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Preparation method of solvent-free elastic metallic paint with high thermal radiation

An elastic metal and radiation technology, applied in the field of metal paint, can solve the problems of poor color and gloss retention, poor high and low temperature resistance deformation, easy cracking of metal paint, etc., and achieve good decoration, excellent elasticity, excellent weather resistance and durability staining effect

Active Publication Date: 2015-08-05
洛阳双瑞防腐工程技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] In order to solve the above problems, the present invention provides a method for preparing a solvent-free elastic metallic paint with high heat radiation. The metallic paint prepared according to the preparation method has excellent elasticity, excellent stain resistance, high It has the characteristics of low temperature deformation, good color and gloss retention, low temperature film formation and environmental protection, and has good heat insulation performance and waterproof performance. Problems such as easy cracking of paint, poor color and gloss retention, and poor resistance to high and low temperature deformation

Method used

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  • Preparation method of solvent-free elastic metallic paint with high thermal radiation
  • Preparation method of solvent-free elastic metallic paint with high thermal radiation

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preparation example Construction

[0037] The preparation of the elastic weather-resistant resin is to add dibutyl maleate dropwise to a four-necked flask with a dispersion, thermometer, and reflux condensation device under room temperature and nitrogen protection conditions, then add a metered linear amino-terminated polyether, and heat Heat it at 60°C for 3 hours, heat it at 80°C for 20 hours, and then discharge it when it cools down to room temperature to get an elastic weather-resistant resin. As the amine resin, it is recommended that the above-mentioned dibutyl maleate be provided by Shanghai Feida Industry and Trade Co., Ltd., and that the above-mentioned linear amino-terminated polyether is Jeffamine D2000 provided by Huntsman Company.

[0038] The preparation of composite cellulose acetate butyrate slurry is to mix 1 weight part of CAB-551-0.2 and 1 weight part of CAB-381-2, and then add 8 weight parts of elastic weather-resistant resin, in a high-speed disperser 800 Mix and disperse at ~1000 rpm for 2...

Embodiment 1

[0050] First prepare the elastic weather-resistant resin, the composite cellulose acetate butyrate slurry and the anti-yellowing elastic curing agent according to the above method.

[0051] Then get 30 parts of elastic weather-resistant resin, 5 parts of ETERFLON4101, 22 parts of composite cellulose acetate butyrate slurry, 0.6 parts of BYK-162, 0.3 parts of Tinuvin384-2, Put 0.5 parts of Tinuvin292, 5 parts of YT-803 and 7 parts of BASF-EVA3 wax into the high-speed disperser and mix and disperse for 30-40 minutes. The speed of the high-speed disperser is controlled at 600-800 rpm. Then transfer to the sand mill and grind until the fineness is ≤30um, then transfer back to the high-speed disperser, and then add 13 parts of CE-110 and 0.6 parts of EFKA3600N in the lower abrasive group in parts by weight, in the disperser 600 Mix and disperse for 30-40 minutes at ~800 r / min, and finally use 6 parts of Lexomer WA98 to adjust its viscosity and filter through a 60-mesh sieve to obta...

Embodiment 2

[0055] First prepare the elastic weather-resistant resin, the composite cellulose acetate butyrate slurry and the anti-yellowing elastic curing agent according to the above method.

[0056] Then get 35 parts of elastic weather-resistant resins, 3 parts of ETERFLON4101, 25 parts of composite cellulose acetate butyrate slurry, 0.4 parts of BYK-162, 0.3 parts of Tinuvin384-2, Put 0.7 parts of Tinuvin292, 7 parts of YT-803 and 5 parts of BASF-EVA3 wax into the high-speed disperser and mix and disperse for 30-40 minutes. The speed of the high-speed disperser is controlled at 600-800 rpm. Go to the sand mill and grind to fineness≤30um and then turn back in the high-speed disperser, transfer the upper abrasive group after grinding to the disperser, and then add 10 parts by weight in the lower abrasive group respectively. 1 part of CE-160 and 0.6 part of EFKA3288, mix and disperse for 30 to 40 minutes in a disperser at a speed of 600 to 800 rpm, and finally use 3 parts of Lexomer WA98...

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Abstract

The invention discloses a preparation method of solvent-free elastic metallic paint producing high thermal radiation. The preparation method comprises the following steps of 1, preparing an elastic weather-resistant resin, composite cellulose acetate butyrate slurry, and a yellowing-resistant elastic curing agent, 2, respectively preparing a component A comprising the elastic weather-resistant resin, a fluorocarbon resin, the composite cellulose acetate butyrate slurry, a wetting dispersant, an ultraviolet light absorber, a light stabilizer, a nano-titanium aldehyde powder, a directional alignment assistant, aluminum powder, a leveling agent and an active toughening agent, and a component B comprising the yellowing-resistant elastic curing agent and an HDI tripolymer, and 3, mixing the component A and the component B according to the ratio of 1: 1, and carrying out uniform dispersion to obtain the solvent-free elastic metallic paint. The solvent-free elastic metallic paint has characteristics of excellent elasticity, excellent stain resistance, high / low temperature deformation resistance, good color retention, good gloss retention, low-temperature film formation and environmental protection, has good heat-insulating properties and water resistance, can cover external wall tiny-cracks produced by deformation, and solves the problem that the existing metallic paint for an external wall crazes easily, has poor color retention and gloss retention, and poor high / low temperature deformation resistance.

Description

technical field [0001] The invention belongs to the technical field of metal paints, in particular to a method for preparing a solvent-free elastic metal paint with high thermal radiation. Background technique [0002] Due to the changeable climatic conditions, local cracks often appear on the surface of the outer wall of the building. Under the action of thermal expansion and contraction, the cracks also become larger or smaller, which requires the metal paint coating to have certain elasticity and waterproof sex. [0003] The traditional solvent-based fluorocarbon metal paint coating is hard, dense, and inelastic, and cannot effectively cover cracks. The phenomenon of cracking, hollowing or even falling off of the metal paint has become a common quality problem. Environmental pollution also limits its application. [0004] Existing water-based metallic paints, due to the chemical reaction of metal pigments such as copper gold powder and aluminum powder in water, lose col...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/04C09D175/08C09D175/06C09D7/12
Inventor 马小强张东亚张乐显卫小星徐飞鹏
Owner 洛阳双瑞防腐工程技术有限公司