Unlock instant, AI-driven research and patent intelligence for your innovation.

Method for preparing superhydrophobic surfaces by biomineralization

A technology of super-hydrophobic surface and biomineralization, which is applied to the device of coating liquid on the surface, special surface, ion implantation plating, etc., which can solve the problem of less research and application of super-hydrophobic surface

Inactive Publication Date: 2016-06-22
JIANGYIN POLYTECHNIC COLLEGE
View PDF1 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the research on simulating biomineralization in vitro focuses on using various templates to regulate the morphology and crystal form of inorganic minerals, so that people can easily prepare various inorganic minerals with complex shapes, but using this green, environmentally friendly However, there are still few researches and applications on the preparation of superhydrophobic surfaces by biomineralization with low energy consumption.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for preparing superhydrophobic surfaces by biomineralization
  • Method for preparing superhydrophobic surfaces by biomineralization
  • Method for preparing superhydrophobic surfaces by biomineralization

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Step 1. Wash the surface of the PP substrate with absolute ethanol and acetone in sequence, then dry it, then soak it in 20wt% nitric acid for 5 hours, and finally wash it with deionized water and dry it;

[0029] Step 2. Soak the surface of the pretreated PP substrate into the pre-prepared barium chloride mineralization solution with a concentration of 5mg / ml, and add a polyacrylic acid solution with a concentration of 1mg / ml (polyacrylic acid is mixed with mineral The concentration in the solution is 0.05mg / ml), and then put the solution soaked in the glass substrate and ammonium carbonate in a closed container. After standing at room temperature for 2 hours, take out the PP substrate, rinse it with deionized water and dry it. , to obtain a solid surface with a micro-nano secondary rough structure, ready for use;

[0030] Step 3: Coat the surface of the prepared PP substrate with a rough structure with a layer of gold by ion sputtering for one minute, and then put it ...

Embodiment 2

[0032] Step 1, washing the surface of the metal iron substrate with absolute ethanol and acetone in turn, drying, then soaking in 80wt% sulfuric acid for 1 hour, and finally washing with deionized water and drying;

[0033] Step 2. Next, soak the surface of the pretreated metal iron substrate into the magnesium chloride mineralization solution with a concentration of 10 mg / ml prepared in advance, and add a polysulfonated styrene solution (polysulfonated benzene) with a concentration of 1 mg / ml. The concentration of ethylene in the mixed mineralization solution is 0.1mg / ml), and then the solution soaked with glass substrate and ammonium carbonate is placed in a closed container, and after 12 hours at room temperature, the metallic iron substrate is taken out and used Rinse with deionized water and dry to obtain a solid surface with a micron-nano secondary rough structure, ready for use.

[0034] Step 3: Coat the surface of the prepared metal iron substrate with a rough structur...

Embodiment 3

[0036] Step 1. Wash the surface of the PET substrate successively with absolute ethanol and acetone, then dry it, then soak it in 35wt% hydrochloric acid for 2 hours, and finally wash it with deionized water and dry it;

[0037] Step 2. Soak the surface of the pretreated PET substrate into the pre-prepared mineralization solution of calcium hydrogen phosphate with a concentration of 5 mg / ml, and add a solution of polyvinyl alcohol and polyaspartic acid with a concentration of 0.5 mg / ml (The concentration of both in the mixed mineralization solution is 0.05mg / ml), and then put the solution soaked with PET matrix and ammonium carbonate in a closed container, and after 6 hours at room temperature, take out the PET matrix , washed with deionized water and then dried to obtain a solid surface with a micron-nano secondary rough structure, ready for use.

[0038] Step 3: Coat the surface of the prepared PET matrix with a rough structure by ion sputtering for one minute, and then put ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a method for preparing a super-hydrophobic surface through a biomineralization method, comprising the following steps: step 1, washing the solid surface with absolute ethanol and acetone in sequence, drying, then soaking in inorganic acid, and finally using deionized Drying after washing with water; step 2, soak the pretreated solid surface into the mineralization solution, and add a mineralization regulator, and then place the solution soaked with the solid surface together with ammonium carbonate in a closed container at room temperature After standing for a period of time, take out the solid surface, rinse it with deionized water, and dry it to obtain a solid surface with a micron-nano secondary rough structure, which is ready for use; step 3, pass the solid surface with a rough structure through ionized water for one minute. A layer of gold is coated on the surface by sputtering, and then soaked in an ethanol solution whose solute is thiol. Finally, the solid surface is taken out and washed with absolute ethanol and dried to obtain a superhydrophobic surface with self-cleaning function.

Description

technical field [0001] The invention relates to a solid surface treatment technology, in particular to a method for preparing a superhydrophobic surface with a self-cleaning function by using a biomineralization method. Background technique [0002] It is generally considered that the contact angle of a water drop on a solid surface is greater than 150 o A solid surface is said to be superhydrophobic when it does not easily roll off the surface. There are a lot of strange natural super-hydrophobic surfaces in nature, such as the leaves of rice, the shells of beetles in the desert, the wings of butterflies and the soles of geckos, etc. With the in-depth study and understanding of these natural superhydrophobic phenomena, it has been found that the combination of multi-level rough structures and low surface energy coatings is a common feature of these superhydrophobic surfaces. A typical example that has been extensively studied is the surface of the lotus leaf. Its unique s...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/34C23C14/58C23C14/14B05D5/02
Inventor 徐娜沈澄英陆敏
Owner JIANGYIN POLYTECHNIC COLLEGE