Method for preparing superhydrophobic surfaces by biomineralization
A technology of super-hydrophobic surface and biomineralization, which is applied to the device of coating liquid on the surface, special surface, ion implantation plating, etc., which can solve the problem of less research and application of super-hydrophobic surface
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Embodiment 1
[0028] Step 1. Wash the surface of the PP substrate with absolute ethanol and acetone in sequence, then dry it, then soak it in 20wt% nitric acid for 5 hours, and finally wash it with deionized water and dry it;
[0029] Step 2. Soak the surface of the pretreated PP substrate into the pre-prepared barium chloride mineralization solution with a concentration of 5mg / ml, and add a polyacrylic acid solution with a concentration of 1mg / ml (polyacrylic acid is mixed with mineral The concentration in the solution is 0.05mg / ml), and then put the solution soaked in the glass substrate and ammonium carbonate in a closed container. After standing at room temperature for 2 hours, take out the PP substrate, rinse it with deionized water and dry it. , to obtain a solid surface with a micro-nano secondary rough structure, ready for use;
[0030] Step 3: Coat the surface of the prepared PP substrate with a rough structure with a layer of gold by ion sputtering for one minute, and then put it ...
Embodiment 2
[0032] Step 1, washing the surface of the metal iron substrate with absolute ethanol and acetone in turn, drying, then soaking in 80wt% sulfuric acid for 1 hour, and finally washing with deionized water and drying;
[0033] Step 2. Next, soak the surface of the pretreated metal iron substrate into the magnesium chloride mineralization solution with a concentration of 10 mg / ml prepared in advance, and add a polysulfonated styrene solution (polysulfonated benzene) with a concentration of 1 mg / ml. The concentration of ethylene in the mixed mineralization solution is 0.1mg / ml), and then the solution soaked with glass substrate and ammonium carbonate is placed in a closed container, and after 12 hours at room temperature, the metallic iron substrate is taken out and used Rinse with deionized water and dry to obtain a solid surface with a micron-nano secondary rough structure, ready for use.
[0034] Step 3: Coat the surface of the prepared metal iron substrate with a rough structur...
Embodiment 3
[0036] Step 1. Wash the surface of the PET substrate successively with absolute ethanol and acetone, then dry it, then soak it in 35wt% hydrochloric acid for 2 hours, and finally wash it with deionized water and dry it;
[0037] Step 2. Soak the surface of the pretreated PET substrate into the pre-prepared mineralization solution of calcium hydrogen phosphate with a concentration of 5 mg / ml, and add a solution of polyvinyl alcohol and polyaspartic acid with a concentration of 0.5 mg / ml (The concentration of both in the mixed mineralization solution is 0.05mg / ml), and then put the solution soaked with PET matrix and ammonium carbonate in a closed container, and after 6 hours at room temperature, take out the PET matrix , washed with deionized water and then dried to obtain a solid surface with a micron-nano secondary rough structure, ready for use.
[0038] Step 3: Coat the surface of the prepared PET matrix with a rough structure by ion sputtering for one minute, and then put ...
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