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Antivacuum alkali metal doping method for flexible substrate copper indium gallium selenide (CIGS) solar battery

A copper indium gallium selenide and solar cell technology, applied in circuits, electrical components, climate sustainability, etc., can solve the problems of difficulty in uniformity control, high production cost, large equipment investment, etc., so as to reduce production costs and production costs. Low, simplified effect of process steps

Inactive Publication Date: 2013-05-01
SHANGHAI INST OF SPACE POWER SOURCES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the problem that the alkali metal doping methods in the prior art all use high-vacuum deposition, with the increase of the battery area, the requirements for the preparation process and vacuum equipment are extremely stringent, the equipment investment is large, the production cost is high, and the uniformity The difficulty of controlling and other problems, the purpose of the present invention is to provide a non-vacuum alkali metal doping method for flexible substrate copper indium gallium selenium solar cells

Method used

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  • Antivacuum alkali metal doping method for flexible substrate copper indium gallium selenide (CIGS) solar battery
  • Antivacuum alkali metal doping method for flexible substrate copper indium gallium selenide (CIGS) solar battery
  • Antivacuum alkali metal doping method for flexible substrate copper indium gallium selenide (CIGS) solar battery

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Embodiment 1

[0021] figure 1 It is a process schematic diagram of the non-vacuum alkali metal doping method of the flexible substrate copper indium gallium selenium solar cell of the present invention, as figure 1 As shown in the embodiment, the treatment solution 11 is a mixed solution prepared with deionized water, methanol, and ethylene glycol in a certain ratio (1:2:1), and NaF compound is added to the mixed solution, and stirred to make it fully Dissolved and prepared into chemical treatment solutions with different concentrations (0.05wt.%~1wt.%); the flexible substrate 10 with deposited Mo thin film is immersed in the treatment solution, after soaking for 30 seconds to 10 minutes, take out the sample, remove After removing moisture from the sample surface, the Na compound film deposition is complete.

[0022] According to the present invention, the non-vacuum alkali metal doping method of a flexible substrate copper indium gallium selenide solar cell includes the following specific...

Embodiment 2

[0031] The process of applying the non-vacuum alkali metal doping method of the flexible substrate copper indium gallium selenium solar cell of the present invention is as follows figure 1 As shown, the treatment solution 11 is a mixed solution prepared with deionized water, methanol, and ethylene glycol in a certain ratio (1:2:1), and NaF compound is added to the mixed solution, and it is fully dissolved by stirring to prepare into chemical treatment solutions with different concentrations (1wt.%~5wt.%); the flexible substrate 10 with the deposited Mo thin film is immersed in the treatment solution, after soaking for a period of time (30 seconds~10 minutes), take out the sample, remove After removing moisture from the sample surface, the Na compound film deposition is complete.

[0032] According to this embodiment, the above-mentioned step 2, preparing the alkali metal treatment solution, may be, adding NaF compound into the mixed solution, stirring to fully dissolve it, and...

Embodiment 3

[0034] The processing technology of the non-vacuum alkali metal doping method for flexible copper indium gallium selenide solar cells using the method of the present invention is as follows: figure 1 As shown, the treatment solution 11 is a mixed solution prepared with deionized water, acetone, and ethanol according to a certain ratio (1:1:1), and NaF compound is added to the mixed solution, and it is fully dissolved by stirring to prepare different solutions. Concentration (0.05wt.% ~ 5wt.%) chemical treatment solution. image 3 It is an electron micrograph of the alkali metal NaF thin film (processing solution concentration is 0.5wt.%) prepared by the present invention deposited on the flexible substrate with Mo thin film.

[0035] According to this embodiment, the above-mentioned step 2, preparation of the alkali metal treatment solution may be that the treatment solution 11 is a mixed solution prepared by deionized water, acetone, and ethanol in a ratio of 1:1:1, and NaF c...

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Abstract

The invention relates to a photovoltaic solar battery and discloses an antivacuum alkali metal doping method for a flexible substrate copper indium gallium selenide (CIGS) solar battery. The antivacuum alkali metal doping method comprises the following steps of: firstly, preparing a substrate with an Mo back electrode; secondly, preparing an alkali metal processing solution; and thirdly, doping the alkali metal. According to the antivacuum alkali metal doping method disclosed by the invention, the problems of high equipment investment, high production cost, high uniformity control difficulty and the like because an alkali metal doping mode in the prior art adopts a high vacuum deposition mode are solved; and the beneficial effects of simple and convenient process, low production cost, high photoelectric conversion efficiency, no pollution and the like are obtained.

Description

technical field [0001] The invention relates to a method for manufacturing a photovoltaic solar cell, in particular to a non-vacuum alkali metal doping method for a flexible substrate copper indium gallium selenium solar cell. Background technique [0002] Thin-film solar cells with copper indium gallium selenide film as the absorber have high photoelectric conversion efficiency and good radiation resistance, and have become one of the research hotspots in the field of photovoltaic cells. Copper indium gallium selenide (CIGS) solar cells on flexible substrates have very broad application prospects in space and on the ground due to their advantages of light weight, high power to weight ratio, and suitability for large-scale roll-to-roll production. In recent years, rapid progress has been made in experimental and theoretical research on materials, processes, and device performance, especially breakthroughs in key technologies such as absorption layer technology and equipment ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/18
CPCY02P70/50
Inventor 吴敏曹章轶徐传明钱峰伟
Owner SHANGHAI INST OF SPACE POWER SOURCES