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Annulus protective liquid of annulus mechanical seat sealed oil-gas well and applications thereof

A technology of annulus protection fluid and annulus machinery, applied in wellbore/well parts, drilling composition, earthwork drilling and production, etc., can solve problems such as pressure relief, wellhead topping, easy aging, etc., and achieve compression Large degree, convenient pressure relief and good stability

Inactive Publication Date: 2015-05-20
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] 1. When water-based annular protection fluid is used in oil and gas wells, there are the following problems: (1) When the temperature is low in winter, the water-based liquid at the wellhead is easy to freeze and block, and the brittleness of the wellhead steel becomes greater at low temperatures, which may affect the wellhead device. stability
(3) When discharging the annular protection fluid at the wellhead, a specific container and subsequent liquid treatment are required, and there are certain safety and environmental hazards
(4) Water-based protective fluid generally contains dissolved gases such as oxygen and carbon dioxide, which makes it difficult to control the corrosion of carbon steel tubing and casing
[0013] 2. When oil-based annulus protection fluid is used in oil and gas wells, there are the following problems: (1) Packer rubber tubes are prone to aging and damage after soaking in oil base for a long time
The cost is relatively high, and the cost of oil-based protection fluid for a well reaches 300,000 to 500,000 yuan / well
(3) After the annulus fluid is filled, the volume of the annulus protection fluid in the closed annulus will expand and hold pressure, which will cause problems such as the top of the wellhead and the need for regular pressure relief.

Method used

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  • Annulus protective liquid of annulus mechanical seat sealed oil-gas well and applications thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] In a liquid mixing tank with a capacity of 10L, 10% of emulsifier oxyethylene sorbitan monooleate span-80 (Jiangsu Haian Petrochemical Plant) was sequentially added in terms of mass percentage, and 0.5% of salt-resistant High-temperature foaming agent polyoxyethylene alkyl alcohol ether (Jiangsu Haian Petrochemical Plant), 0.3% foam stabilizer plant gum heteroglycan KD-03 (Yangzhou Runda Oilfield Chemical Agent Co., Ltd.), 0.1% layering Regulator polyoxypropylene polyoxyethylene ether (Jiangsu Haian Petrochemical Plant), 28% 26# industrial grade white oil (Shanghai Best Chemical Co., Ltd.), 0.5% corrosion inhibitor alkynyloxymethyl quaternary ammonium salt IMC -80BH (Shenyang Zhongke Mingyang Corrosion and Protection Co., Ltd.), the rest is water, 3000rpm continuous stirring and dosing; then feed nitrogen with a volume percentage of 8-10%, 3000rpm continuous stirring for 30min, to form a uniform foam emulsion. Put the foam emulsion at room temperature 25°C, pass the st...

Embodiment 2

[0049] In terms of mass percentage, formulating liquid according to components: 14% emulsifier oxyethylene sorbitan tristearate span65 (Jiangsu Haian Petrochemical Factory), 0.1% nonionic surfactant foaming agent alkyl Phenolic polyoxyethylene ether (Jiangsu Haian Petrochemical Plant), 0.1% foam stabilizer polyacrylamide HPAM (Henan Yiqing Chemical Plant), 0.2% layering regulator phenolamine resin ether (Jiangsu Haian Petrochemical Plant ), 25% of 26# industrial grade white oil (Shanghai Best Chemical Co., Ltd.), 0.1% of corrosion inhibitor alkynyloxymethyl quaternary ammonium salt (Shenyang Zhongke Mingyang Corrosion and Protection Co., Ltd.), and the rest is water.

[0050] Table 2 Components of annular protection fluid

[0051]

[0052] see figure 1 , use the dosing pump truck 7 to prepare the liquid from the dosing port 8 according to the formula in the liquid mixing tank 6, and continue to stir and add the medicine to form a foam emulsion with a uniform phase state (n...

Embodiment 3

[0054] In terms of mass percentage, formulating liquid according to components: 12% polyoxyethylene sorbitan trioleate Span85 (Jiangsu Haian Petrochemical Plant), 0.5% foaming agent polyoxyethylene alkyl alcohol ether (Jiangsu Haian Petrochemical plant), 0.2% carboxymethylcellulose sodium salt CMC foam stabilizer (Yangzhou Runda Oilfield Chemical Agent Co., Ltd.), 0.2% layering regulator hydrazine oxide polyether (Jiangsu Haian Petrochemical Plant), 25% commercially available gas oil, 0.8% corrosion inhibitor alkynyloxymethyl quaternary ammonium salt (Shenyang Zhongke Mingyang Corrosion and Protection Co., Ltd.), and the rest is water.

[0055] Table 3 Components of annular protection solution

[0056]

[0057] see figure 2 , use the dosing pump truck 7 to prepare the liquid in the liquid mixing tank 6 according to the formula from the dosing port 8, continue to stir and add the medicine to form a foam emulsion, and feed in a chemically stable gas with a uniform phase sta...

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Abstract

The invention relates to an annulus protective liquid of annulus mechanical seat sealed oil-gas well and applications thereof. The protective liquid is composed of the following components in percentage by weight: 10 to 14% of emulsifier, 0.1 to 0.5% of foaming agent, 0.1 to 0.3% of foam stabilizer, 25 to 28% of oil phase, 0.5 to 1.0% of corrosion inhibitor, and the balance being water. The emulsifier, foaming agent, foam stabilizer and corrosion inhibitor are mixed, then water and oil phase are added to prepare stable emulsion; then gas with a stable chemical property is introduced into the emulsion to form stable foamed emulsion; and the stable foamed emulsion is injected into an oil sleeve annulus and is automatically separated into layers of gas, oil, and water under the effects of the temperature and pressure in the cylindrical well and the surface tensions of different components. The provided annulus protective liquid can protect the oil sleeve annulus, has a good corrosion inhibiting speed, does not generate an upward force on the wellhead, and can prevent the aging of the packer. Furthermore, the cost of annulus protective liquid is reduced.

Description

technical field [0001] The invention relates to an annulus protection fluid for oil and gas wells and water injection wells, in particular to an annulus protection fluid for annulus mechanically seated oil and gas wells and its application. Background technique [0002] During the development of oil and gas fields at home and abroad, in order to protect the inner wall of the casing and the outer wall of the tubing from H 2 S and CO 2 Corrosion, etc., mainly adopt the method of injecting high-efficiency protective fluid into the annulus of oil casing. When the oil and gas well is drilled, the annulus protection fluid is injected above the casing annulus packer to fill the annulus of the oil casing and isolate the annulus of the oil casing from the production fluid. [0003] Annulus protection fluids are generally water- or oil-based hydrocarbon-based fluids. Its specific function is to provide a stable balance pressure inside and outside the oil and gas well casing, and to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/54E21B41/02
CPCC09K8/54C09K2208/32E21B41/02
Inventor 李琼玮曾亚勤张书平郭钢孙雨来朱方辉李慧奚运涛杨全安
Owner PETROCHINA CO LTD
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