Preparation method and application of super-hydrophobic nanofibers of coral structure

A nanofiber, superhydrophobic technology, applied in the chemical characteristics of fibers, textiles and papermaking, one-component synthetic polymer rayon, etc., can solve the inconvenience of production and life in mass production of superhydrophobic materials, difficult to prepare with superhydrophobic surfaces , reducing the surface energy and other issues, to achieve the effects of good superhydrophobicity, fast and simple preparation method, and low surface free energy

Inactive Publication Date: 2015-06-10
INST OF CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the reported superhydrophobic surface preparation processes involve the use of relatively expensive low-surface-energy substances, such as fluorine- or silane-containing compounds, to reduce the surface energy of the surface, and many methods involve specific equipment, harsh conditions and a long period, it is difficult to be used in the preparation of large-area superhydrophobic surfaces
Several existing preparation methods are not only complicated but also costly, and it is not convenient to prepare a large number of superhydrophobic materials in actual production and life, and there are few methods that can be used for large-scale application production (a) B. Qian, et al, Langmuir .2005,21,9007-9009; b) J.Y.Shiu, et al, Chem.Mater.2004,16,561-564; c) L.B.Zhu, et al, Langmuir.2005,21,11208-11212; d) G.Zhang , et al, Langmuir.2005, 21, 9143-9148.)

Method used

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  • Preparation method and application of super-hydrophobic nanofibers of coral structure
  • Preparation method and application of super-hydrophobic nanofibers of coral structure
  • Preparation method and application of super-hydrophobic nanofibers of coral structure

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Dissolve 0.05g of sorbitan stearate (Span-60) in 125g of n-heptane, add 0.1g of boron trifluoride ethyl ether initiator dropwise, oscillate to emulsify it evenly, and adjust the temperature of the system to 20 ℃, add 2g of divinylbenzene (DVB) monomer, put into 20 ℃ constant temperature water bath to react for 30 minutes, and obtain dark red precipitate. Afterwards, the reaction was terminated with ethanol, and the white powder product was obtained by filtration. It is a superhydrophobic coral-structured nanofiber.

[0036] The scanning electron microscope and transmission electron microscope photos of the polymer nanofibers are as follows figure 1 shown. The length of the obtained polymer fiber material is more than 1 μm, and the diameter of the nanofiber is 10-500 nm. On the surface of the nanofiber, protrusions are uniformly distributed, the diameter of the protrusions is 1-200nm, and the length is 1-500nm.

[0037] The obtained material is prepared into a coatin...

Embodiment 2

[0039] Dissolve 0.15g of sorbitan monostearate (Span-60) in 125g of n-hexane, add dropwise 0.1g of boron trifluoride ethyl ether initiator, oscillate to emulsify evenly, and adjust the temperature of the system to 25°C , add 2g of divinylbenzene (DVB) monomer, put into 25 ℃ constant temperature water bath to react for 20 minutes, obtain deep red cotton flocculent precipitate. Afterwards, the reaction was terminated with ethanol, and a white cotton floc product was obtained by filtration. The resulting superhydrophobic coral-structured nanofibers.

[0040] The scanning electron microscope and transmission electron microscope photos of the polymer nanofibers are as follows figure 2 shown. The length of the obtained polymer fiber material is more than 1 μm, and the diameter of the nanofiber is 10-500 nm. On the surface of the nanofiber, protrusions are uniformly distributed, the diameter of the protrusions is 1-200nm, and the length is 1-500nm.

[0041] The obtained nanofibers...

Embodiment 3

[0043] Dissolve 0.1g of sorbitan stearate (Span-60) in 125g of n-hexane solution, add dropwise 0.1g of boron trifluoride ethyl ether initiator, oscillate to emulsify evenly, and adjust the temperature of the system to 25°C , add 4g of divinylbenzene (DVB) monomer, put into 25 ℃ constant temperature water bath and react for 30 minutes, obtain dark red cotton flocculent precipitate. Afterwards, the reaction was terminated with ethanol, and a white cotton floc product was obtained by filtration. The resulting coral-structured nanofibrous material.

[0044] The scanning electron microscope and transmission electron microscope photos of the polymer nanofibers are as follows image 3 shown. The length of the obtained polymer fiber material is more than 1 μm, and the diameter of the nanofiber is 10-500 nm. On the surface of the nanofiber, protrusions are uniformly distributed, the diameter of the protrusions is 1-200nm, and the length is 1-500nm.

[0045] The obtained material is...

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Abstract

The invention provides nanofibers of a coral structure. The nanofibers are characterized in that the diameters of the nanofibers are 10-500 nm, and the lengths of the nanofibers are over 1 micrometer. Protrusions evenly distributed are formed on the surfaces of the nanofibers, the diameters of the protrusions are 1-200 nm, and the lengths of the protrusions are 1-500 nm. The invention further provides a super-hydrophobic material which is characterized by comprising the nanofibers of the coral structure. The contact angle of the surface of the hydrophobic material is larger than 150 degrees, and the rolling angle is smaller than 5 degrees.

Description

technical field [0001] The invention relates to a superhydrophobic coral structure nanofiber and a preparation method thereof. Background technique [0002] Superhydrophobic material is a material that repells water. Water droplets cannot slide and spread on its surface and keep rolling in a spherical shape, so as to achieve the effect of rolling self-cleaning. The lotus leaf in nature is a typical representative of this material. Due to the special wettability of this material, it has a wide range of potential applications in the fields of self-cleaning, anti-corrosion, anti-fog, and fluid drag reduction. Studies have found that high roughness and low surface free energy on the surface of the material are two necessary conditions for realizing its superhydrophobicity (L. Feng, et al, Adv. Mater. 2002, 14, 1857-1860.) . At present, the methods for preparing organic superhydrophobic surfaces mainly include: engraved candle method, electrostatic spraying method, phase separ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/20C08F112/36C08F2/30
Inventor 杨振忠崔淑芹梁福鑫吕冬梅
Owner INST OF CHEM CHINESE ACAD OF SCI
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