
hydrolysis,
hydrogenolysis and ammonolysis, and oxalic acid,
alcohol, glycol and
oxamide are obtained. The
chemical reaction system disclosed by the invention has the advantages that the influence on environment is avoided, the environment problems of lead-containing
sewage and other waste
discharge do not exist, phosphates from sodium ions and with higher
additional values are generated, the process separation becomes simple, the implementation is easy, and the production process reaches the requirements of clean production and energy saving environment-friendly type production process.