Production technology for chloroprene rubber

A neoprene raw rubber, production process technology, applied in the field of rubber, can solve the problems of low Mooney viscosity of neoprene products, not suitable for automatic production, poor process stability, etc., to reduce scorching phenomenon, improve vulcanization efficiency and Good quality, good quality effect

Inactive Publication Date: 2014-02-05
ANHUI TONGFENG RUBBER & PLASTIC IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003]Neoprene rubber has good physical and mechanical properties, oil resistance, heat resistance, flame resistance, sunlight resistance, ozone resistance, acid and alkali resistance, chemical reagent resistance, widely used in machinery After years of development, the production capacity of neoprene in China has reached 83,000 tons. With new construction or expansion in the future, it has a good development prospect. Therefore, we should produce neoprene with better quality. Rubber products serve the society, and the application number is CN201110328366.8, which discloses a preparation method of special neoprene rubber, including basic processes such as mastication, mixing, calendering or extrusion, molding and vulcanization, and each process is specific to the product. According to different requirements, a number of auxiliary operations are used respectively. In order to add various required compounding agents to the rubber, the raw rubber first needs to be masticated to improve its plasticity, and then carbon black and various rubber additives are mixed with the rubber by kneading. The rubber is uniformly mixed into a rubber material, which is extruded to form a blank of a certain shape, and then combined with a calendered or glued textile material (or with a metal material) to form a semi-finished product; finally vulcanized and Plastic semi-finished products are made into high-elastic final products, but the neoprene products produced by this process have low Mooney viscosity, high viscosity, poor manufacturability, difficult operation, and poor process stability, which is not suitable for factory automation. Production

Method used

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  • Production technology for chloroprene rubber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) Baking: select the raw neoprene rubber and put it into the bake machine for bake, control the bake temperature to 45℃, and control the bake time to 4h;

[0020] (2) Plasticizing: Weigh 25kg of the rubber compound after drying in step (1) and put it in the open mill, control the plasticizing temperature to 55℃, and control the plasticizing time to 7min;

[0021] (3) Mixing: Add the raw rubber produced in step (2) to the internal mixer, mix for a short time for 4 minutes, and quickly discharge the rubber. After parking for 3 minutes, perform two-stage mixing and control the mixer rotor Rotation speed is 75r / min, add zinc oxide and Na-22 on the open mill, then discharge the next piece, control the discharge temperature to 40℃;

[0022] (4) Semi-finished product cutting: After cooling the film produced in step (3) to room temperature, sprinkle zinc stearate on the surface of the film, and then cut it;

[0023] (5) Vulcanization: Put the film prepared in step (4) into a drum vul...

Embodiment 2

[0024] Example 2: The rest is the same as Example 1, but the difference is that in the step (1), the glue baking temperature is controlled to 48°C, and the glue baking time is controlled to 5h; in the step (2), the plasticizing temperature is controlled to 58°C, Control the plasticizing time to 8min; in the step (3), control the speed of the mixer rotor to 78r / min, and control the discharge temperature to 45°C; in the step (3), control the vulcanization temperature to 170°C, and control The curing time is 6min.

Embodiment 3

[0025] Example 3: The rest is the same as Example 1, except that in the step (1), the temperature of the glue is controlled to be 50°C, and the time of the glue is controlled to be 5h; in the step (2), the temperature of the plasticizing is controlled to 60°C , Control the plasticizing time to 9min; in the step (3), control the mixer rotor speed to 80r / min, and control the discharge temperature to 50°C; in the step (3), control the vulcanization temperature to 175°C, Control the curing time to 7min.

[0026] After the above process steps, take out the ethylene propylene rubber sample for testing:

[0027]

[0028] It can be seen from the above data that the produced chloroprene rubber has a wide temperature range, high Mooney viscosity, low viscosity, good ozone resistance, no cracking, high tensile strength, all above 9.0MPa, this process produces The product has a high qualification rate and good process stability.

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Abstract

Relating to the rubber field, the invention discloses a production technology for chloroprene rubber. The technology comprises the processes of: rubber drying, plastication, mixing, semi-finished product cutting and vulcanization. According to the method, by strictly controlling the rubber drying temperature and time in the rubber drying process, the quality of the dried rubber material is improved. The mixing process adopts a two-stage mixing process, well controls the mixing time and discharge temperature, so that scorching phenomenon of chloroprene rubber is significantly reduced, and the rubber guiding, discharge and batch-out of an open mill are smooth, and no roll sticking phenomenon appears. The vulcanization process adopts N-tert-butyl-2-bisbenzothiazole sulfenamide as a vulcanization accelerator, which is safe and pollution-free and has no harm to the human body. The technological process adopts a drum type vulcanizing machine, the vulcanization efficiency and quality are greatly improved, and the produced product has high Mooney viscosity and good quality. The technological method has the advantages of good technology, simple operation, and good technological stability, thus being suitable for factory automation production.

Description

technical field [0001] The invention relates to the rubber field, in particular to a neoprene production process. [0002] Background technique [0003] Neoprene has good physical and mechanical properties, oil resistance, heat resistance, flame resistance, sunlight resistance, ozone resistance, acid and alkali resistance, and chemical reagents. It is widely used in machinery, electric power and rubber industries. After years of development, China's neoprene rubber The production capacity of the company has reached 83,000 tons. With the new construction or expansion in the future, it has a good development prospect. Therefore, we should produce better quality neoprene products to serve the society. The application number is CN201110328366.8. A preparation method of a special type of neoprene, including basic processes such as mastication, mixing, calendering or extrusion, molding and vulcanization. Each process has different requirements for the product, and several auxilia...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29B7/30B29C35/00C08L11/00C08K13/02C08K3/22C08K5/098C08K5/47
Inventor 项宗武
Owner ANHUI TONGFENG RUBBER & PLASTIC IND
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