High-barrier, flame-retardant and anti-electrostatic epoxy-resin adhesive and preparation method thereof

A flame retardant, antistatic, epoxy resin technology, used in epoxy resin adhesives, adhesives, polymer adhesive additives, etc., can solve the problem that epoxy resin adhesives cannot meet the needs, and achieve excellent antistatic properties Good antistatic property, simple process effect

Active Publication Date: 2014-02-26
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the rapid development of science and technology and industry, in...

Method used

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  • High-barrier, flame-retardant and anti-electrostatic epoxy-resin adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] According to the following formula: by weight fraction

[0035] 100 parts epoxy resin

[0036] Ethylene / vinyl alcohol copolymer 4 parts

[0037] Polyamide resin 50 parts

[0038] Thermoplastic polyurethane 0 parts

[0039] N-Methylpyrrolidone 20 parts

[0040] Antistatic agent 0.5 parts

[0041] Modified nano-organic montmorillonite 2 parts

[0042] Modified nano silicon dioxide 1 part

[0043] Dibutyl phthalate 14 parts

[0044] Inorganic filler 3 parts

[0045] Dimethyl methyl phosphate 14 parts

[0046] Take each raw material according to the composition of the raw materials in Example 1, add 4 parts of ethylene / vinyl alcohol copolymer and 20 parts of N-methylpyrrolidone into reaction vessel 1, mix them uniformly in reaction vessel 1, and place them in a water bath at 70°C temperature, and the magnetic stirrer was stirred for 30 min at a rotational speed of 30 n / min to obtain a dissolved ethylene / vinyl alcohol copolymer. Take 100 parts of epoxy resin, 14 part...

Embodiment 2

[0048] According to the following formula: by weight fraction

[0049] 100 parts epoxy resin

[0050] Ethylene / vinyl alcohol copolymer 7 parts

[0051] 60 parts polyamide resin

[0052] 5 parts thermoplastic polyurethane

[0053] N-Methylpyrrolidone 25 parts

[0054] Antistatic agent 1.5 parts

[0055] Modified nano-organic montmorillonite 3 parts

[0056] Modified nano silica 2 parts

[0057] Dibutyl phthalate 17 parts

[0058] Inorganic filler 4 parts

[0059] Dimethyl methyl phosphate 17 parts

[0060] Take each raw material according to the raw material composition in Example 2, add 5 parts of thermoplastic polyurethane, 7 parts of ethylene / vinyl alcohol copolymer and 25 parts of N-methylpyrrolidone into reaction vessel 1, and mix in reaction vessel 1 homogeneously, in a water bath at a temperature of 70° C., and with a magnetic stirrer at a rotational speed of 30 n / min, stirring for 30 minutes to obtain a dissolved thermoplastic polyurethane and ethylene / vinyl al...

Embodiment 3

[0062] According to the following formula: by weight fraction

[0063] 100 parts epoxy resin

[0064] Ethylene / vinyl alcohol copolymer 10 parts

[0065] 70 parts of polyamide resin

[0066] 10 parts thermoplastic polyurethane

[0067] 30 parts of N-methylpyrrolidone

[0068] Antistatic agent 2.5 parts

[0069] Modified nano-organic montmorillonite 4 parts

[0070] Modified nano silicon dioxide 3 parts

[0071] 20 parts of dibutyl phthalate

[0072] Inorganic filler 5 parts

[0073] Dimethyl formate 20 parts

[0074] Take each raw material according to the composition of the raw materials in Example 3, add 10 parts of ethylene / vinyl alcohol copolymer and 30 parts of N-methylpyrrolidone into reaction vessel 1, mix them uniformly in reaction vessel 1, and place them in a water bath at 70°C temperature, and the magnetic stirrer was stirred for 30 min at a rotational speed of 30 n / min to obtain a dissolved ethylene / vinyl alcohol copolymer. Take 100 parts of epoxy resin, 2...

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Abstract

The invention discloses a high-barrier, flame-retardant and anti-electrostatic epoxy-resin adhesive and a preparation method and application thereof. The adhesive is prepared from the following ingredients in parts by weight: 100 parts of epoxy resin, 4-10 parts of ethylene-vinyl alcohol copolymer, 50-70 parts of polyamide resin, 0-10 parts of thermoplastic polyurethane, 20-30 parts of N-methyl pyrrolidone, 0.5-2.5 parts of antistatic agent, 2-4 parts of modified nano organic montmorillonite, 1-3 parts of modified nano-silica, 14-20 parts of di-n-butyl phthalate, 3-5 parts of inorganic filler and 14-20 parts of dimethyl methyl phosphonate. The adhesive prepared by the preparation method has the advantages of good electrostatic resistance, high barrier, excellent flame retardance, high adhesive strength, good toughness, strong deflection resistance and the like, and the preparation method is scientific and reasonable and is simple in process and strong in operability, so that the industrial production is easy to realize. The adhesive can be applied to fields with relatively high requirements for electrostatic resistance, barrier and flame retardance, such as the combination of plastic fuel tank materials and PET (Polyethylene glycol Terephthalate) beer bottle materials, which is relatively popular currently.

Description

technical field [0001] The invention belongs to the technical field of epoxy resin adhesive preparation, and in particular relates to a high-barrier flame-retardant antistatic epoxy resin adhesive and a preparation method and application thereof. Background technique [0002] Epoxy resin adhesive is an important one among the eight synthetic adhesives. It is widely used in aerospace, automobile, chemical industry, electronic appliances, light fields of work and daily life. Generally, epoxy resin adhesives are mainly composed of epoxy resin and curing agent. We can add tougheners, diluents, coupling agents, accelerators, inorganic fillers, etc. as needed. The bonding process of epoxy resin adhesives is a complex physical and chemical process, including steps such as infiltration, adhesion, and curing, and finally generates a cured product with a three-dimensional cross-linked structure to combine the adherend into a whole. Bonding performance (strength, heat resistance, cor...

Claims

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Application Information

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IPC IPC(8): C09J163/00C09J123/08C09J175/08C09J175/06C09J11/06C09J11/04C09J11/08
Inventor 郑玉婴林锦贤樊志敏
Owner FUZHOU UNIV
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