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High-strength fiber composite waterborne polyurethane adhesive

A technology of water-based polyurethane and composite materials, applied in the direction of polyurea/polyurethane adhesives, adhesives, adhesive types, etc., can solve problems such as poor water resistance, increased load, passivation of bullet impact force, etc., and achieve anti-shock performance Excellent, improve water resistance, improve the effect of ballistic resistance

Active Publication Date: 2014-02-12
JIANGSU LINRY NEW MSTAR TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, this kind of high-strength fiber composite material (UD), due to the shortcomings of the adhesive itself as the matrix, affects the comprehensive performance of the composite non-woven fabric, which is reflected in poor water resistance. The high-strength fiber composite material (UD) made of it cannot be used. To effectively passivate the impact of bullets in a humid environment, the bulletproof effect can only be achieved through layers of high-strength fiber composites (UD), but this will cause an increase in the general load of soldiers and police

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A water-based polyurethane adhesive for high-strength fiber composite materials. Add water-based PUR dispersion to the adhesive and mix it, then add it to the slurry tank for drying. The drying temperature is 60°C to obtain a water-based polyurethane adhesive for high-strength fiber composite materials. Water-based PUR The amount of the dispersion added is 10% of the weight of the adhesive; the adhesive is a water-based adhesive, and the weight ratio of the adhesive to water is 20%.

[0024] Aqueous PUR dispersions are prepared as follows:

[0025] (1) Put the dried polyether polyol into the container, add toluene diisocyanate to the container and react at 65°C for 2 hours, then add N-methyl-2 dimethylolpropionic acid dissolved in the container dropwise -Pyrrolidone was reacted at 55°C for 2 hours to obtain a prepolymer; the addition of toluene diisocyanate was 15% of the weight of polyether polyol; the addition of dimethylol propionic acid was 15% of the weight of N-me...

Embodiment 2

[0029] A water-based polyurethane adhesive for high-strength fiber composite materials. Add water-based PUR dispersion to the adhesive and mix it, then add it to the slurry tank for drying. The drying temperature is 70°C to obtain a water-based polyurethane adhesive for high-strength fiber composite materials. Water-based PUR The amount of the dispersion added is 12% of the weight of the adhesive; the adhesive is a water-based adhesive, and the weight ratio of the adhesive to water is 40%.

[0030] Aqueous PUR dispersions are prepared as follows:

[0031] (1) Put the dried polyether polyol into a container, add toluene diisocyanate to the container and react at 68°C for 2.5 hours, then add N-methyl-2 dimethylolpropionic acid dissolved in the container dropwise -Pyrrolidone was reacted at 58°C for 2.5 hours to obtain a prepolymer; the addition of toluene diisocyanate was 18% of the weight of polyether polyol; the addition of dimethylol propionic acid was 18% of the weight of N-...

Embodiment 3

[0035] A water-based polyurethane adhesive for high-strength fiber composite materials. Add water-based PUR dispersion to the adhesive and mix it, then add it to the slurry tank for drying, and the drying temperature is 80°C to obtain a water-based polyurethane adhesive for high-strength fiber composite materials. Water-based PUR The amount of the dispersion added is 15% of the weight of the adhesive; the adhesive is a water-based adhesive, and the weight ratio of the adhesive to water is 60%.

[0036] Aqueous PUR dispersions are prepared as follows:

[0037] (1) Put the dried polyether polyol into the container, add toluene diisocyanate to the container and react at 70°C for 3 hours, then add N-methyl-2 dimethylolpropionic acid dissolved in the container dropwise -Pyrrolidone was reacted at 60°C for 3 hours to obtain a prepolymer; the addition of toluene diisocyanate was 20% of the weight of polyether polyol; the addition of dimethylol propionic acid was 20% of the weight of ...

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Abstract

The invention relates to a high-strength fiber composite (UD) waterborne polyurethane (PUR) adhesive. A purpose of improving the water resistance is achieved by adding a waterborne PUR dispersoid to an adhesive. A preparation method of the waterborne PUR dispersoid comprises the steps that dried polyether polyol is put into a container; toluene diisocynate is added to the container; a reaction lasts for 2h at 65-70 DEG C; N-methyl-2-pyrrolidone with dissolved dimethylolpropionic acid is dropwise added to the container; the reaction lasts for 2h at 55-60 DEG C; a prepolymer is obtained; 0 DEG C deionized water and triethylamine are added to another container, and stirred at a high speed; the prepared prepolymer is injected into the container; dihydroxy propane and an ethylenediamine chain extender are added after 0.5min, and dispersed for 10min; the waterborne PUR dispersoid can be obtained. The waterborne PUR adhesive can improve the water resistance of a high-strength fiber composite, and enhance the shock resistance, the bulletproof property and the anti-puncture property of the high-strength fiber composite.

Description

technical field [0001] The invention relates to an adhesive in the field of bulletproof protective products, in particular to a high-strength fiber composite material (UD) water-based polyurethane adhesive. Background technique [0002] High-strength fiber composites (UD) are made of UHMWPE fibers or aramid fibers that are uniformly, parallel, and straightly arranged, then glued and dried. This process has been described in US4916000 and US5149391. The glued adhesives generally include polyethylene, cross-linked polyethylene, polypropylene, vinyl copolymer, propylene copolymer, ethylene-propylene copolymer and other olefin polymers and copolymers, as well as unsaturated polyester, polybutylene Diene, polyisoprene, natural rubber, epoxy resin, polyimide and many other low-modulus resins; in addition, there are EVA, EEA, SBS, SIS, TPR, SEBS and other sodium-butadiene rubber and styrene-butadiene rubber These thermoplastic high-tough glues such as PVB and PVA. These low-modul...

Claims

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Application Information

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IPC IPC(8): C09J175/08C08G18/76C08G18/66C08G18/48C08G18/34C08G18/32C08G18/12
Inventor 郭振勤丁旭
Owner JIANGSU LINRY NEW MSTAR TECH