Method for reducing arsenic content of biogas slurry
A content, biogas slurry technology, applied in biological sludge treatment, waste fuel, anaerobic digestion treatment, etc., can solve problems such as reducing COD removal rate, increasing environmental pollution, reducing methane production in anaerobic reactors, and achieving low cost , The process is simple, the effect of promoting precipitation
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Embodiment 1
[0013] The inoculum was the digestive juice after anaerobic fermentation of pig manure, the TS was 5%, the mass fraction of volatile solids (VS) was 78%, and the inoculum was 25% of the dry weight of the fermented material. Water was added to the mix so that the system TS load of the reactor was 6%. FeCl added to feed pig manure 2 (Based on iron content) dosages are 0, 0.2, 0.5 and 1.0 g / L respectively, with FeCl 2 The treatment with an amount of 0 was used as a control, and they were mixed with the raw materials and added to the continuous stirred reactor (CSTR) and the upflow sludge bed reactor (USB). The temperature of the reaction system was controlled at 35±2°C. Continuous feeding and discharging every day, and accurate monitoring of daily gas production and methane content to ensure stable operation of the reactor. The system was operated stably for 130 days, and samples were taken 17 times. The results are recorded in Table 1.
[0014] Table 1 The reduction rate and...
Embodiment 2
[0019] Inoculum and consumption are the same as in Example 1. FeCl addition to feed pig manure 2 and FeSO 4 Parallel experiments were carried out, and the addition amount (in terms of iron content) was 0, 0.2, 0.5 and 1.0 g / L respectively, and the treatment with 0 iron amount was used as the control. After mixing evenly with the raw materials, add water to adjust the system TS load of the reactor to 6%, and feed it into the CSTR reactor. Operating conditions and methods Example 1. The system ran stably for 130 days, and samples were taken and analyzed. The results are recorded in Table 2.
[0020] Table 2 FeCl addition 2 and FeSO 4 Decrease rate and gas production of arsenic in post-discharge biogas slurry
[0021]
[0022] Note: mean ± standard error (n=17)
[0023] It can be seen from Table 2: (1) FeCl is added to the feed 2 Compared with adding FeSO 4 It has a greater reduction effect on the content of arsenic in the discharged biogas slurry, and the reduction ra...
Embodiment 3
[0025] Inoculum and consumption are the same as in Example 1. FeCl addition to feed pig manure 2 , the addition is the same as in Example 1, which is used as a control group. FeCl addition to feed pig manure 2 , the addition amount is the same as that in Example 1, and the vegetable residue (quick-acting carbon source) is added at the same time, and the addition amount is 5% of the fermented dry matter weight, which is used as the experimental group. Before adding, the vegetable residues were crushed into small sections no larger than 3 cm, and water was added to the mixture so that the system TS load of the reactor was 6%, and then added to the CSTR reactor. The operation method and reaction conditions were the same as in Example 1. The system ran stably for 130 days, and the samples were taken and analyzed. The results are recorded in Table 3.
[0026] Table 3 Decrease rate of arsenic and gas production in discharged biogas slurry after adding available carbon sources
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