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A kind of water-based conductive paint and preparation method thereof

A conductive coating, water-based technology, applied in conductive coatings, coatings, etc., can solve problems such as poor corrosion resistance, poor coating uniformity, and conductive coating limitations, and achieve the goal of reducing production costs, improving brushability, and reducing dosage. Effect

Inactive Publication Date: 2016-02-03
临泽县鼎丰源凹土高新技术开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

For example, JP64-30103A discloses a preparation method of a conductive coating using metal powder as a conductive filler. Although the metal powder has excellent electrical conductivity, except for silver powder, powders such as aluminum and copper are easily oxidized and have poor corrosion resistance. Higher, in addition, metal powder is generally large in proportion and easy to sink to the bottom and agglomerate, so the dispersibility is not good; CN1060858A discloses a kind of preparation method of conductive coating with carbon black or graphite as conductive filler, although the conductivity of carbon-based conductive powder is higher Good, the stability is also good, but it is difficult to disperse evenly, and the application of conductive coatings is greatly limited; CN102174284B authorizes a production method for preparing conductive coatings with polyaniline / attapulgite clay as conductive fillers, and the composite conductive fillers Excellent electrical conductivity and low cost, but as a conductive filler, polyaniline has poor dispersibility, is easy to agglomerate, and is prone to flocculation after being placed. Although the good viscosity and thixotropy of attapulgite clay can increase the stability of the coating and plasticity, but the cohesion of the two substances is poor, and the uniformity of the coating is poor; CN103077765A discloses a composite conductive material, which is prepared by surface adsorption of organic compounds with attapulgite clay powder and nano carbon powder, the composite material Although it can improve the hydrophilicity, because its structure is still a layer chain structure of attapulgite, the stability is still poor when preparing water-based coatings

Method used

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  • A kind of water-based conductive paint and preparation method thereof

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Effect test

Embodiment 1

[0028] (1) Preparation of modified attapulgite / nano carbon powder composite conductive powder:

[0029] a. Weigh 100g of attapulgite clay with a fineness of 200-400 mesh and put it into 800ml distilled water, treat it with 50ml hydrochloric acid with a concentration of 1mol / L at 80°C for 2 hours, and stir for 2 hours at the same time to prepare a suspension; Add 10mL of organopolysiloxane and OP-10 composite active agent to the suspension, and the volume ratio of the two is 1:1; add NaOH solution dropwise to adjust the pH value of the suspension to 6, and then stirrer with a cross blade at 1500 RPM and stirring for 2 hours, after standing still for 10 hours, the modified attapulgite clay suspension is separated;

[0030] b. Add 10 g of nano-carbon powder to the above-mentioned isolated modified attapulgite clay suspension, after stirring for 10 min, the suspension is centrifuged in a centrifuge for 3 times, each time for 5 minutes, and the solid is recovered by filtration;

...

Embodiment 2

[0036] (1) The modified attapulgite / nano-carbon powder composite conductive powder was prepared according to the method of Example 1.

[0037] (2) Pour 550ml of deionized water into the mixer, add 60g of dispersant, 50g of emulsifier and 50g of coupling agent into it, and stir thoroughly for 60 minutes.

[0038] (3) Put 200g of attapulgite / nano carbon powder composite conductive powder and 50g of sodium bentonite into the mixing system of step (2), and stir thoroughly for 2 hours.

[0039] (4) Add 30g of binder and 5g of defoamer to the mixed system obtained in step (3), put it into a ball mill and mill it at a speed of 200 rpm for 3 hours, and vacuum defoam the slurry after ball milling to obtain Conductive paint.

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Abstract

The invention discloses a water-based conductive coating, which is characterized in that the water-based conductive coating includes the following components in weight percent: 2% to 5% of sodium-based bentonite, modified attapulgite / nano-carbon powder composite conductive powder Material 15-20%, emulsifier 3-5%, binder 1-3%, dispersant 2-6%, coupling agent 2-5%, deionized water 55.5-70%, defoamer 0.1-0.5 %. The invention also discloses a preparation method of the water-based conductive paint. The preparation process is simple, the stability is good, and the industrialized production is easy to realize. Moreover, the prepared water-based conductive coating has good stability, and it still has a suspension of 98.8% after being placed for 7 days, which is beneficial to the uniform coating of the coating on the metal surface.

Description

technical field [0001] The invention relates to a water-based conductive paint and a preparation method thereof. Background technique [0002] Conductive coating has the properties of eliminating static electricity and electromagnetic shielding. It is composed of film-forming substances, conductive fillers, solvents and additives. It has broad application prospects in the fields of conductive coating on the inner wall of oil tanks, electronic components and circuit board printing, and electromagnetic wave shielding. [0003] Conductive coatings are mainly divided into additive conductive coatings and non-additive conductive coatings, among which additive conductive coatings dominate. At present, the conductive fillers commonly used in additive-type conductive coatings mainly include metal-based powders, carbon-based powders, metal oxide-based powders and composite conductive powders. For example, JP64-30103A discloses a preparation method of a conductive coating using metal...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D5/24C09D7/02C09D7/45
Inventor 姚义俊刘斌蒋晓龙李军王涛库勇昌
Owner 临泽县鼎丰源凹土高新技术开发有限公司