Comprehensive utilization method of stone coal resources

A technology of stone coal and resources, applied in the field of comprehensive utilization of stone coal resources, can solve the problems of water pollution, damage to the ecological environment, affect soil structure, etc., and achieve the effects of strong adsorption capacity, environmental friendliness and strong selectivity

Active Publication Date: 2015-08-19
张伟峰
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If left to its own devices and neglected to manage and deal with, it will cause public nuisance, destroy the ecological environment, and endanger people's health.
The hazards of urban garbage generally include the following aspects: 1. Garbage stacking not only occupies cultivated land, but also pollutes soil and crops; makes cultivated land lose its use value
2. Garbage pollutes groundwater or enters surface water through rainwater seepage, causing water pollution
3. During the decay process of garbage, a large amount of heat energy is generated, mainly harmful gases such as ammonia, methane and hydrogen sulfide. If the concentration is too high, it...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The grade of the raw material stone coal ore used in this embodiment is 0.93wt% vanadium content (calculated as vanadium pentoxide).

[0027] This embodiment includes the following steps:

[0028] (1) Crushing and ball milling 1000kg of stone coal to make the fineness 30-60 mesh;

[0029] (2) Add 100L of water to the stone coal, add 250kg of concentrated sulfuric acid with a mass concentration of 98%, stir evenly, stack and mature for 4 days, and obtain 1000 L of mature material;

[0030](3) Add 1500L of water to 1000L of the clinker obtained in step (2), stir at room temperature for 30 minutes; the stirring speed is 50 rpm, and then separate the solid and liquid through a plate and frame filter press, and the resulting 952kg solid is tailings, tailings The vanadium content in the slag (calculated as vanadium pentoxide) is 0.078wt%, and the resulting 1300L liquid is the leaching solution, with a vanadium pentoxide concentration of 6.58g / l;

[0031] (4) Add Shuangf...

Embodiment 2

[0039] The grade of raw material stone coal ore used in this embodiment is 1.05wt% vanadium content (calculated as vanadium pentoxide).

[0040] This embodiment includes the following steps:

[0041] (1) Crushing and ball milling 1000kg of stone coal to make the fineness 30-60 mesh;

[0042] (2) Add 110L of water to the stone coal, add 270kg of concentrated sulfuric acid with a mass concentration of 98%, stir evenly, stack and mature at room temperature for 5 days, and obtain 1000L of mature material;

[0043] (3) Add 1800L of water to the clinker obtained in step (2), stir at room temperature for 30 minutes; the stirring speed is 50 rpm, and then separate the solid and liquid through a plate and frame filter press, and the resulting 950kg solid is tailings, tailings The vanadium content (calculated as vanadium pentoxide) is 0.1wt%, and the resulting 1600L liquid is the leaching solution, and the vanadium content is 6.23g / l in terms of vanadium pentoxide;

[0044] (4) Ad...

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PUM

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Abstract

A comprehensive utilization method of stone coal resources comprises the following steps: 1, crushing stone coal, and carrying out ball milling; 2, adding water, adding concentrated sulfuric acid, and stacking for slaking; 3, adding water, mixing, and carrying out solid-liquid separation; 4, sintering tailings to make red bricks or a garbage fertilizer; 5, preparing ammonium alum; 6, separating to prepare calcium sulfate dihydrate; 7, separating to obtain a sodium metavanadate solution; and 8, preparing vanadic anhydride, carrying out solid-liquid separation to obtain a liquid which is a sodium chloride solution, and heating for evaporation to obtain industrial salt. A small amount of sulfuric acid is added in the production process, most sulfuric acid is consumed in the stacking slaking process to form sulfate, and sulfate basically has no corrosion, so special protection is not needed. Ion exchange resin is Dow weak alkaline anion resin containing a weak alkaline group, and has the advantages of good adsorption ability, strong selectivity, good regeneration property, environmental protection, and simple and safe operation.

Description

technical field [0001] The invention relates to a method for comprehensive utilization of resources, in particular to a method for comprehensive utilization of stone coal resources. Background technique [0002] Stone coal is a kind of low-quality anthracite with low carbon content and low calorific value, and it is also a low-grade polymetallic symbiotic ore. Transformation and coalification. It looks like a stone, and it is difficult to distinguish it from limestone or carbon shale with the naked eye. It is a combustible organic mineral with high ash content (generally greater than 60%) and deep metamorphism. High-quality stone coal with high carbon content is black, with semi-bright luster, less impurities, and a relative density of 1.7 to 2.2. Stone coal with less carbon content is grayish and extremely dark, mixed with more pyrite, quartz veins, phosphorus and calcareous nodules, with a relative density of 2.2 to 2.8, and the calorific value of stone coal is not high,...

Claims

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Application Information

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IPC IPC(8): B09B3/00B09B5/00C05F9/00C01F7/76C04B11/00
CPCY02A40/20
Inventor 张伟峰姜桂生
Owner 张伟峰
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