Biodegradable unsaturated polyurethane material and preparation method thereof
A polyurethane material and unsaturated technology, applied in the field of biomedical materials, can solve the problems of difficult and effective modification of medical degradable polyurethane materials, and achieve the effects of excellent biodegradability, efficient reaction sites, and excellent biocompatibility
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[0023] Example 1
[0024] Biodegradable unsaturated polyurethane material (PPFU / HDI 1.6+Lys-OMe), including soft segment and hard segment, the soft segment is unsaturated polyester polyol polypropylene fumarate PPF, the hard segment It is an aliphatic isocyanate HDI and a small molecule diamine chain extender Lys-OMe.
[0025] It has the following structure.
[0026]
[0027] The PPF with a number average molecular weight of 1000 is formulated into a 30% mass fraction of polypropylene fumarate solution. According to the ISO 2554-1974 method, it is determined that the number of moles of hydroxyl groups in the solution is 14.68 mmol.
[0028] Take the above-mentioned PPF toluene solution into a dry three-necked flask and reduce pressure at 110°C for 1 hour to remove the solvent toluene and residual moisture. Add 30 mL of solvent anhydrous dioxane to re-dissolve, add 1.9752 g of hexamethylene diisocyanate (HDI), 0.03 mmol of catalyst dibutyl tin dilaurate, and react at 70° C. for 3 hour...
Example Embodiment
[0031] Example 2
[0032] Biodegradable unsaturated polyurethane material (PPFU / HMDI 1.6+Lys-OMe), including soft segment and hard segment, the soft segment is unsaturated polyester polyol polypropylene fumarate PPF, the hard segment It is an aliphatic isocyanate HMDI and a small molecule diamine chain extender Lys-OMe.
[0033]
[0034] Its preparation includes the following steps:
[0035] The PPF with a number average molecular weight of 1000 is formulated into a 30% mass fraction of polypropylene fumarate solution. According to the ISO 2554-1974 method, it is determined that the number of moles of hydroxyl groups in the solution is 14.68 mmol.
[0036] Take the above PPF toluene solution into a dry three-necked flask, and distill under reduced pressure at 110°C for 1 hour to remove the solvent toluene and residual moisture. Add 30mL of solvent anhydrous dioxane to re-dissolve, add 3.0810g 4,4'-dicyclohexylmethane diisocyanate (HMDI), 0.03mmol catalyst dibutyltin dilaurate, and re...
Example Embodiment
[0038] Example 3
[0039] Biodegradable unsaturated polyurethane material (PPFU / LDI 1.6+Lys-OMe), including soft segment and hard segment, the soft segment is unsaturated polyester polyol polypropylene fumarate PPF, the hard segment It is an aliphatic isocyanate LDI and a small molecule diamine chain extender Lys-OMe.
[0040] It has the following structure.
[0041]
[0042] Its preparation includes the following steps:
[0043] The PPF with a number average molecular weight of 1000 is formulated into a 30% mass fraction of polypropylene fumarate solution. According to the ISO 2554-1974 method, it is determined that the number of moles of hydroxyl groups in the solution is 14.68 mmol.
[0044] Take the above PPF toluene solution into a dry three-necked flask, and distill under reduced pressure at 110°C for 1 hour to remove the solvent toluene and residual moisture. Add 30mL of solvent anhydrous dioxane to re-dissolve, add 2.6568g L-lysine diisocyanate (LDI), 0.03mmol catalyst dibutyl...
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