High-flowability plastic composite powder material and preparation method thereof

A composite powder, high fluidity technology, applied in the field of plastic composite materials, can solve the problems of low laser power density and cannot be completely absorbed by plastic materials, etc., to enhance mechanical properties and thermal stability, increase fluidity and laser energy. Absorption efficiency, the effect of solving poor fluidity

Inactive Publication Date: 2014-10-22
CHONGQING INST OF GREEN & INTELLIGENT TECH CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The energy used for plastic molding is CO2 laser. During the molding process, the laser high-energy light speed is used to selectively scan the material. The laser energy absorbed by the powder material collides with the basic energy particles inside the powder material through laser photons, so that the temperature of the material after absorbing light energy Raise, the energy is converted into heat energy in a very short moment and gradually transferred to the inside; the laser beam with sufficient power density quickly heats the surface of the material to make it reach the desired temperature and melt, and the heat is transferred in the powder after melting; but The inside of the material is basically kept in a cooling state, mainly because the energy emitted by the laser beam cannot be completely absorbed by the plastic material, and part of the light energy is reflected by the surface of the material, resulting in a low laser power density radiated to the surface of the material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] 1) Select 70 parts of PEEK resin powder with an average particle size of 100 μm, and 28 parts of carbon fiber powder with an average particle size of 150 μm, wherein the PEEK resin powder is prepared by jet milling, and the carbon fiber powder is prepared by high-energy ball milling;

[0024] 2) Dissolve 2.5 parts of silane coupling agent in 5-10 times the ethanol solution, then mix the carbon fiber powder in step 1) into the mixed solution, heat for 3 hours, remove the coupling agent and solvent, and dry;

[0025] 3) mixing the PEEK resin powder selected in step 1) and the modified carbon fiber powder in step 2) through a high-speed mixing device to obtain a PEEK resin composite powder material;

[0026] 4) Selective laser sintering method is used to sinter a standard dumbbell-shaped experimental sample.

Embodiment 2

[0028] 1) Select 89 parts of PPS resin powder with an average particle size of 130 μm, and 9 parts of glass fiber powder with an average particle size of 150 μm, wherein the PPS resin powder is prepared by jet milling, and the glass fiber powder is prepared by high-energy ball milling;

[0029] 2) Dissolve 2 parts of titanate coupling agent in 5-10 times the ethanol solution, then mix the glass fiber powder in step 1) into the mixed solution, heat for 3 hours, remove the coupling agent and solvent, drying;

[0030] 3) mixing the PPS resin powder selected in step 1) and the modified glass fiber powder in step 2) through a high-speed mixing device to obtain a PPS resin composite powder material;

[0031] 4) Selective laser sintering method is used to sinter a standard dumbbell-shaped experimental sample.

Embodiment 3

[0033] 1) Select 60 parts of PA12 resin powder with an average particle size of 30 μm, and 38 parts of glass fiber powder with an average particle size of 50 μm, wherein the PA12 resin powder is prepared by jet milling, and the glass fiber powder is prepared by high-energy ball milling;

[0034] 2) Dissolve 2.5 parts of silane coupling agent in 5-10 times the ethanol solution, then mix the glass fiber powder in step 1) into the mixed solution, heat for 3 hours, remove the coupling agent and solvent, and dry ;

[0035] 3) mixing the PA12 resin powder selected in step 1) and the modified glass fiber powder in step 2) through a high-speed mixing device to obtain a PA12 resin composite powder material;

[0036] 4) Selective laser sintering method is adopted to sinter the standard dumbbell-shaped experimental spline;

[0037] The comparison between the composite powder material obtained by the above three methods and the original resin powder in terms of material performance is s...

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Abstract

The invention discloses a high-flowability plastic composite powder material and a preparation method thereof. The composite powder material comprises a plastic matrix material and a fiber-reinforced component, wherein the plastic matrix material is one or more selected from polypropylene (PP), ABS (Acrylonitrile Butadiene Styrene), polyamide, polyimide, poly(aryl ether ketone), polyether sulfone, polyphenylene sulfide and polytetrafluoroethylene; the fiber-reinforced component is one or more selected from glass fiber, carbon fiber, carbon fiber powder, mineral fiber powder, aramid fiber, ceramic fiber and boron fiber; the additive amount of the fiber-reinforced component is 0.01-30%, and the volume fraction of the fiber-reinforced component is 0-40%. According to the preparation method, firstly, the fiber-reinforced component is subjected to coupling modification, and then, the modified fiber-reinforced component is mixed with a plastic powder matrix to obtain the composite powder material, so that the flowability of the plastic powder is enhanced, the laser energy absorption efficiency of the plastic powder is improved, the powder packing density is also increased, and the mechanical performance and heat stability of a sintered material are enhanced. The high-flowability plastic composite powder material is wide in material source, simple in preparation process and very remarkable in effect.

Description

technical field [0001] The invention belongs to the field of plastic composite materials, and relates to a high-fluidity plastic composite powder material and a preparation method thereof. Background technique [0002] Rapid additive manufacturing technology, also known as "3D printing technology", is a new manufacturing technology that is currently receiving high attention. Together with robotics and artificial intelligence, it is called the key technology to promote the third industrial revolution. Selective laser sintering (SLS) is a very important technology in 3D printing. The SLS process is based on the principle of discrete / stacking forming, integrating new technologies such as computer, numerical control, laser and new materials, and selectively sintering metal or non-metal powder materials to quickly prepare products. The laser power required for polymer SLS sintering is small and not limited by the complexity of the shape of the part. It can accurately and quickly...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/16C08L81/02C08L77/02C08K9/06C08K7/06C08K3/04C08K9/04C08K7/14
Inventor 饶先花范树迁段宣明
Owner CHONGQING INST OF GREEN & INTELLIGENT TECH CHINESE ACADEMY OF SCI
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