Preparation method for composite material of hydrophilic fullerene derivative and metallic oxide

A technology of fullerene derivatives and composite materials, which is applied in the field of preparation of hydrophilic fullerene derivatives and metal oxide composite materials, can solve the problem of free radical removal and achieve the effect of improving stability

Inactive Publication Date: 2014-08-06
BEIJING JIANSIN TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Some free radicals produced by smoking can be removed by filters, but there are still many kinds of free radicals th...

Method used

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  • Preparation method for composite material of hydrophilic fullerene derivative and metallic oxide
  • Preparation method for composite material of hydrophilic fullerene derivative and metallic oxide
  • Preparation method for composite material of hydrophilic fullerene derivative and metallic oxide

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Embodiment

[0026] 1. In one embodiment, the C 60 (1g), 1,8-diazabicycloundec-7-ene (DBU, 0.2g), diethyl bromomalonate (0.35g) were dissolved in toluene solution (500mL), stirred at room temperature for 5 hours, use toluene as eluent to separate on silica gel chromatography to obtain molecular formula C 61 (COOCH 2 CH 3 ) 2 product of. Will C 61 (COOCH 2 CH 3 ) 2 (0.5g), p-toluenesulfonic acid (0.2g), triethylene glycol monomethyl ether (0.2g) were dissolved in toluene solution (200mL), refluxed and stirred for 24 hours, and separated by silica gel chromatography to obtain molecular formula C 61 [CO(OCH 2 CH 3 ) 3 OCH 3 ] 2 The target product, structural formula is:

[0027]

[0028] 2. In one embodiment, the C 61 [CO(OCH 2 CH 3 ) 3 OCH 3 ] 2 (0.1g) was dispersed in ethanol and water mixed solution (v / v=1: 9, 100mL), slowly added dropwise the ethanol solution of titanium tetrachloride (20g), obtained sol-gel, then dried to obtain the nanopowder of composite material...

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Abstract

Fullerene derivatives are widely applied to solar cells, cosmetics, biological medicine and other aspects; metallic oxides are applied to catalysis, semiconductor devices, energy storage and other aspects due to the advantages of good stability, easiness for preparation, controllable morphology and the like. The invention provides a preparation method for preparing a composite material by mixing a hydrophilic fullerene derivative with titanium dioxide, zinc oxide, aluminium oxide and other inorganic oxides. A flexible ether oxygen chain contained in the fullerene derivative disclosed by the invention is used for providing a hydrophilic group and improving the compatibility of the hydrophilic group and the oxide; in addition, polyvinyl alcohol and polyvinylpyrrolidone polymer are introduced as a thickening agent and a film forming agent. The composite materials can be prepared into nano-powder body, films or porous materials, have the advantages of high stability and strength, controllable morphology, easiness for processing and the like and can be used as plates, films, coatings, filling particles and the like for clearing free radicals in smog or atmosphere, resisting bacteria and being taken as battery active layers and the like.

Description

technical field [0001] The invention relates to a method for preparing a composite material of hydrophilic fullerene derivatives and metal oxides. Background technique [0002] Fullerene is the third allotrope of carbon discovered in 1985 after diamond and graphite. C 60 The molecule is aromatic, and its unique molecular structure and physical and chemical properties make fullerenes widely used in many fields such as semiconductors, catalysts, battery materials, lubricants, and biomedicine. [0003] The large conjugated system of fullerene makes it have a special ability to absorb free radicals, such as hydroxyl radicals, alkyl carbon radicals, superoxide anion radicals, etc. In the human body, free radicals play an important role in metabolism and life activities. In modern society, with the increase of pressure, the intensification of various electromagnetic radiation, and the excessive use of chemicals, the level of free radicals in the human body far exceeds the norma...

Claims

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Application Information

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IPC IPC(8): C08L29/04C08K3/22C08K5/10C08J5/18C07C69/753C07C69/616C07C67/31
Inventor 刘文增王太山王春儒李志波
Owner BEIJING JIANSIN TECH
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