Light-emitting diode epitaxial wafer and manufacture method thereof
A technology for light-emitting diodes and epitaxial wafers, applied in electrical components, circuits, semiconductor devices, etc., can solve the problems of limited improvement of light-emitting diode brightness and low internal quantum efficiency of light-emitting diodes, reducing electron overflow and improving internal quantum efficiency. Efficiency, the effect of increasing the barrier height
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Embodiment 1
[0030] An embodiment of the present invention provides an epitaxial wafer for a light-emitting diode, see figure 1 , the epitaxial wafer includes a substrate 1, a low temperature buffer layer 2 grown on the substrate 1, an undoped gallium nitride layer 3, an N-type gallium nitride layer 4, a multiple quantum well layer 5 and a P-type gallium nitride layer Layer 6, the multiple quantum well layer 5 is a superlattice structure, the superlattice structure includes a quantum well layer 51 and a quantum barrier layer 52 (see Figure 1a and 1b ), the quantum well layers 51 and the quantum barrier layers 52 are alternately grown, wherein at least one quantum barrier layer 52a starting from the N-type gallium nitride layer side is made of Al x Ga 1-x N growth, 0z Ga 1-z N grows, 0<z<0.15, and the P-type gallium nitride layer 6 is grown directly on the multiple quantum well layer 5 .
[0031] Preferably, the period number of the multiple quantum well layer is 5-15, but it is not li...
Embodiment 2
[0050] An embodiment of the present invention provides an epitaxial wafer for a light-emitting diode. The structure of the epitaxial wafer in this embodiment is basically the same as that of the epitaxial wafer in Embodiment 1, except that the multiple quantum well layer 5 of the epitaxial wafer does not include Intermediate quantum barrier layer 52c.
[0051] see figure 2 , the epitaxial wafer includes, from bottom to top, a substrate 1, a low temperature buffer layer 2, an undoped gallium nitride layer 3, an N-type gallium nitride layer 4, a multiple quantum well layer 5 and a P-type gallium nitride layer 6, The multi-quantum well layer 5 is a superlattice structure, and each period includes a quantum well layer 51 and a quantum barrier layer 52, and the quantum well layer 51 and the quantum barrier layer 52 grow alternately, wherein, from the side of the N-type gallium nitride layer. At least one quantum barrier layer 52a uses Al x Ga 1-x N growth, 0z Ga 1-z N grows, 0...
Embodiment 3
[0056] Embodiments of the present invention provide a method for fabricating an epitaxial wafer of a light-emitting diode, see image 3 , methods include:
[0057] Step 301: providing a substrate;
[0058] Optionally, in this embodiment, the substrate includes but is not limited to a sapphire substrate.
[0059] When realized, the substrate can be kept at 1300 °C H 2 The heat treatment was performed in the atmosphere for 10 minutes, and the surface was cleaned.
[0060] Step 302 : growing a low temperature buffer layer, an undoped gallium nitride layer, and an N-type gallium nitride layer on the substrate in sequence;
[0061] Optionally, in this embodiment, the low temperature buffer layer may be a gallium nitride layer, or may be an aluminum nitride layer or an aluminum gallium nitride layer. Specifically, at a temperature of 550° C., a low-temperature buffer layer made of GaN is grown on the surface of the substrate with a thickness of 20-30 nm.
[0062] Specifically, ...
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