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Heat storage fiber and preparation method thereof

A technology of heat storage fibers and copolymers, which is applied in the chemical characteristics of fibers, wet spinning, and rayon manufacturing, etc., can solve the problems of unsustainable heat storage effect of fibers, poor chemical stability of zirconium carbide, and unsatisfactory thermal insulation effect. Reduce the cost of dyeing treatment, save the dyeing process, and improve the effect of microcirculation

Active Publication Date: 2016-03-30
河北艾科瑞纤维有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In recent years, the world's fiber consumption for fitness clothes, sportswear, casual clothes, etc. has increased dramatically year by year. Especially for winter sportswear, it is required to be comfortable and warm to wear, so there are many researches on moisture permeability and warmth retention The development of new fiber products, such as moisture-permeable and heat-retaining fibers and their products, is mainly produced through the following two methods: 1. Endowed by post-finishing methods, such as moisture-permeable coating or lamination on the base fabric and high-density The fabric is subjected to hydrophobic processing (such as coating or film coating) to make the fiber product have the function of moisture permeability and heat preservation; 2. By adding additives with heat storage function during the fiber production process, such as zirconium carbide, ceramic micropowder, iron powder or ATO powder and other metals or metal oxides release heat through metal oxidation or absorb sunlight and human body heat, so that fibers and their products have moisture permeability and heat preservation functions, but the heat preservation effect is not ideal and the durability is poor.
[0003] The heat storage fiber additives that are common in the market now mainly include the following two types. One is composed of zirconium carbide and ceramics. However, due to the poor chemical stability of zirconium carbide, it will decompose in water and dissolve in acid, so the heat storage effect of the fiber cannot last; The other uses ATO powder or GTO (modified ATO powder) as an additive, but due to the large amount of addition (about 11% on the fiber), the index in the fiber material drops significantly, and because the powder If the content is high, the powder is easy to fall off, and the heat storage effect of the fiber cannot last long. Long-term exposure of the human body to such metal oxides will also affect health.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Heat storage fiber and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0023] The preparation method of a kind of heat storage fiber of embodiment 1, mix 92~94wt% acrylonitrile, 6~8wt% vinyl acetate two monomers, and adjust the concentration after mixing to 30~40wt%, in 58~ Continuous suspension copolymerization in water at 62°C and pH 2.5 to 3.5; the reacted copolymer powder is terminated by chelation reaction, the unreacted monomer is removed by a stripper, and then the salt and water are removed by washing and filtering. After granulation and molding, the copolymer powder formed by acrylonitrile and vinyl acetate is obtained by drying; the copolymer powder and dimethylacetamide are mixed and dissolved at a mass ratio of 1:3, and the temperature is raised to 80-90 ° C to make the copolymer powder Dissolve the powder in dimethylacetamide completely, and then lower the temperature to 70-80°C to filter the obtained spinning stock solution, adjust the temperature and pressure, and filter at 0.7-0.9MPa pressure and 92-97°C. Spinning, during the spin...

Embodiment 2

[0024] The preparation method of a kind of heat storage fiber of embodiment 2, mix 92~94wt% acrylonitrile, 6~8wt% vinyl acetate two monomers, and adjust the concentration after mixing to 30~40wt%, at 58~ Continuous suspension copolymerization in water at 62°C and pH 2.5 to 3.5; the reacted copolymer powder is terminated by chelation reaction, the unreacted monomer is removed by a stripper, and then the salt and water are removed by washing and filtering. After granulation and molding, the copolymer powder formed by acrylonitrile and vinyl acetate is obtained by drying; the copolymer powder and dimethylacetamide are mixed and dissolved at a mass ratio of 1:3, and the temperature is raised to 80-90 ° C to make the copolymer powder Dissolve the powder in dimethylacetamide completely, and then lower the temperature to 70-80°C to filter the obtained spinning stock solution, adjust the temperature and pressure, and filter at 0.7-0.9MPa pressure and 92-97°C. Spinning, during the spin...

Embodiment 3

[0025] The preparation method of a kind of heat storage fiber of embodiment 3, mix 92~94wt% acrylonitrile, 6~8wt% vinyl acetate two monomers, and adjust the concentration after mixing to 30~40wt%, in 58~ Continuous suspension copolymerization in water at 62°C and pH 2.5 to 3.5; the reacted copolymer powder is terminated by chelation reaction, the unreacted monomer is removed by a stripper, and then the salt and water are removed by washing and filtering. After granulation and molding, the copolymer powder formed by acrylonitrile and vinyl acetate is obtained by drying; the copolymer powder and dimethylacetamide are mixed and dissolved at a mass ratio of 1:3, and the temperature is raised to 80-90 ° C to make the copolymer powder Dissolve the powder in dimethylacetamide completely, and then lower the temperature to 70-80°C to filter the obtained spinning stock solution, adjust the temperature and pressure, and filter at 0.7-0.9MPa pressure and 92-97°C. Spinning, during the spin...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention relates to a thermal storage fiber. The thermal storage fiber is characterized in that thermal storage powder with the diameter being 0.1-1 micrometer are uniformly dispersed in a fiber prepared from copolymer powder formed by acrylonitrile and vinyl acetate, and the mass ratio of the thermal storage powder to the fiber is (0.5-2):(98-99.5). A preparation method for the thermal storage fiber comprises the following steps: producing copolymer powder, preparing a spinning solution, regulating temperature and pressure of the spinning solution, and filtering and spinning the spinning solution; in the spinning process, adding the thermal storage powder with the diameter being 0.1-1 micrometer into the spinning solution according to the mass ratio (0.5-2):(98-99.5) of the thermal storage powder and the fiber; intensively and uniformly mixing at 1400rpm through a dynamic mixer and then spinning and carrying out a coagulating bath, wherein the coagulating bath adopts a dimethyl acetamide aqueous solution, the concentration of the solution is 40-55 weight percent, and the temperature is 38-50 DEG C; carrying out double-diffusion forming, washing with water, drafting, oiling, drying and crimping, wherein the drafting times are 4-7 times; and shaping through 200-330KPa shaping pressure so as to finally obtain a finished thermal storage fiber product. The thermal storage fiber has the advantages of good performance, environmental protection and good thermal storage effect and is beneficial to health. The preparation method is simple and feasible, has high production efficiency, and is easily controlled.

Description

technical field [0001] The invention belongs to the technical field of textiles, in particular to a thermal storage fiber and a preparation method thereof. Background technique [0002] In recent years, the world's fiber consumption for fitness clothes, sportswear, casual clothes, etc. has increased dramatically year by year. Especially for winter sportswear, it is required to be comfortable and warm to wear, so there are many researches on moisture permeability and warmth retention The development of new fiber products, such as moisture-permeable and heat-retaining fibers and their products, is mainly produced through the following two methods: 1. Endowed by post-finishing methods, such as moisture-permeable coating or lamination on the base fabric and high-density The fabric is subjected to hydrophobic processing (such as coating or film coating) to make the fiber product have the function of moisture permeability and heat preservation; 2. By adding additives with heat sto...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/54D01F1/10C08F220/44C08F218/08
CPCD01F6/54D01D5/06
Inventor 杨雪峰刘明哲张海鸥邵宝忠郝朋林白桦安继东杨立杰陈卫国桂荣杨标盛杰段志国郝东文白雪峰
Owner 河北艾科瑞纤维有限公司
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