Acid-proof cathode electrophoretic paint as well as preparation method and application method
A cathodic electrophoretic coating and reaction technology, which is applied in the direction of electrophoretic coating, electrolytic coating, electrophoretic plating, etc., and can solve problems such as blistering, insufficient acid resistance of the coating film, and peeling off of the coating film
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Embodiment 1
[0032] Embodiment 1 preparation of auxiliary agent
[0033] Mix monoethanolamine and methyl isobutyl ketone with a weight ratio of 0.9:1 in a reaction kettle, and under the protection of stirring and passing through nitrogen, heat up to 109°C and start reflux; continue to heat up to 148°C for 3 hours to undergo ketone-amine condensation reaction , when the temperature is lowered to 60°C, add monoethanolamine 3wt% methyl isobutyl ketone, and then lower the temperature to 35°C to prepare additives.
Embodiment 2
[0034] Embodiment 2 preparation of amine-modified epoxy resin
[0035] 41 parts by weight of epoxy resin EP828, 16 parts by weight of bisphenol A, and 0.58 parts by weight of methyl isobutyl ketone are mixed in a reaction kettle, and the temperature is raised to 110°C under stirring and nitrogen protection, and the temperature is kept until bisphenol A is dissolved Finally, add 0.73 parts by weight of ethyl pentaacetone to undergo epoxy polymerization, continue to heat up to 130°C, and react at 130°C for 1 hour and 40 minutes to viscosity: 2.4S (sample / ethylene glycol butyl ether=20g / 20g), EP value: 0.79meq / g (1g viscosity sample, NV=100%); add 8.76 parts by weight of ethyl pentaacetone, raise the temperature to 150°C, and react at 150°C for 2 hours until viscosity: 8.1S (sample / ethylene glycol butyl Ether = 20g / 20g ), EP value: 0.48meq / g (1g viscosity sample, NV=100%), water-soluble amine value: below 2.1 (2g viscosity sample, NV=100%); add 11.68 parts by weight of ethylene g...
Embodiment 3
[0036] Embodiment 3 preparation of amine-modified epoxy resin
[0037] Mix 50 parts by weight of epoxy resin 850S, 21 parts by weight of bisphenol A, and 0.73 parts by weight of methyl isobutyl ketone in a reaction kettle, heat up to 115°C under stirring and nitrogen protection, and keep warm until bisphenol A dissolves Finally, add 0.91 parts by weight of ethyl pentaacetone to generate epoxy polymerization reaction, continue to heat up to 130°C, and react at 130°C for 1 hour and 50 minutes to viscosity: 4.03S (sample / ethylene glycol butyl ether=20g / 20g), EP value: 0.94meq / g (1g viscosity sample, NV=100%); add 11 parts by weight of ethyl pentaacetone, raise the temperature to 150°C, and react at 150°C for 2 hours until viscosity: 13.0S (sample / ethylene glycol butyl Ether = 20g / 20g ), EP value: 0.52meq / g (1g viscosity sample, NV=100%), water-soluble amine value: below 2.1 (2g viscosity sample, NV=100%); add 14.5 parts by weight of ethylene glycol Butyl ether terminates the epo...
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