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Polyolefin/polystyrene blend-based wood plastic composite material and preparation method thereof

A technology of wood-plastic composite materials and polystyrene, which is applied in the field of wood-plastic composite materials, can solve the problems of poor interface adhesion, high production cost, and low dosage, so as to improve interface adhesion, improve mechanical properties, and promote Effect of grafting reaction

Inactive Publication Date: 2013-11-20
罗卫华
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recycled plastics, polyethylene, polypropylene and polystyrene occupy a considerable proportion, but due to the poor compatibility between polyethylene, polypropylene and polystyrene, and the interface adhesion between polar wood fibers Therefore, the mechanical properties of the prepared wood-plastic composites are very low, which seriously limits the recycling of waste plastics and the development of high-performance wood-plastic composites.
[0004] In the Chinese patent "A wood-plastic composite material and its manufacturing method" (application number: CN200510135239), it is disclosed that the recycled polyolefin mixture and wood powder are reacted and extruded to prepare wood-plastic composite materials, but because all raw materials are disposable When added to a mixer for mixing, the amount of the initiator is small and is easily absorbed by wood powder, so it is difficult to mix evenly in the plastic, so that the grafting reaction between the plastic and maleic anhydride cannot be carried out effectively, and the performance of the prepared wood-plastic composite material is also difficult to obtain effectively. improve
In the Chinese patent "Wood Plastic Composite Material Prepared from Waste Plastic Mixture and Its Preparation Method" (application number: CN200710144992), it is disclosed that the waste plastic mixture is first reacted with peroxide and maleic anhydride to prepare modified waste Plastic blends are mixed with wood fibers and extruded to prepare wood-plastic composite materials. Although the prepared wood-plastic composite materials have high mechanical properties, because of the need for two extrusions, the production efficiency is low and the production cost is relatively high. High, and this method mainly considers the interfacial adhesion between the plastic matrix and the wood fiber, but there is no effective measure for the improvement of the compatibility between polyolefin and polystyrene. When the content of polystyrene is high, The resulting wood-plastic composites will be difficult to obtain ideal mechanical properties

Method used

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  • Polyolefin/polystyrene blend-based wood plastic composite material and preparation method thereof
  • Polyolefin/polystyrene blend-based wood plastic composite material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0019] Weigh 100 parts of a mixture of polypropylene / polystyrene (80 / 20), 0.3 parts of dicumyl peroxide, and 3 parts of maleic anhydride, and dissolve the initiator and maleic anhydride in acetone to prepare 20% solutions respectively , and then mix it with the plastic mixture evenly, and store it open to allow the solvent to evaporate completely; add 50 parts of wood fiber, 0.75 parts of stearic acid and styrene into a high-speed mixer, and the molar ratio of styrene to maleic anhydride is 1:1, and the Mix for 3 minutes, then add the previously mixed plastic mixture, and mix evenly for 5 minutes; put the mixed material into the twin-screw extruder, the extrusion temperature is 170~195°C, adjust the host and feeding speed to make the material in The residence time in the extruder was 2 minutes and 53 seconds, and the polyolefin / polystyrene blend-based wood-plastic composite material was obtained after extrusion. The resulting wood-plastic composite material was injection molde...

Embodiment 2

[0021] Weigh 100 parts of a mixture of polyethylene / polystyrene (80 / 20), 0.3 parts of dicumyl peroxide, and 3 parts of maleic anhydride, and dissolve the initiator and maleic anhydride in acetone to prepare 20% solutions respectively , and then mix it with the plastic mixture evenly, and store it open to allow the solvent to evaporate completely; add 50 parts of wood fiber, 0.75 parts of stearic acid and styrene into a high-speed mixer, and the molar ratio of styrene to maleic anhydride is 0.5:1, and the mixture is uniform Mix for 3 minutes, then add the previously mixed plastic mixture, and mix evenly for 5 minutes; put the mixed material into the twin-screw extruder, the extrusion temperature is 170~195°C, adjust the host and feeding speed to make the material in The residence time in the extruder was 2 minutes and 51 seconds, and the polyolefin / polystyrene blend-based wood-plastic composite material was obtained after extrusion. The resulting wood-plastic composite material...

Embodiment 3

[0023] Weigh 100 parts of a mixture of polyethylene / polystyrene (80 / 20), 0.3 parts of dicumyl peroxide, and 3 parts of maleic anhydride, and dissolve the initiator and maleic anhydride in acetone to prepare 20% solutions respectively , and then mix it with the plastic mixture evenly, and store it open to allow the solvent to evaporate completely; add 50 parts of wood fiber, 0.75 parts of stearic acid and styrene into a high-speed mixer, and the molar ratio of styrene to maleic anhydride is 1:1, and the Mix for 3 minutes, then add the previously mixed plastic mixture, and mix evenly for 5 minutes; put the mixed material into the twin-screw extruder, the extrusion temperature is 170~195°C, adjust the host and feeding speed to make the material in The residence time in the extruder was 2 minutes and 51 seconds, and the polyolefin / polystyrene blend-based wood-plastic composite material was obtained after extrusion. The resulting wood-plastic composite material was injection molded...

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Abstract

The invention belongs to the field of wood-plastic composite materials, and relates to a polyolefin / polystyrene blend-based wood plastic composite material and a preparation method thereof. The preparation method of the polyolefin / polystyrene blend-based wood plastic composite material comprises the following steps: dissolving an initiator and maleic anhydride in acetone for preparing a solution, uniformly mixing the solution with the polyolefin / polystyrene blend, storing in an open manner for completely volatilizing the solvent; adding wood fiber, the stearic acid and the styrene into a high-speed mixer, uniformly mixing, adding the mixed plastic mixture, and uniformly mixing; and adding the mixed materials into a double-screw extruder, and extruding to obtain the polyolefin / polystyrene blend-based wood plastic composite material. The interface adhesion between a plastic base body and the wood fiber in the wood-plastic composite material, and the compatibility between the plastic components polyolefin and the polystyrenes are improved, so that the tensile strength and impact strength of the composite material are improved. Moreover, the preparation method of the polyolefin / polystyrene blend-based wood plastic composite material has the advantages of being simple in process, high in generating efficiency and low in cost.

Description

technical field [0001] The invention belongs to the field of wood-plastic composite materials, and in particular relates to a polyolefin / polystyrene blend-based wood-plastic composite material and a preparation method thereof. Background technique [0002] The wood-plastic composite material prepared by compounding lignocellulosic materials and polymer resins is a new type of wood-substituting material that is both similar to wood and superior to wood. It fully embodies circular economy, resource utilization, health and environmental protection, and economical substitution. The advanced concept of sustainable economic development is a promising environment-friendly composite material with a wide range of application fields and development prospects. [0003] In recent years, with the increasing amount of plastic used in the world, plastic waste and its environmental pollution have caused more and more concerns. How to effectively recycle various waste plastics has become one...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/00C08L97/00C08F291/00
Inventor 罗卫华吴传荣向世欢夏斌
Owner 罗卫华
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