Preparation method of anti-falling corrosion-resistant double-metal composite coating

A composite coating and corrosion-resistant technology, applied in anti-corrosion coatings, epoxy resin coatings, coatings, etc., can solve the problems of serious electrolyte solution pollution, high energy consumption of the anodic oxidation process, and application limitations, and achieve good decorative appearance, metal The effect of strong texture and easy pre-treatment

Inactive Publication Date: 2015-05-27
JIANGSU XIN AN NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In order to prevent the occurrence and development of metal corrosion, metal rust removal, rust prevention and anticorrosion operations have to be carried out; there are many methods to prevent metal corrosion, and the metal protection methods currently used can be divided into three categories: one is anodic oxidation treatment, That is, an anodic oxidation film of tens of microns is formed on the metal surface, but its application is limited due to the high energy consumption of the anodic oxidation process and the serious pollution of the electrolyte solution, which is difficult to handle; the second type is the chemical conversion film, that is, the metal parts Soaked in a solution of a certain composition, relying on a chemical reaction at a certain temperature to form a chemical conversion film, the most widely used now is the chemical oxidation of chromate, but chromate is a carcinogenic toxic substance, the world's environment The protection organization has restricted the use of chromate and other chromate-containing compounds; the third category is organic coating, which is to apply an organic coating on the metal surface to improve the appearance and physical and chemical properties of the metal

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] This embodiment provides a method for preparing an anti-shedding and corrosion-resistant bimetallic composite coating. The composite coating is composed of composition A, composition B and heat-resistant filler, and the composition A, composition B and heat-resistant filler are The weight ratio is 1.5:1:1;

[0034]Composition A contains the following components by mass percentage: boron modified silicone resin: 45-58%, silicone acrylic resin: 10%-60%, fluorinated alkyl silicate: 3-25%, epoxy resin : 10%-60%, erucamide: 0.5%-8%, polyethylene wax: 0.1%-5%, polytetrafluoroethylene: 0-5%, silicone oil: 0.1%-2%, grafted silicone resin : 20-40%, aluminum powder: 35-45%, zinc powder: 25-30%, additives: 2-4%, the sum of the above is 100%;

[0035] Wherein, the boron-modified silicone resin is a boric acid-modified silicone resin, and the preparation method is as follows:

[0036] Select boric acid and silicone resin as reactants, the mass ratio of boric acid and silicone resi...

Embodiment 2

[0048] This embodiment provides a method for preparing an anti-shedding and corrosion-resistant bimetallic composite coating. The composite coating is composed of composition A, composition B and heat-resistant filler, and the composition A, composition B and heat-resistant filler are The weight ratio is 1.5:1:1;

[0049] Composition A contains the following components by mass percentage: boron modified silicone resin: 45-58%, silicone acrylic resin: 10%-60%, fluorinated alkyl silicate: 3-25%, epoxy resin : 10%-60%, erucamide: 0.5%-8%, polyethylene wax: 0.1%-5%, polytetrafluoroethylene: 0-5%, silicone oil: 0.1%-2%, grafted silicone resin : 20-40%, aluminum powder: 35-45%, zinc powder: 25-30%, additives: 2-4%, the sum of the above is 100%;

[0050] Wherein, the boron-modified silicone resin is a boric acid-modified silicone resin, and the preparation method is as follows:

[0051] Select boric acid and silicone resin as reactants, the mass ratio of boric acid and silicone res...

Embodiment 3

[0063] This embodiment provides a method for preparing an anti-shedding and corrosion-resistant bimetallic composite coating. The composite coating is composed of composition A, composition B and heat-resistant filler, and the composition A, composition B and heat-resistant filler are The weight ratio is 1.5:1:1;

[0064] Composition A contains the following components by mass percentage: boron modified silicone resin: 45-58%, silicone acrylic resin: 10%-60%, fluorinated alkyl silicate: 3-25%, epoxy resin : 10%-60%, erucamide: 0.5%-8%, polyethylene wax: 0.1%-5%, polytetrafluoroethylene: 0-5%, silicone oil: 0.1%-2%, grafted silicone resin : 20-40%, aluminum powder: 35-45%, zinc powder: 25-30%, additives: 2-4%, the sum of the above is 100%;

[0065] Wherein, the boron-modified silicone resin is epoxy-modified silicon-boron resin, and the preparation method is as follows:

[0066] Select the mass ratio of epoxy resin to organoborosilicate resin as 25:100, select n-butanol, cycl...

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Abstract

The invention discloses a preparation method of an anti-falling corrosion-resistant double-metal composite coating. The composite coating consists of a composition A, a composition B and heat-resistant filler in a weight ratio of 1.5: 1: 1; 0.5-1 part of compound rare earth, 30-35 parts of a vapor phase inhibitor, 20-25 parts of deionized water and 10-15 parts of a thixotropic agent are added into the composition B; the heat-resistant filler comprises nanosilicon dioxide, blocking functional filler and powdered aluminum in a mass ratio of 1.5: 1: 1; the blocking functional filler comprises the following components in parts by mass: 2-6 parts of hollow glass beads, 10-15 parts of graphite, 20-35 parts of black silicon carbide, 25-30 parts of fine crystal aluminum oxide, 5-10 parts of molybdenum disulfide, 1-5 parts of zinc oxide and 3-6 parts of talcum powder.

Description

technical field [0001] The invention relates to the field of composite paint and its production and preparation, in particular to a preparation method of an anti-shedding and corrosion-resistant bimetallic composite paint. Background technique [0002] In order to prevent the occurrence and development of metal corrosion, metal rust removal, rust prevention and anticorrosion operations have to be carried out; there are many methods to prevent metal corrosion, and the metal protection methods currently used can be divided into three categories: one is anodic oxidation treatment, That is, an anodic oxidation film of tens of microns is formed on the metal surface, but its application is limited due to the high energy consumption of the anodic oxidation process and the serious pollution of the electrolyte solution, which is difficult to handle; the second type is the chemical conversion film, that is, the metal parts Soaked in a solution of a certain composition, relying on a ch...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/04C09D183/14C09D133/04C09D163/00C09D5/10C09D7/12
Inventor 张望杨松林
Owner JIANGSU XIN AN NEW MATERIALS TECH
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