Monomer with anion recognizing function, oligomer and preparation method thereof

Abstract

The invention discloses a N-p-nitrophenyl-N-(p-acetenyl-2-pentafluorobenzoic acid benzoyloxycarbonyl)-phenyl-urea monomer, an oligomer and a preparation method thereof. As a target product of the technology, the N-p-nitrophenyl-N-(p-acetenyl-2-pentafluorobenzoic acid benzoyloxycarbonyl)-phenyl-urea and the oligomer structure have urea structure units which can be used as hydrogen-bond donors, also have aromatic-ring structure units which can be used as anion-n donors, and when the urea structure units and the aromatic-ring structure units are combined with the anions, the synergy on the space geometry is achieved, i.e., the N-p-nitrophenyl-N-(p-acetenyl-2-pentafluorobenzoic acid benzoyloxycarbonyl)-phenyl-urea can recognize anions by the synergistic effect of two weak bonds such as hydrogen bonds and anion-n simultaneously, the target-product oligomer of the N-p-nitrophenyl-N-(p-acetenyl-2-pentafluorobenzoic acid benzoyloxycarbonyl)-phenyl-urea has the same space geometrical structure with the monomer thereof, i.e., a plurality of anions also can be recognized and combined by the synergistic effect of the two weak bonds such as the hydrogen bonds and the anion-n.

Description

technical field [0001] The invention belongs to the technical field of hydrogen bond and π-electron cooperative recognition of anions, and specifically relates to a monomer and an oligomer based on a hydrogen bond and π-electron cooperative recognition of anions, and the invention also relates to the preparation of the monomer and oligomer methods and applications. Background technique [0002] In nature or life process, the anion recognition process plays an extremely important role, such as the processing of information by the retina, the metabolism of arginine in the liver and kidney, and many other important biochemical processes are controlled by anions. In artificial systems, anion recognition is used to precisely control the formation of pseudorotaxanes, prepare supramolecular capsules, and manipulate the morphological evolution of molecular machines and crystals, especially in molecular machines and molecular storage materials, how to control the combination of host ...

AI Technical Summary

Problems solved by technology

At present, the functional group design of anion acceptors is still based on various -NH hydrogen bond donors, and the structural design of anion recognition by anion-π weak interaction is mainly used for the development of small molecule acceptors, and has not been studied yet. The introduction of anion-π into the synthesis of oligomer acceptors, and the introduction of hydrogen bond donors and anion-π donors into the synthesis of molecular skeleton structures at the same time has not been reported to study the weak synergy between hydrogen bonds and anion-π Recognition of anions by interactions

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