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Chalcopyrite type thin film solar cell and preparation method thereof

A solar cell and chalcopyrite-type technology, which is applied in the manufacture of circuits, electrical components, and final products, can solve the problem that the photoelectric conversion efficiency of chalcopyrite-type thin-film solar cells does not meet the ideal requirements, and facilitates equipment manufacturing and simplification Technology, the effect of reducing battery cost

Active Publication Date: 2015-08-26
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to solve the technical problem that the photoelectric conversion efficiency of the existing chalcopyrite-type thin-film solar cells still does not meet the ideal requirements, the present invention provides a chalcopyrite-type thin-film solar cell with high open-circuit voltage and photoelectric conversion efficiency that is easy to implement

Method used

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  • Chalcopyrite type thin film solar cell and preparation method thereof
  • Chalcopyrite type thin film solar cell and preparation method thereof
  • Chalcopyrite type thin film solar cell and preparation method thereof

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preparation example Construction

[0031] The present invention also provides a method for preparing a chalcopyrite-type thin-film solar cell, the steps comprising: a. cleaning the substrate; b. preparing a main light-absorbing layer on the surface of the substrate; c. preparing mutual insulation on the surface of the main light-absorbing layer The first electrode area and the second electrode area; wherein, preparing the first electrode area includes depositing a back electrode on the surface of the main light absorbing layer; preparing the second electrode area includes sequentially depositing a buffer layer and a conductive layer on the surface of the main light absorbing layer and preparing The second external electrode is simple and easy to implement.

[0032] Preferred steps of the present invention include:

[0033] a. Clean the substrate;

[0034] b. preparing a main light absorbing layer on the surface of the substrate;

[0035] c. Prepare a first electrode region and a second electrode region that a...

Embodiment 1

[0097] (1) Clean ordinary soda-lime glass 1 with a thickness of 2.2 mm for 5 minutes, then dry it with argon, and set it aside;

[0098] (2) Preparation of the main light-absorbing layer 2, take the substrate glass 1 prepared in step (1), and use the reactive co-evaporation process to evaporate Cu, In, and Se to directly prepare p-type CIS (copper: indium: Selenium=0.85:1.0:2.0) layer, the thickness of the prepared CIS layer is 1.5 microns;

[0099] (3) The preparation of the insulating layer 8, first use a mask to cover the positions that do not need to prepare the insulating layer 8, and then use a thermal evaporation process to evaporate silicon oxide to prepare the insulating layer 8. The width of the insulating layer 8 is 50 microns, and the evaporation The height of the insulating layer 8 is 8.0 microns;

[0100] (4) The preparation of the second absorption layer 3 uses a mask to cover the position (including the insulating layer) that does not need to deposit the p+ la...

Embodiment 2

[0106] (1) Clean ordinary soda-lime glass 1 with a thickness of 2.2 mm for 5 minutes, then dry it with argon, and set it aside;

[0107] (2) Preparation of the main light absorbing layer 2, take the substrate glass 1 prepared in the step (1), use a pre-sputtered CuIn target and a CuGa target to prepare a CuInGa metal prefabricated layer on the upper surface of the glass, and then use a solid selenium source selenium Chemical method directly prepares p-type CIGS (copper: indium: gallium: selenium=0.85:0.7:0.3:2.0 layer, the thickness of the prepared CIGS layer is 2.0 microns;

[0108] (3) The preparation of the insulating layer 8, first use a mask to cover the position that does not need to prepare the insulating layer 8, and then use the electron beam evaporation method to evaporate aluminum oxide to prepare the insulating layer 8, the insulating layer 8 is on the surface of the main light absorbing layer 2 The area is 15%, and the height of the evaporated insulating layer 8 i...

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Abstract

The invention provides a chalcopyrite type film solar battery and a preparation method thereof. The film solar battery comprises a substrate, a main light absorbing layer, a first electrode region and a second electrode region, wherein the main light absorbing layer is positioned on the substrate, the first electrode region and the second electrode region are positioned on the main light absorbing layer, and the first electrode region and the second electrode region are isolated from each other; and the first electrode region comprises a back electrode, the back electrode is provided with a first outer electrode for leading out current, the second electrode region comprises a buffer layer / conducting layer and a second outer electrode which are successively stacked, and the buffer layer and the main light absorbing layer are contacted. The solar battery provided by the invention has individual design, a substrate surface is utilized as a light receiving surface in use, and different from the conventional manner that the substrate is utilized as a backlight surface in the traditional chalcopyrite type film solar battery, sunlight directly radiates on the main absorbing layer, and a light source is effectively utilized; and meanwhile, two electrodes are led out from the back, shielding of an electrode grid wire of the light receiving surface on light is avoided, meanwhile, the structures led out from one sides of the two electrode are adopted so as to be beneficial for the assembly of a battery module, and the parallel connection and series connection of the battery are convenient. The preparation method provided by the invention has the advantages of being simple and easy to realize, meanwhile, the cost is low, and the technological manufacture is easy.

Description

technical field [0001] The invention belongs to the photovoltaic field. Specifically, the present invention relates to a chalcopyrite type thin film solar cell and a preparation method thereof. Background technique [0002] At present, commercialized solar cells mainly include: silicon-based wafer cells, thin-film solar cells and gallium arsenide-based concentrator solar cells, among which, chalcopyrite-type thin-film solar cells (copper indium gallium selenide, copper indium selenide, copper indium gallium selenide, copper indium gallium selenide) Selenium-sulfur, copper-indium-sulfur and copper-indium-selenide-sulfur) thin-film solar cells have the characteristics of low production cost, high conversion efficiency, good low-light performance, strong radiation resistance, no light-induced degradation, and can be deposited on flexible substrates. It is known internationally as "the most promising new thin-film solar cell in the next era". [0003] Chalcopyrite thin-film so...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/032H01L31/0352H01L31/0224H01L31/18
CPCY02P70/50
Inventor 钟北军马青云仓芹严道全周勇
Owner BYD CO LTD