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Polyurethane gas hole sealing material for underground coal mine and preparation method thereof

A sealing material, polyurethane technology, applied in the field of materials, can solve the problems of endangering human health and social security, releasing large harmful gases and smoke, and high cost, improving safety and economy, avoiding fire, and good sealing. Effect

Inactive Publication Date: 2014-04-16
LIAONING TECHNICAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the cost of the existing polyurethane gas sealing materials is relatively high, and the polyurethane sealing materials without flame retardants are extremely easy to burn in the environment where the medium itself has the potential for spontaneous combustion, and a large amount of harmful gases and smoke are released during the combustion process, which is harmful Human health and social safety, therefore, it is particularly important to reduce the cost of polyurethane sealing materials while improving their flame retardancy

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The polyurethane gas sealing material used in underground coal mines is composed of three components A, B and C. The A component is toluene diisocyanate, accounting for 49.2% of the total mass of the material; the B component is 4063 polyether multi-component Alcohol and auxiliary materials account for 31% of the total mass of the material, of which 4063 polyether polyol accounts for 69.6% of the mass of component B, the catalyst triethylenediamine B accounts for 1.9% of the mass of the component, and the flame retardant dimethyl phosphate It accounts for 12.6% of the mass of component B, foam stabilizer SD-102 accounts for 3.2% of the mass of component B, foaming agent water accounts for 6.3% of the mass of component B, and chain extender 1,4-butanediol accounts for 3.2% of the mass of component B. 6.3% of the mass; C component is sodium silicate, accounting for 19.8% of the total mass of the material.

[0031] Its preparation method is:

[0032] (1) Weigh 25 g...

Embodiment 2

[0037] The polyurethane gas sealing material used in coal mines is composed of three components A, B and C. The A component is diphenylmethane diisocyanate and polymethylene polyisocyanate, accounting for 41.2% of the total mass of the material. %; B component is 4110 polyether polyol and auxiliary materials, accounting for 25.8% of the total mass of the material, of which 4110 polyether polyol accounts for 70.4% of the mass of B component, and the catalyst N,N-dimethylcyclohexylamine accounts for B 0.77% of the mass of the component, the flame retardant triphenyl phosphate accounts for 12.8% of the mass of the B component, the foam stabilizer XH-295 accounts for 3.2% of the mass of the B component, and the blowing agent cyclopentane and n-hexane account for the B component 6.4% of the mass, chain extender 1,6-hexanediol accounts for 6.4% of the mass of component B; component C is potassium silicate, accounting for 33% of the total mass of the material.

[0038] Its prepar...

Embodiment 3

[0044] The polyurethane gas sealing material used in coal mines consists of three components A, B and C. The A component is hexamethylene diisocyanate, accounting for 35.2% of the total mass of the material; the B component is 3050 Polyether polyols and auxiliary materials account for 53.5% of the total mass of materials, of which 3050 polyether polyols account for 60% of the mass of component B, catalysts tetramethylethylenediamine and pentamethyldiethylenetriamine account for the mass of component B The flame retardant triethyl phosphate accounts for 10% of the mass of component B, the foam stabilizer 055 accounts for 15% of the mass of component B, the foaming agent dichloroethylene accounts for 5% of the mass of component B, and the chain extender The agent neopentyl glycol accounts for 10% of the mass of the B component; the C component is water glass, accounting for 11.3% of the total mass of the material.

[0045] Its preparation method is:

[0046] (1) Weigh 25...

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Abstract

The invention belongs to the technical field of materials, and particularly relates to a polyurethane gas hole sealing material for an underground coal mine and a preparation method thereof. The hole sealing material disclosed by the invention comprises three components A, B and C, wherein the component A is isocyanate and accounts for 35-55% of total mass of the materials; the component B is polyether polyol and auxiliary materials, and accounts for 5-55% of total mass of the materials, wherein the polyether polyol accounts for 60-84.9% of the mass of the component B, a catalyst accounts for 0.1-5% of the mass of the component B, a fire retardant accounts for 10-30% of the mass of the component B, a foam stabilizer accounts for 0-15% of the mass of the component B, a foaming agent accounts for 5-20% of the mass of the component B and a chain extender accounts for 0-10% of the mass of the component B; the component C is sodium silicate, and accounts for 10-50% of total mass of the materials. The preparation method comprises the following steps: burdening according to the ratio of the components A, B and C, and fully mixing to obtain the hole sealing material. The hole sealing material disclosed by the invention is the gas hole sealing material which is low in price, low in viscosity, large in expansion times, good in air-tightness, strong in binding power and good in flame retardant property, and the safety and the economical efficiency of gas hole sealing for the underground coal mine can be greatly improved.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to a polyurethane gas sealing material used in underground coal mines and a preparation method thereof. Background technique [0002] At present, the commonly used gas sealing materials mainly include clay sealing materials, cement mortar sealing materials and polyurethane sealing materials. Among them, the softness and hardness of clay sealing materials are not easy to control, and the sealing length is short, so the sealing effect cannot be achieved well. ; The plasticity of the cement mortar sealing material is small, it is easy to produce air leakage, the setting time is long, and the operation is complicated. The polyurethane sealing material is more and more used in the treatment of underground gas drainage due to its characteristics of large expansion, good sealing, strong cohesive force, no shrinkage, and antistatic properties. [0003] However, the cost of th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/48C08L75/08C08K5/521C08K5/523C08K3/34
CPCC08G18/4829C08G18/6674C08G2101/00C08J9/141C08J9/142C08J9/145C08J2203/14C08J2203/162C08J2203/182C08J2375/08C08K3/34C08K5/521C08K5/523C08G2110/0083
Inventor 杨绍斌王阳董伟杜斌
Owner LIAONING TECHNICAL UNIVERSITY
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