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Plastic adhesion layer cleaning agent as well as plastic cleaning process and equipment adopting same

A technology for cleaning and attaching layers of plastics, applied in the fields of plastic recycling, detergent compositions, soap detergent compositions, etc., can solve the problems of non-recycling for one-time use, health hazards for operators, and reducing the quality of recycled plastics, and achieves a Conducive to metal recovery, economical and practical quality, and the effect of reducing process costs

Active Publication Date: 2014-07-16
天津市生态环境科学研究院
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The solvents of existing organic paint removers mainly contain dichloromethane, ethyl acetate, acetone, benzene, toluene, chloroform, etc., but the organic paint removers still have the following problems in use: (1) by dissolving and chemical reaction to remove paint , which is a consumable agent, has fast failure and cannot be recycled for one-time use, which not only increases the process cost, but also pollutes the environment; ⑵Because of its solubility in plastics, it modifies plastics and reduces the quality of recycled plastics; ⑶The above organic paint removal The agent can only remove the paint layer and ink layer, but cannot remove the above-mentioned metal foil layer, adhesive layer and protective film layer; (4) low boiling point, volatile, and large loss; (5) strong Odor, harmful to the health of operators
Therefore, how to develop a cleaning agent that can simultaneously remove the paint layer, ink layer and other material adhesion layers and overcome the above-mentioned organic paint remover's rapid failure, non-recyclable, polluting environment, volatile and strong odor for the above defects The shortcomings of the industry have become a concern in the industry

Method used

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  • Plastic adhesion layer cleaning agent as well as plastic cleaning process and equipment adopting same
  • Plastic adhesion layer cleaning agent as well as plastic cleaning process and equipment adopting same
  • Plastic adhesion layer cleaning agent as well as plastic cleaning process and equipment adopting same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Using the plastic cleaning process of plastic adhesion layer cleaning agent, the processed plastics are colorless and transparent PC (polycarbonate) waste DVDs and CDs. They were purchased from a waste plastic distribution center in Xingtan County, Shunde City, Guangdong Province. The ink needs to be cleaned off layer, aluminum foil layer, anti-oxidation protective film layer. The cleaning process includes the following steps:

[0054] (1) Configure 100kg of cleaning agent, and take materials according to the proportion of each component in Example 1 in Table 1. The preparation steps are: ① Dissolve 6 kg of main solvent dimethyl sulfoxide in 25 kg of co-solvent, 9.5 kg of ethanol, benzene Methanol 7.5kg, ethylene glycol butyl ether 8kg; ②Dissolve activator sodium hydroxide 1kg, thickener methyl cellulose 2kg, surfactant sodium dodecylbenzene sulfonate 1kg in 65kg water; ③Step ① Mix with the solution obtained in step ② to prepare 100Kg of cleaning agent.

[0055] (2) C...

Embodiment 2

[0060] In this embodiment, the types, processing items and sources of plastics with an adhesive layer to be processed are the same as those in Embodiment 1. The plastic cleaning process includes the following steps:

[0061] (1) prepare plastic adhesion layer cleaning agent, preparation method is the same as embodiment 1, and difference is to take material according to each component ratio of embodiment 2 in table 1, main solvent dimethyl sulfoxide 10kg, auxiliary solvent 32kg, wherein ethanol 16kg, Benzyl alcohol 7.68kg, ethylene glycol butyl ether 8.32kg; activator sodium hydroxide 2kg, thickener methylcellulose 3kg, surfactant sodium dodecylbenzenesulfonate 1.5kg, water 51.5kg.

[0062] Thereafter, the plastic cleaning process is the same as that of Example 1 except for the following steps: in step (2), put the plastic fragments and cleaning agent into the reactor 5, seal and heat to 70° C. and stir for 30 minutes.

Embodiment 3

[0064] The type, processing item and source of the plastic with an adhesive layer to be processed in this embodiment are the same as in Embodiment 1. The plastic cleaning process includes the following steps:

[0065] (1) prepare plastic adhesion layer cleaning agent, preparation method is the same as embodiment 1, and difference is to take materials according to the ratio of each component in embodiment 3 in table 1, main solvent dimethyl sulfoxide 12kg, auxiliary solvent 38kg, wherein: ethanol 16.72 kg, benzyl alcohol 13.68kg, ethylene glycol butyl ether 7.6kg, activator sodium hydroxide 3kg, thickener methylcellulose 4kg, surfactant sodium dodecylbenzenesulfonate 2kg, water 41kg.

[0066] Thereafter, the plastic cleaning process is the same as in Example 1 except for the following steps: in step (2), put the plastic fragments and cleaning agent into the reactor 5, seal and heat to 65° C. and stir for 40 minutes.

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Abstract

The invention relates to a plastic adhesion layer cleaning agent as well as a plastic cleaning process and equipment adopting the same. The cleaning agent comprises the following components in percentage by mass: 6-12 percent of a master solvent, 25-38 percent of a cosolvent, 1-3 percent of an activating agent, 2-4 percent of a thickener, 1-2 percent of a surfactant and the balance of water, wherein the master solvent is dimethyl sulfoxide or propylene carbonate; the cosolvent comprises the following components in percentage by mass: 38-50 percent of monohydric alcohol or polyhydric alcohol, 24-36 percent of phenylcarbinol and 20-32 percent of polyhydric alcohol ether. The cleaning process comprises the following steps: crushing plastic to form plastic fragments; putting the plastic fragments and the cleaning agent into a reaction kettle according to a mass ratio of 1: 2; heating to 65-75 DEG C in a sealed manner and stirring for 20-40 minutes; leading the cleaning agent out for recycling; separating and dehydrating the plastic fragments and stripped substances of the adhesion layer to obtain a recycled plastic finished-product; and periodically extracting liquid in a separating tank and recovering the cleaning agent. The equipment comprises the reaction kettle, the separating tank, an extracting pot, a liquid storage pot and a reflux condenser.

Description

technical field [0001] The invention relates to the technical field of plastic recycling, in particular to a plastic adhesive layer cleaning agent, a plastic cleaning process and cleaning equipment using the cleaning agent. Background technique [0002] With the development of the plastics industry, plastics with different properties are widely used as important raw materials in machinery, electronics, medical care, and various fields of life, such as optical discs, electrical device housings, auto parts, building pipes, plates, household appliances and toys, etc. ; Since waste plastics contain high-end plastics and a large amount of ordinary plastic production raw materials, they have huge potential economic value, and at the same time, they themselves constitute environmental problems. Therefore, the recycling of a large number of waste plastic products has also become a critical issue for resource reuse. However, since many plastic products are attached with an adhesive l...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C11D10/02C09D9/04C08J11/04B29B17/00
CPCY02P20/143Y02W30/62
Inventor 焦永杰刘畅邓小文陈红袁雪竹马建立霍宁李晓光张良运杨静张晓惠董菁
Owner 天津市生态环境科学研究院
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