Preparation method of house-of-cards-like hierarchical porous ZSM-5 molecular sieve
A ZSM-5, multi-level pore technology, applied in the field of preparation of inorganic porous materials, can solve the problems of unfavorable large-scale commercial production, complex and cumbersome process, high preparation cost, etc., and achieve rich channels, wide application prospects, and large external area Effect
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[0030] Example 1
[0031] (1) Add 0.42g aluminum sulfate octahydrate and 0.4g sodium hydroxide into 9g deionized water, stir until a clear solution, then add 4g deionized water and stir evenly;
[0032] (2) Add 2g of N-methyl-2-pyrrolidone to the clear solution of step (1) and stir evenly;
[0033] (3) Slowly add 1.5 g of white carbon black to the clear solution of step (2), stir evenly, and make a dilute colloid;
[0034] (4) Stir and evaporate the dilute colloid obtained in step (3) at 60°C for 4 hours (total mass is reduced by about 4g) to obtain a uniform wet gel;
[0035] (5) Put the wet gel obtained in step (4) into a hydrothermal reaction kettle and crystallize at 140°C for 72 hours. After the crystallization is completed, the solid product is suction filtered, washed, and dried in an oven at 70°C for 24 hours. Calcining in air at 550℃ for 5h (heating rate is 1℃min -1 ), to obtain 1.14 g of "card-in-card" type multi-stage ZSM-5 molecular sieve, with a yield of 10.1% (the percent...
Example Embodiment
[0040] Example 2
[0041] (1) Add 0.37 g of aluminum sulfate octahydrate and 0.4 g of sodium hydroxide into 10 g of deionized water, stir until a clear solution, and then add 6 g of deionized water and stir evenly;
[0042] (2) Add 1g of N-methyl-2-pyrrolidone to the clear solution of step (1) and stir evenly;
[0043] (3) Slowly add 1.5 g of white carbon black to the clear solution of step (2), stir evenly, and make a dilute colloid;
[0044] (4) Stir and evaporate the dilute colloid obtained in step (3) at 60°C for 6 hours (total mass is reduced by about 6g) to obtain a uniform wet gel;
[0045] (5) Put the wet gel obtained in step (4) into a hydrothermal reaction kettle and crystallize at 140°C for 72 hours. After the crystallization is completed, the solid product is suction filtered, washed, and dried in an oven at 70°C for 24 hours. Calcined in the air at 500℃ for 4h (heating rate is 1℃min -1 ), to obtain 1.10 g of the "insertion card" type multistage porous ZSM-5 molecular sieve...
Example Embodiment
[0046] Example 3
[0047] (1) Add 0.42g aluminum sulfate octahydrate and 0.4g sodium hydroxide into 5.6g deionized water, stir until a clear solution, then add 4g deionized water and stir evenly;
[0048] (2) Add 2g of N-methyl-2-pyrrolidone to the clear solution of step (1) and stir evenly;
[0049] (3) To the clear solution of step (2), slowly add 5.4 g of silica sol (SiO 2 The mass percentage of 25-30%), stir evenly to make a thin colloid;
[0050] (4) Stir and evaporate the dilute colloid obtained in step (3) at 70°C for 2 hours (the total mass is reduced by about 4g) to obtain a uniform wet gel;
[0051] (5) Put the wet gel obtained in step (4) into a hydrothermal reaction kettle and crystallize at 140°C for 60 hours. After the crystallization is completed, the solid product is filtered and washed with suction, dried in an oven at 70°C under normal pressure for 24 hours, and then Calcining in air at 550℃ for 6h (heating rate is 1℃min -1 ), to obtain 1.21 g of a "card" type multi-p...
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