Technique for recycling heat energy of tail gas of gas-fired boiler and purifying nitric oxide
A heat energy recovery and nitrogen oxide technology, applied in lighting and heating equipment, etc., can solve the problems of low energy saving efficiency and ineffective recovery of latent heat, and achieve the effect of reducing carbon emissions and saving fuel
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[0070] Adsorb NO X The preparation method of the adsorbent: its raw material quality consists of: 20-50% of natural zeolite, 10-55% of attapulgite, and 15-65% of clay; comprising the following steps:
[0071] (1) Crush the natural zeolite to 2-4mm particles, and then use HNO 3 、H 2 SO 4 or HCl treatment, HNO 3 、H 2 SO 4 or HCl, after treatment, dry below 130°C;
[0072] (2) The natural zeolite treated in step (1) is treated with NaOH solution, dried at 130°C after the treatment, and then crushed to more than 200 mesh;
[0073] (3) The attapulgite is crushed to more than 100 mesh;
[0074] (4) Natural clay using HNO 3 、H 2 SO 4 Or HCl treatment, heat and dry below 130°C after treatment;
[0075] (5) The natural clay treated in step (4) is treated with NaOH solution, baked and dried at 130°C after the treatment, and then pulverized to 100 mesh;
[0076] (6) Mix the materials prepared in step (2), step (3), and step (5), and shape them into 1-5mm particles on a moldin...
Embodiment 1
[0079] The temperature of the flue gas discharged from the boiler is 130°C, and the NOx concentration is 250mg / m 3 .
[0080] Through the first stage metal heat exchanger, the flue gas temperature drops to 100°C. The inlet water temperature of the heat exchanger is 45°C. The outlet water temperature is 75°C. It can be directly used for heating.
[0081] The flue gas enters the second-stage anti-corrosion heat exchanger, and the outlet gas temperature drops to 55°C. The inlet water temperature is 45°C, and the outlet water temperature is 50°C. This part of water is sent back to the boiler for further heating.
[0082] After passing through the third-stage anti-corrosion heat exchanger, the outlet temperature of the flue gas drops to 28°C, and then it can enter the adsorption device for NOx purification. The third-stage heat exchanger has an inlet water temperature of 12°C and an outlet water temperature of 22°C. This part of water is cooled in the heat pump source water c...
Embodiment 2
[0086] The flue gas temperature is 100°C, and the NOx concentration at the boiler outlet is 150mg / m 3 .
[0087] The flue gas enters the first-stage heat exchanger, which is directly an anti-corrosion heat exchanger, and the outlet temperature drops to 65°C. The inlet temperature of the water is 40°C and the outlet water temperature is 50°C. This boiler heating system is a direct heating system, and the heating water temperature is required to be 50°C, so the outlet water can be directly used for heating.
[0088] The flue gas enters the second-stage anti-corrosion heat exchanger, the outlet flue gas temperature is 25°C, and can enter the adsorption device for purification. The inlet water temperature is 8°C and the outlet water temperature is 19°C. This part of the water is measured at the source water of the heat pump, and the temperature is continuously lowered and circulated through the heat pump. The load side at the other end of the heat pump heats the incoming water...
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