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Solar energy mono-crystalline silicon piece flocking solution and application method thereof

A technology of monocrystalline silicon wafer and application method, which is applied in the field of texturing liquid, can solve the problems of reducing the passivation effect, reducing the lifetime of minority carriers, and large size differences, so as to achieve good passivation effect of the textured surface, reduce the density of defect states, The effect of fewer surface defect states

Inactive Publication Date: 2013-07-17
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The effect of this kind of velvet liquid is not very good, the stability of velvet is not very good, the uniformity of the pyramid after velvet is not good, the pyramid on the surface has sharp edges and corners, and the number of children of this velvet surface is low. Lifespan is often not high
[0003] The main defect of the technology currently used in the industry is that the size of the pyramids on the surface of monocrystalline silicon made of lye is not uniform. The size of the large pyramids can reach 4-6 μm, and the size of the small pyramids is about 1 μm. Sharper edge angles
The sharp corners and edges have a very high defect state density, which is easy to form a minority carrier recombination center and reduce the minority carrier lifetime
During the passivation process, cracks are easily formed between the film and the silicon on the corners and edges of the pyramids, which reduces the passivation effect, and increases the electrode resistance and leakage current of the electrode, which is not conducive to improving the conversion efficiency of solar cells.

Method used

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  • Solar energy mono-crystalline silicon piece flocking solution and application method thereof

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Experimental program
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Effect test

Embodiment 1

[0021] The texturing liquid for solar cell monocrystalline silicon wafers in the present embodiment has the following components: the proportion of alkaline reagent NAOH is 9.6g / L, the ethanol content is 50ml / L, sodium ethylate 0.3g / L, vitamin 1g / L and 0.5g / L perfluoroalkyl ether carboxylate potassium salt FC-5, polyoxyethylene ether, polyethylene glycol ester, polyol ester or lauroyl diethanolamine.

[0022] Put the above proportioned texturing solution in a water bath and control the temperature at 78-80°C, place the cleaned silicon chip in it for 30 minutes, take it out, wash and dry it, observe it with a scanning electron microscope, and get the following: figure 1 Pyramid suede SEM shown.

[0023] The silicon wafers are ultrasonically cleaned and polished.

Embodiment 2

[0025] The texturing liquid for solar cell monocrystalline silicon wafers in the present embodiment has the following components: the proportion of alkaline reagent NAOH is 11.2g / L, the ethanol content is 80ml / L, sodium ethylate 1g / L, and vitamin 1.3g / L and 1g / L perfluoroalkyl ether carboxylate potassium salt FC-5, polyoxyethylene ether, polyethylene glycol ester, polyol ester or lauroyl diethanolamine.

[0026] Put the texturing solution with the above ratio in a water bath and control the temperature at 78-80°C, place the cleaned silicon wafer in it for 30 minutes of corrosion, take it out, wash and dry it.

[0027] The silicon wafers are ultrasonically cleaned and polished.

Embodiment 3

[0029] The texturizing liquid for solar cell monocrystalline silicon wafers in the present embodiment has the following components: the proportion of alkaline reagent NAOH is 12.5g / L, the ethanol content is 100ml / L, sodium ethylate 2g / L, vitamin 2g / L L and 2.5g / L perfluoroalkyl ether carboxylate potassium salt FC-5, polyoxyethylene ether, polyethylene glycol ester, polyol ester or lauroyl diethanolamine.

[0030] Put the texturing solution with the above ratio in a water bath and control the temperature at 78-80°C, place the cleaned silicon wafer in it for 30 minutes of corrosion, take it out, wash and dry it.

[0031] The silicon wafers are ultrasonically cleaned and polished.

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Abstract

The invention provides a solar energy mono-crystalline silicon piece flocking solution and an application method of the solar energy mono-crystalline silicon piece flocking solution. The flocking solution comprises the following components: 9.6 to 12.5g / L of NaOH, 50 to 100mL / L of ethanol, 0.25 to 2g / L of sodium ethoxide, 1 to 2g / L of vitamin, and one of 0.5 to 2.5g / L of at least one of potassium perfluoro alkyl ether carboxylate FC-5, polyoxyethylene ether, polyethylene glycol acid ester, polyol ester or lauroyl diethanol amine; and water and used as a solvent. A flocked face prepared by the method provided by the invention has good effect, pyramids of about 1-3 microns are fully and uniformly distributed on the flocked face, thus, little defect mode appears on the surface, the passivating effect of the flocked face is good, the minority carrier lifetime is prolonged, and the open-circuit voltage (Voc) (Variable Output Circuit), the short-circuit current (Isc) and a fill factor (FF) are correspondingly increased; the obtained pyramids are uniformly distributed in dimension and have no sharp edges and apex angles, therefore, the defect mode density on the surface can be greatly reduced, the passivating effect is improved, and the conversion efficiency of a solar cell can be increased.

Description

technical field [0001] The present invention relates to a texturing solution in the technical field of solar photovoltaic cells and an application method thereof, in particular to an alkali etching solution for wet etching the surface microstructure of solar monocrystalline silicon wafers and its application, which can obtain high minority carrier life method. Background technique [0002] Solar photovoltaic power generation is by far the cleanest and most promising power generation technology, and has important applications in many fields. Photovoltaic power generation is reliable and safe, without noise and pollution, and the energy can be said to be inexhaustible for a long period of time. Photovoltaic power generation has no geographical restrictions, does not need to consume fuel, is renewable, does not need to erect wires, has a low probability of failure, and is relatively simple to maintain. It can be combined with many households such as roofs and glass. At presen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C30B33/10
Inventor 单以洪冯仕猛
Owner SHANGHAI JIAO TONG UNIV
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