Comprehensive utilization method of stone coal resources
A technology of stone coal and resources, applied in the field of comprehensive utilization of stone coal resources, can solve the problems of water pollution, damage to the ecological environment, affect soil structure, etc., and achieve the effects of strong adsorption capacity, environmental friendliness and strong selectivity
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Embodiment 1
[0026] The grade of the raw material stone coal ore used in this embodiment is 0.93wt% vanadium content (calculated as vanadium pentoxide).
[0027] This embodiment includes the following steps:
[0028] (1) Crushing and ball milling 1000kg of stone coal to make the fineness 30-60 mesh;
[0029] (2) Add 100L of water to the stone coal, add 250kg of concentrated sulfuric acid with a mass concentration of 98%, stir evenly, stack and mature for 4 days, and obtain 1000 L of mature material;
[0030](3) Add 1500L of water to 1000L of the clinker obtained in step (2), stir at room temperature for 30 minutes; the stirring speed is 50 rpm, and then separate the solid and liquid through a plate and frame filter press, and the resulting 952kg solid is tailings, tailings The vanadium content in the slag (calculated as vanadium pentoxide) is 0.078wt%, and the resulting 1300L liquid is the leaching solution, with a vanadium pentoxide concentration of 6.58g / l;
[0031] (4) Add Shuangf...
Embodiment 2
[0039] The grade of raw material stone coal ore used in this embodiment is 1.05wt% vanadium content (calculated as vanadium pentoxide).
[0040] This embodiment includes the following steps:
[0041] (1) Crushing and ball milling 1000kg of stone coal to make the fineness 30-60 mesh;
[0042] (2) Add 110L of water to the stone coal, add 270kg of concentrated sulfuric acid with a mass concentration of 98%, stir evenly, stack and mature at room temperature for 5 days, and obtain 1000L of mature material;
[0043] (3) Add 1800L of water to the clinker obtained in step (2), stir at room temperature for 30 minutes; the stirring speed is 50 rpm, and then separate the solid and liquid through a plate and frame filter press, and the resulting 950kg solid is tailings, tailings The vanadium content (calculated as vanadium pentoxide) is 0.1wt%, and the resulting 1600L liquid is the leaching solution, and the vanadium content is 6.23g / l in terms of vanadium pentoxide;
[0044] (4) Ad...
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