Pre-molten type square billet crystallizer casting powder and preparation method thereof

A crystallizer powder and pre-melting technology, which is applied in the field of metallurgical auxiliary materials, can solve the problems that are not conducive to the preparation of mold powder with excellent performance, affect the physical and chemical properties of the mold powder, and the mass percentage is irregular. Low rate and uniform composition

Active Publication Date: 2014-04-23
郑州市裕丰耐火材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Disadvantages of red mud: radiation; the content of TiO2 in red mud is relatively large, and it is easy to generate high melting point substances, thereby deteriorating slag Physical and chemical properties, deterioration of lubrication, and it is one of the reasons for the formation of "cold skin" on the liquid surface of the crystallizer; the mass percentage of calcium oxide, silicon oxide, aluminum oxide and other substances in red mud is irregular, and direct application is not conducive to excellent performance Preparation of mold flux; the bulk density of red mud is 0.67g / cm3 is too light, which directly affects the physical and chemical properties of mold flux

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] In terms of weight percent, the raw material composition of the premelt is: 60% red mud, 24% quartz, 11% calcite, 2% clay and 3% barium sulfate.

[0037] The weight percentage of various chemical components in the red mud is Al 2 o 3 8.0~19%, SiO 2 16~25%, Fe 2 o 3 4.0~7.0%, CaO 28~38%, Na 2 O 3.5-5.9%; the particle size of the quartz, calcite, clay and barium sulfate are all 150-250 mesh.

[0038] The processing method of the present embodiment premelt is:

[0039] a. First dry the red mud, control the water content in the dried red mud to be less than 0.4%, and then grind the dried red mud to 150-250 mesh powder;

[0040] c. Mix the red mud powder pulverized in step a with quartz, calcite, clay and barium sulfate powder of 150-250 meshes, and mix uniformly according to the raw material composition ratio of the premelt described in this embodiment, and add 20-25% of water is stirred and formed (the pressure is 4-6 MPa during forming, forming a rectangular or ...

Embodiment 2

[0050] The pre-melted billet mold powder of the present invention is represented by weight percentage. The raw material composition of the pre-melted billet mold powder is: 76% of premelt, 4% of wollastonite, 3% of fluorite %, sodium carbonate 4%, carbonaceous material 7% (graphite 5% and carbon black 2%), quartz 4% and dextrin 2%;

[0051] In terms of weight percent, the raw material composition of the premelt is: 70% red mud, 18% quartz, 4% calcite, 2% clay and 6% barium sulfate.

[0052] The percentages by weight of each chemical component in the mold flux prepared in this example are: Al 2 o 3 5.2~6.9%, SiO 2 30~32.2%, Fe 2 o 3 2.0~2.5%, CaO 23.8~26.1%, Na 2 O 6.0~8.2%, F - 3.0~4.0%, C 固定 10.6-12.1%, BaO 0.95-1.1%. Chemical index: Alkalinity is 0.79-0.84, melting point is 1130°C, viscosity is 0.42Pa·s (1300°C), particle size is 0.15-1mm and over 90%.

[0053] During the use of the mold powder prepared in this implementation, it is used to add less and more ti...

Embodiment 3

[0056] The pre-melted billet mold powder of the present invention is represented by weight percentage. The raw material composition of the pre-melted billet mold powder is: 63% premelt, 8% wollastonite, 5% fluorite %, sodium carbonate 7%, carbonaceous material 4% (graphite 3% and carbon black 1%), bentonite 3%, quartz 6%, lithium carbonate 2% and dextrin 2%;

[0057] In terms of weight percent, the raw material composition of the premelt is: 68% red mud, 8% quartz, 12% calcite, 4% clay and 8% barium sulfate.

[0058] The percentages by weight of each chemical component in the mold flux prepared in this example are: Al 2 o 3 3.4~4.2%, SiO 2 30~35%, Fe 2 o 3 2.0~2.3%, CaO 29~32%, Na 2 O 6.5~8.2%, F - 4.8~7.2%, C 固定 3-6%, BaO 1.2-1.6%. Chemical index: Alkalinity is 0.85-0.88, melting point is 1200°C, viscosity is 0.2-0.6Pa·s (1300°C), particle size is 0.15-1mm above 90%.

[0059] During the use of the mold powder prepared in this implementation, it is used to add le...

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PUM

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Abstract

The invention discloses a pre-molten type square billet crystallizer casting powder and a preparation method thereof. The pre-molten type square billet crystallizer casting powder is composed of the raw materials, by weight percentage, 60-80% of premelting agent, 4-14% of wollastonite, 2-5% of fluorite, 3-8% of sodium carbonate, 4-8% of carbonaceous materials, 0-3% of bentonite, 2% of dextrin, 0-8% of quartz and 0-3% of lithium carbonate, wherein the premelting agent is composed of 60-70% of red mud, 6-24% of quartz, 4-12% of calcite, 2-4% of clay and 2-8% of barium sulfate. The preparation method comprises adding the raw materials into water for uniform mixing; performing ball milling; performing atomizing, drying and prilling after ball milling to obtain the pre-molten type square billet crystallizer casting powder. According to the pre-molten type square billet crystallizer casting powder and the preparation method thereof, the red mud is applied to the crystallizer casting powder and reaches an adding quantity up to 50%, so that a breakthrough on the application quantity of recycled waste red mud can be achieved; meanwhile, the square billet casting powder prepared through the premelting agent is uniform in component, stable in melting performance and relatively low in cost.

Description

technical field [0001] The invention belongs to the technical field of metallurgical auxiliary materials, in particular to a mold powder for a premelted billet mold and a preparation method thereof. Background technique [0002] my country is one of the countries with the highest dependence on energy in the world, among which coal accounts for about 75% of the total energy resources, and has an important strategic position in the national economy. Saving coal resources is of great strategic significance to ensure the stable development of the national economy. During the "Twelfth Five-Year Plan" period, my country's development is still in an important period of strategic opportunities where great achievements can be made. With the acceleration of industrialization and urbanization and the continuous upgrading of the consumption structure, my country's energy demand has shown a rigid growth. Due to the constraints of domestic resource guarantee capacity and environmental ca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22D11/111
Inventor 张景倚张会敏郑化张志明
Owner 郑州市裕丰耐火材料有限公司
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