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Carbon material/covalent organic two-dimensional gird composite electrode material as well as preparation method and application thereof

A covalent organic, two-dimensional grid technology, applied in the field of energy material preparation and electrochemistry, can solve the problem of low utilization rate of diaminoanthraquinone active groups, and achieve the effect of simple and economical preparation method and improved utilization rate

Inactive Publication Date: 2015-04-22
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The purpose of the present invention is to provide a carbon material / covalent organic two-dimensional grid composite electrode material and its preparation method and application. The problem of low utilization rate of diaminoanthraquinone active group of electrochemical active group

Method used

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  • Carbon material/covalent organic two-dimensional gird composite electrode material as well as preparation method and application thereof
  • Carbon material/covalent organic two-dimensional gird composite electrode material as well as preparation method and application thereof
  • Carbon material/covalent organic two-dimensional gird composite electrode material as well as preparation method and application thereof

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Experimental program
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Embodiment 1

[0038] This embodiment provides a method for preparing a carbon material / covalent organic two-dimensional grid composite electrode material, and the specific operation steps are as follows:

[0039] 1. Using dimethylacetamide solution as the solvent, prepare 1 mg / g trimesaldehyde solution and 2.2 mg / g 2,6-diaminoanthraquinone solution respectively, and prepare 370 microliters of mixed solution according to the mass ratio of 1:2.2 , and add 22.2 microliters of water to the mixed solution.

[0040] 2. Use a pipette gun to uniformly infiltrate all surfaces of the three-dimensional nickel-based graphene with the mixed solution in step 1, and place it in a tube furnace protected by argon.

[0041] 3. Raise the temperature from room temperature to 140°C at 5°C / min, keep it warm for 5 hours, then raise the temperature to 205°C at 5°C / min, keep it warm for 1 hour, and then take it out by natural cooling. The thickness of the covalent organic 2D mesh is about 130 nm.

[0042] The cov...

Embodiment 2

[0051] This embodiment provides a method for preparing a carbon material / covalent organic two-dimensional grid composite electrode material, and the specific operation steps are as follows:

[0052] 1. Using dimethylacetamide solution as solvent, prepare 0.1 mg / g 1,3,5-tris(4-formylphenyl)benzene (CAS number: 118688-53-2) dimethylacetamide solution respectively and 0.1 mg / g 2,6-diaminoanthraquinone dimethylacetamide solution, prepare 100 microliters of mixed solution according to the mass ratio of 1:0.92, and add 6 microliters of water to the mixed solution.

[0053] 2. Use a pipette gun to evenly infiltrate the upper surface of the highly oriented pyrolytic graphite with the mixed solution in step 1, and place it in a vacuum drying oven.

[0054] 3. Heat at 200°C for 30 minutes under vacuum.

[0055] In this embodiment, the structural formula of 1,3,5-tris(4-formylphenyl)benzene is as follows:

[0056] .

[0057] In this embodiment, the surface size of the highly orien...

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Abstract

The invention discloses a carbon material / covalent organic two-dimensional gird composite electrode material as well as a preparation method and application thereof. The carbon material / covalent organic two-dimensional gird composite electrode material has the advantages that a graphitized carbon material is taken as a base template, a covalent organic two-dimensional gird layer grows on the graphitized carbon material base in situ, and the covalent organic two-dimensional gird layer is prepared by carrying out reaction on an aroma polyaldehyde compound and diamino-anthraquinone; a covalent organic two-dimensional gird prepared by taking diamino-anthraquinone as a reaction monomer is compounded with the graphitized carbon material for the first time, and a condition for growing the covalent organic two-dimensional gird on the graphitized carbon material is provided; meanwhile, the preparation method is simple and economic, no high-end delicate instrument is needed, no high energy is needed, and the actual production need can be met; and compared with an electrode prepared by directly adopting covalent organic two-dimensional gird crystal powder, the preparation method disclosed by the invention has the advantage that the utilization rate of an electrochemical active group, namely diamino-anthraquinone, is increased.

Description

technical field [0001] The invention belongs to the field of energy material preparation and electrochemistry, and relates to a carbon material / covalent organic two-dimensional grid composite electrode material and its preparation method and application. Background technique [0002] High specific surface area electrodes can be used as electrochemical sensors, electrocatalysis, and enhanced energy storage components, such as batteries, supercapacitors, and fuel cells. Low relative density, light weight, and high specific surface area are the characteristics of nanoporous materials, which make nanoporous materials play an important role in the fields of electrode materials, catalysis, and hydrogen storage materials. Among numerous nanoporous materials, covalent organic frameworks (COFs) have attracted great interest. This material is composed of lighter elements (H, B, C, N, O) formed by strong covalent bonds between atoms to form a very stable nanoporous material. Three-di...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/583
CPCH01M4/139H01M4/366H01M4/625H01M12/00Y02E60/10
Inventor 雷圣宾查泽奇许丽荣
Owner HARBIN INST OF TECH
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