Plastic stabilizer and preparation method thereof
A technology of plastic stabilizer and initiator, applied in the field of preparation of plastic stabilizer, can solve the problems of high cost, inability to meet the requirements of large-scale promotion of ordinary mortar, large investment in production equipment, etc. The effect of water retention and high molecular weight
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Embodiment 1
[0036] Add 300 g of deionized water into a 500 ml four-neck flask, add 105 g of allyl alcohol polyoxyethylene ether 2000 (APEG-2000), 5 g of maleic anhydride, 10 g of acrylic acid, and 1 g of acrylamide while stirring. After the addition, nitrogen gas was introduced and the temperature was raised to 80°C. At the same time, the oxidant solution prepared by 6 grams of 35% hydrogen peroxide and 40 grams of deionized water and the solution prepared by 1 gram of sodium sulfite, 1 gram of vitamin C and 25 grams of deionized water were added dropwise. Reducing agent solution, control the reaction temperature at 80--85°C. After 2 hours of reaction, 3 grams of methacryl alcohol polyoxyethylene ether acrylate (molecular weight: 1000) was added at one time, and the remaining initiator was added dropwise within 3 hours at the same time, and then the temperature was maintained for 1 hour. Cool to about 50°C and adjust the pH value to 7.5 with 50% sodium hydroxide solution. The product aft...
Embodiment 2
[0038] Add 300 grams of deionized water into a 500 ml four-necked flask, and add 105 grams of prenol polyoxyethylene ether 2400 (TPEG-2400), 7.5 grams of methacrylic acid, 7.5 grams of acrylic acid, and 1 gram of methacrylic acid under stirring amides. After the addition, nitrogen gas was introduced and the temperature was raised to 70°C. At the same time, 4 grams of 35% hydrogen peroxide, 2 grams of potassium persulfate and 40 grams of deionized water were added dropwise. A reducing agent solution prepared with 25 grams of deionized water, control the reaction temperature at 70--75°C, add 3 grams of allyl alcohol polyoxyethylene ether acrylate (molecular weight: 700) at one time after 110 minutes of reaction, and the remaining initiator in 3 hours The dropwise addition was completed at the same time, and the temperature was maintained for 1 hour. Cool to about 50°C and use 50% sodium hydroxide solution to adjust the pH value to 7.5. The product after adjusting the pH value c...
Embodiment 3
[0040] Add 300 g of deionized water into a 500 ml four-neck flask, add 105 g of methacryl alcohol polyoxyethylene ether 4000 (HPEG-4000), 15 g of acrylic acid, and 1 g of N-methylol acrylamide while stirring. After the addition, nitrogen gas was introduced and the temperature was raised to 70°C. At the same time, 3 grams of 35% hydrogen peroxide, 3 grams of sodium persulfate and 40 grams of deionized water were added dropwise. The reducing agent solution prepared by ion water, the reaction temperature is controlled at 70--75°C. After 130 minutes of reaction, 3 grams of prenol polyoxyethylene ether acrylate (molecular weight: 1300) was added at one time, and the remaining initiator was added dropwise within 3 hours at the same time, and the temperature was kept constant for 1 hour. Cool to about 50°C and use 50% sodium hydroxide solution to adjust the pH value to 7.5. The product after adjusting the pH value can also be spray-dried to make powder.
[0041] The plastic stabiliz...
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