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Dual-N-layer structure amorphous silicon solar cell and preparation method of dual-N-layer structure amorphous silicon solar cell

A technology of solar cells and layer structures, applied in circuits, photovoltaic power generation, electrical components, etc., can solve problems such as solar cell current and voltage loss, achieve high photoelectric conversion efficiency, improve conversion efficiency, and increase short-circuit current effects

Active Publication Date: 2015-06-03
SOUTH CHINA NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This is because the conductive film is weakly N-type, and forms a reverse PN junction with the P-type amorphous silicon film, resulting in loss of current and voltage of the solar cell. How to solve this problem needs to be further studied.

Method used

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  • Dual-N-layer structure amorphous silicon solar cell and preparation method of dual-N-layer structure amorphous silicon solar cell
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  • Dual-N-layer structure amorphous silicon solar cell and preparation method of dual-N-layer structure amorphous silicon solar cell

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Embodiment 1

[0040] The double n-layer structure amorphous silicon solar cell provided in this embodiment comprises a glass substrate, a transparent conductive film 1, a P-type amorphous silicon layer 2, a buffer layer 3, and an intrinsic amorphous silicon layer i arranged on the glass substrate in sequence. Layer 4, a double-layer n-type amorphous silicon layer 5, a back reflection layer 6 and a back electrode 7. The double-layer n-type amorphous silicon layer is composed of a lightly doped n-type amorphous silicon layer and a heavily doped n-type amorphous silicon layer. A double n-layer structure composed of two silicon layers.

[0041] The transparent conductive film is SnO with textured structure 2 : F thin film; p-type amorphous silicon layer is p-a-SiC:H; buffer layer is a-SiC:H thin film; amorphous silicon intrinsic layer i layer is i-a-Si:H thin film; lightly doped n-type amorphous The silicon layer is a lightly doped n-a-Si:H film; the heavily doped n-type amorphous silicon laye...

Embodiment 2

[0058] The double n-layer structure amorphous silicon solar cell provided in this embodiment includes a glass substrate, a transparent conductive film, a p-type amorphous silicon layer, a buffer layer, an intrinsic layer i of amorphous silicon, a double A layer of n-type amorphous silicon layer, a back reflection layer and a back electrode. n layer structure.

[0059] The transparent conductive film is SnO with textured structure 2: F film; p-type amorphous silicon layer is p-a-SiC:H film; buffer layer is a-SiC:H film; amorphous silicon intrinsic layer i layer is i-a-Si:H film; lightly doped n-type non The crystalline silicon layer is a lightly doped n-a-Si:H film; the heavily doped n-type amorphous silicon layer is a heavily doped n-a-Si:H film; the back reflection layer is zinc oxide doped with aluminum ZnO:Al film; the back electrode is silver electrodes.

[0060] The film thickness of p-a-Si:H film is 10-30nm; the film thickness of a-SiC:H film is 10-20nm; the film thic...

Embodiment 3

[0068] The amorphous silicon solar cell with double n-layer structure provided in this embodiment is the same as that in Embodiment 1.

[0069] The difference of the preparation method of this double n-layer structure amorphous silicon solar cell is that with embodiment 1: change step 5) and step 6), change the deposition time of these two steps, namely

[0070] Step (5) The vacuum degree of the vacuum chamber is pumped to 3.0×10 -6 Torr, the substrate temperature is heated to 260°C, the flow rate of silane gas is 15sccm, the flow rate of phosphine gas is 30sccm, the flow rate of hydrogen gas is 105sccm, the gas is uniform for 8 minutes, the reaction pressure is 0.4Torr, and the discharge power is 80mW / cm 2 , the deposition time is 2 minutes and 25 seconds;

[0071] Step (6) Vacuum the vacuum chamber to 3.0×10 -6 Torr, the substrate temperature is heated to 260°C, the flow rate of silane gas is 10sccm, the flow rate of phosphine gas is 40sccm, the flow rate of hydrogen gas i...

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Abstract

The invention discloses a dual-N-layer structure amorphous silicon solar cell. The dual-N-layer structure amorphous silicon solar cell comprises a glass substrate, a transparent conducting film, a P-type amorphous silicon layer, a buffer layer, an amorphous silicon intrinsic layer i layer, a dual-layer N type amorphous silicon layer, a back reflecting layer and a back electrode, which are arranged on the glass substrate in sequence; the dual-layer N type amorphous silicon layer is composed of a light-doped N type amorphous silicon layer and a heavy-doped N type amorphous silicon layer; the dual-N-layer structure amorphous silicon solar cell has higher current density and photoelectric conversion efficiency. The invention also discloses a preparation method of the dual-N-layer structure amorphous silicon solar cell; the preparation method has the advantages that the process is concise, and the investment on new equipment is not needed.

Description

technical field [0001] The invention belongs to the technical field of amorphous silicon solar cells, and in particular relates to a double n-layer structure amorphous silicon solar cell and a preparation method thereof. Background technique [0002] With the depletion of non-renewable energy such as coal and oil, the demand for new energy in the world economy has led to the rapid development of solar cell technology. Solar cells are a renewable clean energy by converting sunlight into electrical energy. technology. [0003] At present, the industrial production in the market is dominated by monocrystalline silicon and polycrystalline silicon solar cells. The cell efficiency of monocrystalline silicon is 18.5%, and the efficiency of polycrystalline silicon cells is about 16.7%. However, there is a shortage of silicon materials required for these two batteries and environmental pollution in the preparation process of silicon materials. Amorphous silicon thin-film solar cells...

Claims

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Application Information

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IPC IPC(8): H01L31/076H01L31/0352H01L31/0288H01L31/20
CPCH01L31/02167H01L31/0288H01L31/035272H01L31/076H01L31/20Y02E10/548Y02P70/50
Inventor 高进伟容齐坤韩兵李若朋彭强林振炫
Owner SOUTH CHINA NORMAL UNIVERSITY