Preparation method of heat-insulating anti-fogging film
A technology of anti-fog film and preparation method, which is applied in the field of preparation of heat-insulating anti-fog film, which can solve the problems that the surface of the window film does not have anti-fog function, reduces the visible light transmittance of the glass, and affects the driver's field of vision, so as to achieve good waterproofing Heat insulation function, good oil resistance, good anti-adhesion effect
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Embodiment 1
[0026] The invention discloses a method for preparing a heat-insulating anti-fog film agent, which comprises the following steps:
[0027] Step 1 The preparation of heat insulation layer resin is to add 15g of pentahydroxypolyoxypropylene ether and maleic acid-polyacrylic acid copolymer to the mixed solution made of 60g of methyl isobutyl ketone and tetrahydrofuran according to the mass ratio of 5:1. A mixture made with a ratio of 3:1, 10g of hexamethylene diisocyanate trimer, stirred at 30°C for 8h, and then added with 5g of nano-silica particles and indium tin oxide at a mass ratio of 1:1 The mixture and 0.2g polyether polyester modified organosiloxane are stirred evenly to obtain the heat insulating layer resin;
[0028] The second step is to mix and hydrolyze N-(2-aminoethyl)-3-aminopropylmethyldimethoxysilane and hydrochloric acid, adjust the pH value to 5.0-7.0, and add chemical auxiliary formamide, ethyl alcohol to the hydrolyzate Glycol, glycerin and calcium oxide, fo...
Embodiment 2
[0033] A method for preparing a heat-insulating anti-fog film agent, comprising the steps of:
[0034] Step 1 The preparation of heat insulation layer resin is to add 30g of pentahydroxypolyoxypropylene ether and maleic acid-polyacrylic acid copolymer to the mixed solution made of 90g of methyl isobutyl ketone and tetrahydrofuran according to the mass ratio of 5:1. The mixture made at a ratio of 3:1, 30g of polyisocyanate, stirred at 60°C for 2h, and then 18g of nano-silica particles and gallium zinc oxide at a mass ratio of 2:1 and 2g of polyether polyester were added Modified organosiloxane, after stirring evenly, the heat insulation layer resin can be obtained;
[0035] The second step is to mix and hydrolyze γ-mercaptopropyltrimethoxysilane with hydrochloric acid, adjust the pH value to 5.0-7.0, and add chemical auxiliary formamide, ethylene glycol, glycerol and calcium oxide, formamide, ethyl alcohol to the hydrolyzate. Glycol, glycerin and calcium oxide are added accord...
Embodiment 3
[0040] A method for preparing a heat-insulating anti-fog film agent, comprising the steps of:
[0041] Step 1 The preparation of heat insulation layer resin is to add 20g of pentahydroxypolyoxypropylene ether and maleic acid-polyacrylic acid copolymer to the mixed solution made of 75g of methyl isobutyl ketone and tetrahydrofuran according to the mass ratio of 5:1. A mixture made with a ratio of 3:1, 20g of hexamethylene diisocyanate trimer, stirred at 50°C for 4h, and then added with 12g of nano-silica particles and zinc gallium oxide at a mass ratio of 2:1 The mixture and 1g of polyether polyester modified organosiloxane are stirred evenly to obtain the heat insulating layer resin;
[0042]The second step is to hydrolyze γ-methacryloxypropyltrimethoxysilane with hydrochloric acid, adjust the pH value to 5.0-7.0, and add chemical additives formamide, ethylene glycol, glycerol and calcium oxide to the hydrolyzate , formamide, ethylene glycol, glycerin and calcium oxide are ad...
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