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Preparation technology of water-based PU (Polyurethane) glue substituting solvent type printing ink TPU (Thermoplastic Polyurethane)

A preparation process, solvent-based technology, applied in the field of water-based PU adhesive preparation process, can solve the problems of many residual solvents, single color, limited flexibility, etc.

Inactive Publication Date: 2014-06-25
SHISHI DECAI CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although most of the organic solvents can be removed by drying, but because the pigment particles in the ink are very fine and have strong adsorption capacity, coupled with the short heating and drying time, the drying is often not complete, especially when the ink area is large, Prints with a thicker ink layer have more residual solvents, which are more difficult to release after compounding
Moreover, the residual solvent will slowly migrate and infiltrate, causing pollution to materials and endangering people's health.
At the same time, the color of traditional solvent-based TPU ink is single during use, which greatly limits the flexibility of its application.
Therefore, the existing solvent-based ink TPU has the problem of pollution to the environment, and the problem of single color during use
In addition, the shoe fabrics using solvent-based ink TPU glue will have solvent pollutants volatilized during the drying process, so it needs to be changed

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Slowly stir 26.4kg of acrylic resin in a dispersion tank at normal temperature and pressure, and adjust its pH value to 8 by adding ammonia water.

[0017] Put 30kg of polyurethane aqueous dispersion (Impranit DL1537XP), 25kg of polyurethane aqueous dispersion (ADEKA HUX-280), 2kg of propylene glycol methyl ether acetate, 2kg of ethylene glycol butyl ether, and wetting defoamer (Surfynol 104E) into the dispersion tank in turn. ) 1kg, silicon defoamer (Dehydran 12930) 4kg, leveling wetting agent (BYK346) 0.3kg, slip agent (BYK333) 0.25kg, matte powder 2kg, elastomer 2kg, wear agent 3kg, thickener (PTF) 0.2kg, thickener (Viscdam Ps166) 0.4kg, deionized water 2.45kg, continue to disperse for 1 hour.

[0018] After dispersing, heat it to 80°C, and at the same time, use a vacuum pump to continuously evacuate the inside of the tank, and keep the air pressure in the tank at 0.8 negative pressure for 0.5 hours.

[0019] Then inject cooling circulating water into the outer wall...

Embodiment 2

[0021] Slowly stir 30kg of acrylic resin in a dispersion tank at normal temperature and pressure, and add ammonia water to adjust its pH value to 8.

[0022] Put 25kg of polyurethane aqueous dispersion (Impranit DL1537XP), 26kg of polyurethane aqueous dispersion (ADEKA HUX-280), 2kg of propylene glycol methyl ether acetate, 1kg of ethylene glycol butyl ether, and wetting defoamer (Surfynol 104E) into the dispersion tank in turn. ) 3kg, silicon defoamer (Dehydran 12930) 6kg, leveling wetting agent (BYK346) 0.3kg, slip agent (BYK333) 0.2kg, matte powder 1kg, elastomer 1kg, wear agent 2kg, thickener (PTF) 0.2kg, thickener (Viscdam Ps166) 0.1kg, deionized water 2.2kg, continuous dispersion for 1 hour.

[0023] After dispersing, heat it to 80°C, and at the same time, use a vacuum pump to continuously evacuate the inside of the tank, and keep the air pressure in the tank at 0.8 negative pressure for 0.5 hours.

[0024] Then inject cooling circulating water into the outer wall of th...

Embodiment 3

[0026] Slowly stir 24kg of acrylic resin in a dispersion tank at normal temperature and pressure, and add ammonia water to adjust its pH value to 8.

[0027] Put 31kg of polyurethane aqueous dispersion (Impranit DL1537XP), 23kg of polyurethane aqueous dispersion (ADEKA HUX-280), 1kg of propylene glycol methyl ether acetate, 2kg of ethylene glycol butyl ether, and wetting defoamer (Surfynol 104E) into the dispersion tank in turn. ) 1kg, silicon defoamer (Dehydran 12930) 2kg, leveling wetting agent (BYK346) 1kg, slip agent (BYK333) 1kg, matting powder 2kg, elastomer 2kg, wear agent 3kg, thickener (PTF ) 1kg, thickener (Viscdam Ps166) 1kg, deionized water 3kg, continue to disperse for 1 hour.

[0028] After dispersing, heat it to 80°C, and at the same time, use a vacuum pump to continuously evacuate the inside of the tank, and keep the air pressure in the tank at 0.8 negative pressure for 0.5 hours.

[0029] Then inject cooling circulating water into the outer wall of the disper...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention relates to a preparation technology of water-based PU (Polyurethane) glue substituting solvent type printing ink TPU (Thermoplastic Polyurethane). The technology is characterized by comprising the following steps: slowly stirring 24-30% of acrylic resin in a dispersion tank at normal temperature and pressure state, adding ammonium hydroxide for regulating the pH value to 7-8; sequentially feeding a polyurethane aqueous dispersion, propylene glycol monomethyl acetate, ethylene glycol butyl ether and the like into the dispersion tank, and continuously dispersing for one hour; after the dispersion is over, heating, continuously vacuumizing the tank through a vacuum pump, injecting cooling circulation water to the outer wall of the dispersion tank under the condition that the pressure in the tank is maintained at the negative pressure state of 0.8-1Pa, cooling the temperature to 50DEG C below, releasing the negative pressure in the tank to be normal pressure, filtering through a vacuum filtering machine, to obtain the printing ink TPU water-based PU glue. The product can be used as a printing ink in the ink printing technology of a TPU shoe material. Furthermore, no pollutant solvent is volatized in the process of drying shoe shell fabric using the water-based PU glue, and patterns are colorful.

Description

technical field [0001] The invention relates to a process for preparing water-based PU glue, in particular to a process for preparing water-based PU glue that replaces solvent-based ink TPU. Background technique [0002] The Chinese name of TPU is thermoplastic polyurethane elastomer. It is a polymer material with excellent high tension, high tensile strength, toughness and aging resistance. It is a mature environmental protection material. At present, TPU materials are widely used in automobile manufacturing, home appliance manufacturing, transportation, civil engineering, shoe materials, synthetic leather and other fields. [0003] TPU material has been widely used in the field of shoe materials. Because of its good cushioning performance, light weight, wear resistance, and anti-skid, it has become an important supporting material in the shoe material industry. [0004] Shoe material ink refers to the coating ink used on the sole, also called sole paint. As one of many i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L33/00C09D11/107C09D11/102
Inventor 朱爱红卢少欣颜宗政
Owner SHISHI DECAI CHEM TECH
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