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Acid-proof cathode electrophoretic paint as well as preparation method and application method

A cathodic electrophoretic coating and reaction technology, which is applied in the direction of electrophoretic coating, electrolytic coating, electrophoretic plating, etc., and can solve problems such as blistering, insufficient acid resistance of the coating film, and peeling off of the coating film

Active Publication Date: 2014-06-18
湖南伟邦汽车涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the cathodic electrophoretic coatings of the prior art have the following deficiencies: since epoxy resins are generally modified with amines in the water-based process, the acid resistance of the coating film is insufficient. my country's current cathodic electrophoretic coatings standard HG / T 3952- In 2007, the regulations on acid resistance are only 24 hours soaked in 5% sulfuric acid solution without any abnormalities. If soaked for 2-3 days, blistering and peeling of the coating film will occur, which is far from meeting the anti-corrosion performance requirements of petroleum pipelines and other industries.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Embodiment 1 preparation of auxiliary agent

[0033] Mix monoethanolamine and methyl isobutyl ketone with a weight ratio of 0.9:1 in a reaction kettle, and under the protection of stirring and passing through nitrogen, heat up to 109°C and start reflux; continue to heat up to 148°C for 3 hours to undergo ketone-amine condensation reaction , when the temperature is lowered to 60°C, add monoethanolamine 3wt% methyl isobutyl ketone, and then lower the temperature to 35°C to prepare additives.

Embodiment 2

[0034] Embodiment 2 preparation of amine-modified epoxy resin

[0035] 41 parts by weight of epoxy resin EP828, 16 parts by weight of bisphenol A, and 0.58 parts by weight of methyl isobutyl ketone are mixed in a reaction kettle, and the temperature is raised to 110°C under stirring and nitrogen protection, and the temperature is kept until bisphenol A is dissolved Finally, add 0.73 parts by weight of ethyl pentaacetone to undergo epoxy polymerization, continue to heat up to 130°C, and react at 130°C for 1 hour and 40 minutes to viscosity: 2.4S (sample / ethylene glycol butyl ether=20g / 20g), EP value: 0.79meq / g (1g viscosity sample, NV=100%); add 8.76 parts by weight of ethyl pentaacetone, raise the temperature to 150°C, and react at 150°C for 2 hours until viscosity: 8.1S (sample / ethylene glycol butyl Ether = 20g / 20g ), EP value: 0.48meq / g (1g viscosity sample, NV=100%), water-soluble amine value: below 2.1 (2g viscosity sample, NV=100%); add 11.68 parts by weight of ethylene g...

Embodiment 3

[0036] Embodiment 3 preparation of amine-modified epoxy resin

[0037] Mix 50 parts by weight of epoxy resin 850S, 21 parts by weight of bisphenol A, and 0.73 parts by weight of methyl isobutyl ketone in a reaction kettle, heat up to 115°C under stirring and nitrogen protection, and keep warm until bisphenol A dissolves Finally, add 0.91 parts by weight of ethyl pentaacetone to generate epoxy polymerization reaction, continue to heat up to 130°C, and react at 130°C for 1 hour and 50 minutes to viscosity: 4.03S (sample / ethylene glycol butyl ether=20g / 20g), EP value: 0.94meq / g (1g viscosity sample, NV=100%); add 11 parts by weight of ethyl pentaacetone, raise the temperature to 150°C, and react at 150°C for 2 hours until viscosity: 13.0S (sample / ethylene glycol butyl Ether = 20g / 20g ), EP value: 0.52meq / g (1g viscosity sample, NV=100%), water-soluble amine value: below 2.1 (2g viscosity sample, NV=100%); add 14.5 parts by weight of ethylene glycol Butyl ether terminates the epo...

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PUM

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Abstract

The invention discloses an acid-proof cathode electrophoretic paint as well as a preparation method and an application method. The electrophoretic paint comprises emulsion and color paste, wherein the emulsion is prepared by steps of mixing amine modified epoxy resin, a totally-closed isocyanate cross-linking agent and an emulsifying agent, uniformly stirring at the temperature of 43 DEG C to 47 DEG C, adding formic acid at the temperature of 45 DEG C to 49 DEG C to perform an acidification reaction for more than 70 minutes, subsequently adding deionized water, uniformly stirring and then filtering. The color paste is prepared by the steps of mixing quaternary ammonium dispersion resin, deionized water, dibutyl tin oxide, kaolin, carbon black, an emulsifying agent, rutile titanium dioxide and titanium-based nanometer paste, uniformly stirring at the temperature not higher than 30 DEG C, grinding the mixture at the temperature not higher than 35 DEG C by use of a grinder until the fineness is not larger than 15 microns, uniformly stirring and filtering. An application process comprises batching, preparation of a tank and an electrophoretic coating process; the preparation of the tank comprises steps of mixing 10-15 parts by weight of the color paste, 35-40 parts by weight of the emulsion and 50-75 parts by weight of the deionized water, and curing for 48-50 hours at the temperature of 28-30 DEG C; and the electrophoretic coating process comprises a step of performing electrophoresis to a to-be-coated element for 3-4 minutes under the voltage of 200V.

Description

technical field [0001] The invention relates to the technical field of cathodic electrophoretic paint, in particular to an acid-resistant cathodic electrophoretic paint, a preparation method and an application method. Background technique [0002] Cathodic electrophoretic coatings are widely used, and the proportion is mainly epoxy resin as the main film-forming substance, which has good corrosion resistance. [0003] However, the cathodic electrophoretic coatings of the prior art have the following deficiencies: since epoxy resins are generally modified with amines in the water-based process, the acid resistance of the coating film is insufficient. my country's current cathodic electrophoretic coatings standard HG / T 3952- In 2007, the regulations on acid resistance are only 24 hours soaked in 5% sulfuric acid solution without abnormalities. If soaked for 2-3 days, blistering and peeling of the coating film will occur, which is far from meeting the anti-corrosion performance ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D5/44C09D5/08C09D17/00C25D13/06
Inventor 刘颂东裴俊
Owner 湖南伟邦汽车涂料有限公司
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