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Aluminum die-cast alloy surface corrosion-resistant silver-based amorphous film and preparation process thereof

A technology of casting aluminum alloy and amorphous film, which is applied in metal material coating process, ion implantation plating, coating, etc., can solve the problems of restricting the application of amorphous materials and harsh conditions, and achieve improved smoothness and good acid resistance , The effect of saving target materials

Inactive Publication Date: 2014-12-31
张振星
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the conditions required for the preparation of amorphous materials are relatively harsh, which limits the application of amorphous materials in actual industry.

Method used

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  • Aluminum die-cast alloy surface corrosion-resistant silver-based amorphous film and preparation process thereof
  • Aluminum die-cast alloy surface corrosion-resistant silver-based amorphous film and preparation process thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] The raw materials are: 3.5mm thick A380 die-cast aluminum alloy sheet, metal Ag, Cu and rare earth element Ce.

[0020] Preparation process of silver-based amorphous film on aluminum alloy surface:

[0021] (1) First, prepare the target material, calculate according to atomic percentage 45%, 45%, 10% and weigh the corresponding elements Ag, Cu, Ce. Under the protection of argon atmosphere, the smelting is repeated in a high-frequency induction furnace. First melt Ag and Cu, and then add Ce into the melt under the silver foil. The induction frequency is controlled at 45-50kHz. In order to obtain an alloy ingot with uniform element distribution. The skin is removed and cut into squares. After polishing and cleaning the surface, it is fixedly installed on the target device of the plasma sputtering equipment.

[0022] (2) Polish the aluminum alloy surface with sandpaper first, and then perform ultrasonic cleaning in acetone and ethanol solutions to remove oil stains. Clamp the...

Embodiment 2

[0026] Preparation process of silver-based amorphous film on aluminum alloy surface:

[0027] (1) First, prepare the target material, calculate according to atomic percentage 50%, 45%, 5%, and weigh the corresponding elements Ag, Cu, Ce. Under the protection of argon atmosphere, the smelting is repeated in a high-frequency induction furnace. First melt Ag and Cu, and then add Ce into the melt under the silver foil. The induction frequency is controlled at 45-50kHz. In order to obtain an alloy ingot with uniform element distribution. The skin is removed and cut into squares. After polishing and cleaning the surface, it is fixedly installed on the target device of the plasma sputtering equipment.

[0028] (2) Polish the aluminum alloy surface with sandpaper first, and then perform ultrasonic cleaning in acetone and ethanol solutions to remove oil stains. Clamp the cleaned aluminum alloy into the plasma sputtering equipment.

[0029] (3) Vacuum to P=4×10 -4 Pa, then argon gas with a...

Embodiment 3

[0032] Preparation process of silver-based amorphous film on aluminum alloy surface:

[0033] (1) First, prepare the target material, calculate according to atomic percentage 55%, 40%, 5% and weigh the corresponding elements Ag, Cu, Ce. Under the protection of argon atmosphere, the smelting is repeated in a high-frequency induction furnace. First melt Ag and Cu, and then add Ce into the melt under the silver foil. The induction frequency is controlled at 45-50kHz. In order to obtain an alloy ingot with uniform element distribution. The skin is removed and cut into squares. After polishing and cleaning the surface, it is fixedly installed on the target device of the plasma sputtering equipment.

[0034] (2) Polish the aluminum alloy surface with sandpaper first, and then perform ultrasonic cleaning in acetone and ethanol solutions to remove oil stains. Clamp the cleaned aluminum alloy into the plasma sputtering equipment.

[0035] (3) Vacuum to P=4×10 -4 Pa, then argon gas with a ...

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Abstract

The invention relates to an aluminum die-cast alloy surface corrosion-resistant silver-based amorphous film and a preparation process thereof. A 150-300nm thick Ag-Cu-Ce amorphous film is formed on the surface of an aluminum alloy substrate in a plasma sputtering manner and comprises, in weight percent, 40-60% of Ag, 35-45% of Cu and 5-10% of Ce. In a sputtering experiment, discharge current is adjusted to range from 0.4A to 0.5A by the aid of filament current, accelerating voltage is increased to range from 140V to 180V, and then beam voltage is adjusted to range 0.8kV to 0.9kV. The whole sputtering process is performed at room temperature, and the temperature of a target is prevented from being over-high in a cavity by a water cooling system. The uniform and compact Ag-Cu-Ce amorphous film with high micro-hardness and fine wear resistance and corrosion resistance is formed on the aluminum alloy surface by a physical deposition method, the amorphous film is effectively combined with the aluminum alloy substrate, glossiness of the aluminum alloy surface is improved, a coating is thin, and target materials are saved.

Description

Technical field [0001] The invention relates to a silver-based amorphous film with corrosion resistance on the surface of a die-cast aluminum alloy and a preparation process thereof. The method uses plasma sputtering to form an extremely thin amorphous film on the surface of the aluminum alloy, thereby improving the surface corrosion resistance. At the same time, the wear resistance of the alloy is improved, and belongs to the field of preparation of material surface films. Background technique [0002] With the continuous maturity of aluminum alloy products and people's requirements for lightweight, aluminum alloy products have been applied to more and more fields. However, aluminum alloy is soft, the surface is easy to wear, and is susceptible to moisture corrosion under certain conditions. The lighter casting surface darkens and the gloss is poor, and the severer casts white aluminum rust on the casting surface. Surface coating has become an effective method to improve the c...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/16C23C14/34C22C45/00
Inventor 张振星
Owner 张振星