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Water-based antimicrobial moldproof hydrophilic paint for heat exchanger fin surface treatment

A surface treatment and heat exchanger technology, applied in antifouling/underwater coatings, polyether coatings, coatings, etc., can solve problems such as loss, difficulty in maintenance, and discoloration, and achieve less addition, good stability, and cost-effective high effect

Active Publication Date: 2013-10-02
GUANGZHOU HUMAN CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because silver ions are easy to dissolve and cause loss, it is difficult to achieve the persistence of antibacterial properties, that is, it is difficult to maintain antibacterial properties during post-processing and use.
On the other hand, silver ions are easily reduced, and their presence can easily lead to discoloration and even precipitation
[0010] At present, the hydrophilic coating products on the market rarely have antibacterial and antifungal properties, and some only have initial antibacterial properties, which are difficult to maintain during post-processing and actual use.

Method used

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  • Water-based antimicrobial moldproof hydrophilic paint for heat exchanger fin surface treatment

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] A water-based antibacterial, mildew-proof and hydrophilic coating for the surface treatment of heat exchanger fins, which consists of the following components in mass percentage: polyacrylic acid (molecular weight: 200,000) 5g, silver-loaded nano-silica 0.1g, pentaerythritol 5g, Alkylphenol polyoxyethylene ether 0.02g, ethanol 5g, and water to make up to 100g.

[0064] (1) Polyacrylic acid is prepared by the following steps:

[0065] 1. 1g of sodium persulfate is prepared into an aqueous solution of sodium persulfate with a concentration of 3% by mass;

[0066] ②Put 5g of acrylic acid and 61.7g of water into the reaction kettle, stir evenly, heat to 80°C, add the sodium persulfate aqueous solution prepared in step ① dropwise, the dropwise addition time is 30 minutes, react for 4 hours, and pass nitrogen during the whole process;

[0067] ③Reduce the temperature to 25°C to obtain polyacrylic acid (molecular weight measured by gel permeation chromatography is 200,000). ...

Embodiment 2

[0077] A water-based antibacterial, anti-mildew, and hydrophilic coating for the surface treatment of heat exchanger fins, which consists of the following ingredients in terms of mass percentage: polyacrylic acid (molecular weight: 100,000) 8g, silver-loaded nano-alumina 0.5g, glycerin 2g, alkane Base phenol polyoxyethylene ether sodium sulfate 0.02g, isopropanol 2g, and water to make up to 100g.

[0078] (1) Polyacrylic acid is prepared by the following steps:

[0079] ① 0.5g of azobisisobutyridine hydrochloride is prepared into an aqueous solution with a concentration of 5% by mass;

[0080] ②Put 10g of acrylic acid and 80g of water into the reaction kettle, stir evenly, heat to 70°C, add the aqueous solution prepared in step ① dropwise, the dropwise addition time is 30 minutes, react for 5 hours, and pass nitrogen during the whole process;

[0081] ③Reduce the temperature to 25°C to obtain polyacrylic acid (the molecular weight measured by gel permeation chromatography is ...

Embodiment 3

[0091] A water-based antibacterial, mildew-proof and hydrophilic coating for the surface treatment of heat exchanger fins, which consists of the following ingredients in mass percentage: polyethylene glycol (PEG-8000, Dow Chemical) 15g, silver-loaded nano-zirconia 0.05g, 0.3g of trimethylolpropane, 0.2g of alkyl diphenyl ether disulfonate, 10g of propylene glycol methyl ether, make up to 100g with water.

[0092] (1) Silver-loaded nano-zirconia is prepared by the following steps:

[0093] ① Prepare 5g of nano-zirconia (average particle size of 25nm, sol state) into a nano-zirconia aqueous dispersion with a concentration of 20% by mass;

[0094] ②Add 0.5g AgClO 4 Prepare AgClO with a molar concentration of 0.2mol / L 4 aqueous solution;

[0095] ③ 0.3g ascorbic acid is mixed with molar concentration and is the ascorbic acid aqueous solution of 0.3mol / L;

[0096] 4. Add the nano-zirconia aqueous dispersion liquid prepared in step 1. to the AgClO prepared in step 2. under the s...

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Abstract

The invention discloses a water-based antimicrobial moldproof hydrophilic paint for heat exchanger fin surface treatment. The paint comprises 3-30% of high molecular compound containing hydrophilic group, 0.05-1% of inorganic nano material with antibacterial action, 0.3-5% of curing agent, 0.02-0.2% of leveling agent and 2-10% of cosolvent. The inorganic nano material with antibacterial action is composed of 2-10% of nano oxide, 0.1-2% of silver salt or nano silver solution, 0.1-2% of reducer, 0.1-1% of stabilizer and the balance of water. Since the inorganic nano material with antibacterial action has high stability in the system, the antimicrobial and moldproof properties and hydrophilicity do not attenuate after the processing technique, and can last for a long time in the application process. The paint has the advantages of low addition amount and high cost performance, and does not influence the later working properties.

Description

technical field [0001] The invention relates to a water-based coating, in particular to a water-based antibacterial, mildew-proof and hydrophilic coating used for the surface treatment of heat exchanger fins. Background technique [0002] In recent years, with the continuous promotion of national policies and the continuous popularization of energy-saving, environmental protection, and low-carbon concepts, high-efficiency energy-saving has become the mainstream of the development of the air-conditioning industry. As an important part of air conditioners, the high performance of heat exchangers has become the general trend. [0003] The surface of the fins of the heat exchanger is generally hydrophilized. After the treatment, the surface of the fins is hydrophilic, so that the condensed water attached to it and the dissolved water during defrosting can quickly flow away along the surface, thereby Avoid forming a "water bridge" between the fins to block the air duct and impro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/02C09D171/08C09D101/28C09D5/14C08F120/06
Inventor 陈兴耀黄艳轶李月峰魏小飞
Owner GUANGZHOU HUMAN CHEM
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