Subcritical hydrothermal treatment-based efficient recycling treatment process for sludge

A subcritical water and treatment process technology, applied in the field of solid waste recycling, can solve the problems of complexity, reduced sludge anaerobic digestion efficiency, low dissolution and hydrolysis rate, etc., and achieves less solid residue, fast reaction rate, and residence time. short effect

Inactive Publication Date: 2015-02-18
TONGJI UNIV
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Problems solved by technology

However, municipal sludge is rich in microbial residues and has a high proportion of solid organic pollutants, which leads to the following problems in the process of using anaerobic digestion technology for sludge recycling and harmlessness: First, the organic matter in sludge Most of them exist in solid form and are mixed with anaerobic microorganisms, and the residence time of anaerobic microorganisms and pollutants cannot be controlled separately, so the traditional high-speed anaero

Method used

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  • Subcritical hydrothermal treatment-based efficient recycling treatment process for sludge

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Embodiment 1

[0023] The dewatered sludge of a sewage treatment plant has a measured solid content of 10%. Put 50Kg of the sludge in the sludge storage tank into the inner tank of a hydrothermal reactor with an effective volume of 75L. The set temperature is 200°C and the pressure is 1.6MPa, after reaching the set temperature, maintain it for 30 minutes, recover the water vapor and use it to preheat the sludge in the sludge storage tank. It is measured that the solid content of the sludge after hydrothermal modification is reduced to 8%, and it is obtained after dehydration by plate and frame filtration. The filtrate is 46kg, and the mud cake is 4kg. The filtrate enters the UASB anaerobic digestion water storage tank for subsequent biogas recovery, and the mud cakes produced in multiple batches are jointly treated with aerobic composting.

Embodiment 2

[0025] The dewatered sludge of a sewage treatment plant has a measured solid content of 25%. 50kg of sludge is semi-continuously entered into a subcritical hydrothermal reactor with a temperature of 300°C and a pressure of 8.6MPa through a high-pressure pump to reach the design level. After maintaining the temperature for 10 minutes, the water vapor is recovered and used to preheat the sludge in the mud storage tank. It is measured that the solid content of the sludge after hydrothermal modification is reduced to 15%. 10kg, the reaction material enters the dehydration system after multi-stage decompression cooling, the dehydration filtrate enters the water inlet storage tank of the anaerobic MBR system for subsequent biogas recovery, and the dehydration residue enters aerobic composting treatment.

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Abstract

The invention relates to a subcritical hydrothermal treatment-based efficient recycling treatment process for sludge. According to the treatment process, sludge with the solid content of 10 to 25 percent of a sewage treatment plant is placed into a hydrothermal reaction kettle for 5 to 30 minutes at the subcritical high temperature of 200 to 300 DEG C and under the high pressure of 1.6 to 8.6 MPa, so that intracellular substances in sludge are fully dissolved, solid organic matters are fully dissolved and hydrolyzed and are partially decomposed; the release of bound water and surface water in the sludge facilitates improvement on the dehydration performance of the sludge. The sludge which is subjected to hydrothermal modification is dehydrated to enable the solid content of the dehydrated sludge to be not higher than 60 percent, and then aerobic composting stabilizing treatment is performed. The filtrate which is rich in dissolved organic matters and is obtained by dehydrating the sludge enters a high-speed anaerobic digestion system for fully recovering methane. According to the technology, the hygienization, the recycling and the stabilization of the sludge are realized effectively; the subcritical/supercritical reaction speed is high, the subsequent efficient anaerobic digestion hydraulic retention time is short, and the solid residues generated after hydrothermal modification dehydration are few, so that large-scale urban sludge treatment capacity can be realized by adopting small-capacity reactors in a hydrothermal link, an anaerobic link and an aerobic link of the treatment process.

Description

technical field [0001] The invention belongs to the field of solid waste recycling, and relates to a high-efficiency sludge recycling process based on subcritical hydrothermal treatment. Background technique [0002] The amount of dewatered sludge produced by urban sewage treatment plants due to the purification of domestic sewage is huge. At present, the annual collection capacity is about 30 million tons. Traditional sludge treatment methods, such as landfill, open-air stacking and foreign transportation Unable to adapt to the increasingly stringent sludge treatment and disposal standards. In recent years, the global energy structure is undergoing a transformation from fossil energy-based to the coexistence of multiple energy sources. Issues such as food security and environmental degradation have become increasingly prominent. Anaerobic fermentation technology has been adopted Recycling of non-food biomass energy in sludge—biogas has gradually gained attention. [0003] ...

Claims

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Application Information

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IPC IPC(8): C02F11/00
CPCC02F3/28C02F3/2846C02F3/2853C02F11/02C02F11/10C02F11/12C02F11/122C02F2303/06Y02E50/30
Inventor 戴晓虎董滨段妮娜张静思陈思思
Owner TONGJI UNIV
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