The invention discloses a blast furnace oxygen delivery system and a working method. The system comprises a first oxygen delivery system, a second oxygen delivery system and a delivery main pipe; thefirst oxygen delivery system comprises a first delivery pipe, a first fire arrestor, a first stop valve, a first pressure gauge, a first pressure reduction regulating valve, a second pressure gauge, asecond stop valve and a third stop valve; and the second oxygen delivery system comprises a second delivery pipe, a second fire arrestor, a fourth stop valve, a third pressure gauge, a filter, a second pressure reduction regulating valve, a fourth pressure gauge, a third pressure reduction regulating valve, a fifth pressure gauge and a fifth stop valve. According to the system, middle-pressure oxygen and low-pressure oxygen can achieve hierarchical control, it is guaranteed that the low-pressure oxygen with low energy consumption is used firstly, the insufficient section is supplemented withthe middle-pressure oxygen, the problems that the low-pressure oxygen is diffused, and energy waste is generated when the middle-pressure oxygen is used a lot are effectively avoided, and oxygen-enriched energy conservation and consumption reduction of a blast furnace are achieved to the maximum limit.